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Ethylenediamine-Modified SBA-15 as Regenerable CO2 Sorbent

Zheng, Feng, Tran, Diana N., Busche, Brad J., Fryxell, Glen E., Addleman, R. Shane, Zemanian, Thomas S., Aardahl, Christopher L.·2005·Industrial & Engineering Chemistry Research

Abstract

The CO 2 adsorption properties of an ethylenediamine-modified mesoporous silica, EDA-SBA-15, have been examined. Adsorption isotherms were collected by TGA measurements, and the breakthrough time and adsorption capacity were measured using a fixed-bed flow system. The EDA-SBA-15 sorbent adsorbs around 20 mg/g of CO 2 from 15% CO 2 in N 2 at 25 °C and 1 atm total pressure. In pure CO 2 at 1 atm, its adsorption capacity is 86 mg/g at 22 °C. The EDA-SBA-15 sorbent is fully regenerable by thermal swings during cyclic adsorption/desorption. Desorption of CO 2 occurs at 110 °C on EDA-SBA-15 and the sorbent is stable in air up to 200 °C. The CO 2 uptake by EDA-SBA-15 is not influenced by humidity. The adsorption capacity data are compared with those of previously reported amine-modified silica sorbents.

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Metadata

Authors
Zheng, F., Tran, D. N., Busche, B. J., Fryxell, G. E., Addleman, R. S., Zemanian, T. S., & Aardahl, C. L.
Venue
Industrial & Engineering Chemistry Research
Published
2005-03-25
Volume
44
Issue
9
Pages
3099-3105
ISSN
  • 0888-5885 (ISSN-L)
  • 1520-5045
OpenAlex
W2012365839
Cited by
261
References
14
FWCI
17.59
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ethylenediamine-Modified SBA-15 as Regenerable CO2 Sorbent. https://app.cochat.ai/papers/10.1021/ie049488t
The paper
Zheng, F., Tran, D. N., Busche, B. J., Fryxell, G. E., Addleman, R. S., Zemanian, T. S., & Aardahl, C. L. (2005). Ethylenediamine-Modified SBA-15 as Regenerable CO2 Sorbent. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie049488t

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