Arsenic Removal Using Iron Oxide Loaded Alginate Beads
Abstract
The application of biopolymers (alginate), as sorbent supports, for the removal of arsenic from contaminated water has been investigated in the present study. Calcium alginate beads were placed in a column to form a fixed bed and treated (doped/coated) with hydrous ferric oxides. Three different types of modified alginate beads were examined for the removal of arsenic; the most efficient type was found to be doped with alginate and subsequently coated with iron oxides, whereas the other two types were calcium alginate beads doped or coated with iron oxides. The total amount of iron loaded on this material was found to be 3.9 mg of Fe/g of wet alginate bead. Approximately 230 bed volumes of a 50 μg/L As(V) solution were treated before the breakthrough point was reached, whereas the removal of As(III) was not as efficient, reaching the breakthrough point after the treatment of only 45 bed volumes. The results were modeled using the bed depth service time and empty bed residence time models.
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The oxidation of AsIII is generally carried out by the incorporation of chemical reagents such as ozone, hydrogen peroxide, chlorine, or potassium permanganate.
“The oxidation of AsIII is generally carried out by the incorporation of chemical reagents such as ozone, hydrogen peroxide, chlorine, or potassium permanganate [203–205].”
From Arsenic Contamination of Groundwater: A Review of Sources, Prevalence, Health Risks, and Strategies for Mitigation (2014) · cites this paper as [204]
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- Authors
- Zouboulis, A. I., & Katsoyiannis, I. A.
- Affiliations
- Aristotle University of Thessaloniki (GR)
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-10-29
- Volume
- 41
- Issue
- 24
- Pages
- 6149-6155
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2018731408
- Cited by
- 193
- References
- 29
- Citations by year
- 2025: 2 · 2024: 4 · 2023: 9 · 2022: 11 · 2021: 11 · 2020: 5 · 2019: 11 · 2018: 6 · 2017: 11 · 2016: 5 · 2015: 11 · 2014: 14 · 2013: 3 · 2012: 16
- FWCI
- 1.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Industrial & Engineering Chemistry Research (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- arsenic removal, calcium alginate beads, iron oxide, fixed-bed adsorption, As(V) adsorption, As(III) adsorption, breakthrough point, bed depth service time, water treatment
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