Hydrolysis equilibrium of dinitrogen trioxide in dilute acid solution

Markovits, G. Y.; Schwartz, S. E.; Newman, L.

doi:10.1021/ic50216a025

Cited by 84Chemical Reaction MechanismsChemical and Physical Properties in Aqueous SolutionsInorganic and Organometallic Chemistry

Hydrolysis equilibrium of dinitrogen trioxide in dilute acid solution

Markovits, G. Y., Schwartz, S. E., Newman, L.·1981·Inorganic Chemistry

DOI 10.1021/ic50216a025

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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHydrolysis equilibrium of dinitrogen trioxide in dilute acid solutionG. Y. Markovits, S. E. Schwartz, and L. NewmanCite this: Inorg. Chem. 1981, 20, 2, 445–450Publication Date (Print):February 1, 1981Publication History Published online1 May 2002Published inissue 1 February 1981https://pubs.acs.org/doi/10.1021/ic50216a025https://doi.org/10.1021/ic50216a025research-articleACS PublicationsRequest reuse permissionsArticle Views318Altmetric-Citations76LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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HS- is a powerful nucleophile, exceeded only by hydrazine.
“While H2S itself is relatively unreactive, the thiolate ion (HS -) is a powerful nucleophile [36], exceeded only by hydrazine (H2N-NH2), which is a 'super nucleophile' because of the α-effect [39].”
From On the chemical biology of the nitrite/sulfide interaction (2015) · cites this paper as [39]

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Authors: Markovits, G. Y., Schwartz, S. E., & Newman, L.
ORCID: Schwartz, S. E.
Newman, L.
Venue: Inorganic Chemistry
Publisher: American Chemical Society (ACS)
Published: 1981-02
Volume: 20
Issue: 2
Pages: 445-450
ISSN: 0020-1669 (ISSN-L)
1520-510X
DOI: 10.1021/ic50216a025
OpenAlex: W1988163498
Cited by: 84
References: 0
Citations by year: 2024: 2 · 2023: 4 · 2022: 2 · 2021: 2 · 2020: 3 · 2019: 5 · 2018: 3 · 2016: 2 · 2015: 2 · 2014: 2 · 2013: 3 · 2012: 5
FWCI: 4.20
Type: journal article
Language: en
Open access: closed
Locations: Inorganic Chemistry (publishedVersion)
Topics: Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
Keywords: dinitrogen trioxide, hydrolysis equilibrium, dilute acid solutions, acid catalysis, nitric acid, nitrous acid, nitric oxide, nitric acid dimer

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Hydrolysis equilibrium of dinitrogen trioxide in dilute acid solution

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