The DOI matches its Crossref record.
CO2 Capture Capacity of CaO in Long Series of Carbonation/Calcination Cycles
Abstract
Calcium oxide can be an effective sorbent to separate CO 2 at high temperatures. When coupled with a calcination step to produce pure CO 2, the carbonation reaction is the basis for several high-temperature CO 2 capture systems. The evolution with cycling of the capture capacity of CaO derived from natural limestones is experimentally investigated in this work. Long series of carbonation/calcination cycles (up to 500) varying different variables affecting sorbent capacity have been tested in a thermogravimetric apparatus. Calcination temperatures above T > 950 °C and very long calcination times accelerate the decay in sorption capacity, while other variables have a comparatively modest effect on the overall sorbent performance. A residual conversion of about 7−8% that remains constant after many hundreds of cycles and that seems insensitive to process conditions has been found. This residual conversion makes very attractive the carbonation/calcination cycle, by reducing (or even eliminating) sorbent purge rates in the system. A semiempirical equation has been proposed to describe sorbent conversion with the number of cycles based on these new long data series.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
No references could be resolved yet.
Research works printed but not linked: 26
- Special Report, 2005, Intergovernmental Panel on Climate Change
- Abanades J. C., 2005, Environ. Sci. Technol., 39, 2861, 10.1021/es0496221 · DOI · Paper page
- Collot A. G., 2003, Prospects for hydrogen from coal
- Abanades J. C., 2004, Ind. Eng. Chem. Res., 43, 3462, 10.1021/ie049962v · DOI · Paper page
- Curran G. P., 1967, Adv. Chem. Ser., 69, 141, 10.1021/ba-1967-0069.ch010 · DOI
- Silaban A., 1995, Chem. Eng. Commun., 137, 177, 10.1080/00986449508936375 · DOI
- Barker R., 1973, J. Appl. Chem. Biotechnol., 23, 733, 10.1002/jctb.5020231005 · DOI · Paper page
- Bathia S. K., 1983, AIChE J., 39, 79
- Shimizu T., 1999, Trans. Inst. Chem.Eng., 77, 62, 10.1205/026387699525882 · DOI · Paper page
- Abanades J. C., 2003, Energy Fuels, 17, 308, 10.1021/ef020152a · DOI · Paper page
- Ahiara M., 2001, Appl. Energy, 69, 225, 10.1016/S0306-2619(00)00072-6 · DOI
- Gupta H., 2002, Ind. Eng. Chem. Res., 41, 4035, 10.1021/ie010867l · DOI · Paper page
- Lu H., 2006, Ind. Eng. Chem. Res., 45, 3944, 10.1021/ie051325x · DOI · Paper page
- Hughes R. W., 2004, Ind. Eng. Chem. Res., 43, 5529, 10.1021/ie034260b · DOI · Paper page
- Alvarez D., 2005, Ind. Eng. Chem. Res., 44, 5608, 10.1021/ie050305s · DOI · Paper page
- Anthony E. J., 2001, Prog. Energy Combust. Sci., 27, 215, 10.1016/S0360-1285(00)00021-6 · DOI · Paper page
- Laursen K., 2000, Fuel, 79, 153, 10.1016/S0016-2361(99)00147-7 · DOI
- Alvarez D., 2005, Energy Fuels, 19, 270, 10.1021/ef049864m · DOI · Paper page
- Bandi A, 1976, Thermochim. Acta, 14, 221, 10.1016/0040-6031(76)80070-6 · doi:10.1016/0040-6031(76)80070-6
- Lin S. Y., 2002, Energy Convers. Manage., 43, 1283, 10.1016/S0196-8904(02)00014-6 · DOI
- Wang J., 2004, Fuel, 83, 1341, 10.1016/j.fuel.2004.01.002 · doi:10.1016/j.fuel.2004.01.002
- Deutch Y., 1991, Thermochim. Acta, 182, 77, 10.1016/0040-6031(91)87010-T · doi:10.1016/0040-6031(91)87010-t
- Wang J., 2005, Ind. Eng. Chem. Res.., 44, 627, 10.1021/ie0493154 · doi:10.1021/ie0493154
- Bartholomew C. H., 1993, A: Gen.
- Corella J., 1988, Ind. Eng. Chem. Res., 27, 375, 10.1021/ie00075a002 · doi:10.1021/ie00075a002
- Abanades J. C., 2005, International Conference on Coal Science and Technology
Cited by
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Carbon capture and storage using alkaline industrial wastes
Bobicki, E. R., Liu, Q., Xu, Z., & Zeng, H. (2012) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2011.11.002 · Cited by 666
A critical review of high-temperature reversible thermochemical energy storage systems
Sunku Prasad, J., Muthukumar, P., Desai, F., Basu, D. N., & Rahman, M. M. (2019) · Applied Energy · doi:10.1016/j.apenergy.2019.113733 · Cited by 405
Dean, C. C., Blamey, J., Florin, N. H., Al-Jeboori, M. J., & Fennell, P. S. (2011) · Chemical Engineering Research and Design · doi:10.1016/j.cherd.2010.10.013 · Cited by 375
Calcium looping sorbents for CO2 capture
Erans, M., Manovic, V., & Anthony, E. J. (2016) · Applied Energy · doi:10.1016/j.apenergy.2016.07.074 · Cited by 369
Metadata
- Authors
- Grasa, G. S., & Abanades, J. C.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-11-09
- Volume
- 45
- Issue
- 26
- Pages
- 8846-8851
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W1999180312
- Cited by
- 757
- References
- 0
- FWCI
- 60.30
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: CO2 Capture Capacity of CaO in Long Series of Carbonation/Calcination Cycles. https://app.cochat.ai/papers/10.1021/ie0606946
- The paper
- Grasa, G. S., & Abanades, J. C. (2006). CO2 Capture Capacity of CaO in Long Series of Carbonation/Calcination Cycles. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/ie0606946
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
