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In Situ Microwave-Assisted Synthesis of Porous N-TiO2/g-C3N4Heterojunctions with Enhanced Visible-Light Photocatalytic Properties
Abstract
An in situ microwave-assisted synthesis approach has been developed to prepare N-TiO 2 /g-C 3 N 4 composites using H 2 TiO 3 as the reactant and NH 3 ·H 2 O as the N-doping source. In this way, the N-TiO 2 /g-C 3 N 4 composite catalysts have a porous structure and large surface areas, which increase the contact area of pollutants. Degradation of rhodamine B (Rh B) and methylene blue (MB) were carried out to evaluate the photocatalytic activity of samples under visible light irradiation. N-TiO 2 /g-C 3 N 4 composite with 40 wt % N-TiO 2 exhibits the highest photocatalytic activity and the optimal temperature is 400 °C. The increased photocatalytic activity of N-TiO 2 /g-C 3 N 4 composites can be attributed to the formation of the heterojunction between N-TiO 2 and g-C 3 N 4, which suppresses the recombination of photoinduced electron–hole pairs. The tests of radical scavengers confirmed that • O 2 – was the main reactive species during the photocatalytic process.
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Metadata
- Authors
- Wang, X.-J., Yang, W.-Y., Li, F.-T., Xue, Y.-B., Liu, R.-H., & Hao, Y.-J.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-11-20
- Volume
- 52
- Issue
- 48
- Pages
- 17140-17150
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2326454326
- Cited by
- 365
- References
- 43
- FWCI
- 12.14
- Type
- journal article
- Language
- en
- Open access
- closed
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