Influence of the Heating Rate and the Type of Catalyst on the Formation of Key Intermediates and on the Generation of Gases During Hydropyrolysis of Glucose in Supercritical Water in a Batch Reactor

Sınaǧ, Ali; Kruse, Andrea; Rathert, Jens

doi:10.1021/ie030475+

Cited by 332Subcritical and Supercritical Water ProcessesThermochemical Biomass Conversion ProcessesCatalysis for Biomass Conversion

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Influence of the Heating Rate and the Type of Catalyst on the Formation of Key Intermediates and on the Generation of Gases During Hydropyrolysis of Glucose in Supercritical Water in a Batch Reactor

Sınaǧ, Ali, Kruse, Andrea, Rathert, Jens·2004·Industrial & Engineering Chemistry Research

DOI 10.1021/ie030475+

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Abstract

To understand the influence of experimental conditions on the chemistry of biomass degradation in supercritical water, the effect of heating rate and of different catalysts (1 wt % of Raney nickel and 0.5 wt % K 2 CO 3 ) on the product distribution during hydropyrolysis of glucose is investigated. Glucose in aqueous solution (5 wt %) is selected as a model compound for cellulosic biomass. The heating rates are 1 or 3 K/min up to 500 °C, and then, the reactor is kept at this temperature for 1 h. Despite the long reaction time of 1 h at 500 °C, the presence of catalysts has an significant influence on intermediates of glucose gasification such as phenols or furfurals. The influence of catalyst and the heating rate on these intermediates and the product yields points to the assumption that the chemical processes during heating have a drastic effect on the results of the gasification process at 500 °C.

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Small amounts of corrosion product solids were found after batch experiments at 500°C with 5 wt% glucose and 0.5 wt% K2CO3 in an Inconel 625 reactor.
“However, small amounts of corrosion products (solids) were found after batch experiments performed at 500°C with 5 wt% glucose and 0.5 wt% K2CO3 using an Inconel 625 reactor 72 .”
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Authors: Sınaǧ, A., Kruse, A., & Rathert, J.
Affiliations: Institut füer Technische Chemie CPV, Forschungszentrum Karlsruhe, P.O. Box 3640, 76021 Karlsruhe, Germany
Karlsruhe Institute of Technology (DE)
Corresponding author: Kruse, Andrea
ORCID: Kruse, Andrea
Venue: Industrial & Engineering Chemistry Research
Publisher: American Chemical Society (ACS)
Published: 2003-12-23
Volume: 43
Issue: 2
Pages: 502-508
ISSN: 0888-5885 (ISSN-L)
1520-5045
DOI: 10.1021/ie030475+
OpenAlex: W1978094764
Cited by: 327
References: 29
Citations by year: 2026: 2 · 2025: 7 · 2024: 9 · 2023: 12 · 2022: 21 · 2021: 18 · 2020: 15 · 2019: 11 · 2018: 18 · 2017: 17 · 2016: 9 · 2015: 21 · 2014: 23 · 2013: 22 · 2012: 18
FWCI: 6.33
Type: journal article
Language: en
Open access: closed
Locations: Industrial & Engineering Chemistry Research (publishedVersion)
Topics: Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Subcritical and Supercritical Water Processes
Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
Keywords: supercritical water, heating rate, Raney nickel catalyst, potassium carbonate catalyst, biomass degradation, phenols, furfural, reaction intermediates, product distribution

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Influence of the Heating Rate and the Type of Catalyst on the Formation of Key Intermediates and on the Generation of Gases During Hydropyrolysis of Glucose in Supercritical Water in a Batch Reactor

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