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High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide
Abstract
Despite recent advances regarding catalysts for CO2/epoxide copolymerization, the development of high-activity catalysts for alternating polymerization of CO2 and commodity epoxides, such as propylene oxide, remains a challenge. A new class of unsymmetrically substituted beta-diiminate zinc complexes is reported that exhibits unprecedented activity for CO2/propylene oxide copolymerization. The polymers formed are of high molecular weight (Mn approximately 35 kg/mol) and have narrow polydispersities (PDI approximately 1.1), consistent with a living polymerization.
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Citations
Cited by
JOHN, M., & THOMAS, S. (2008) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2007.05.040 · Cited by 2,453
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154
Self-citationCatalysts for CO 2 /epoxide copolymerisation
Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797
Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms
Klaus, S., Lehenmeier, M. W., Anderson, C. E., & Rieger, B. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.12.002 · Cited by 710
Metadata
- Authors
- Allen, S. D., Moore, D. R., Lobkovsky, E. B., & Coates, G. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-11-08
- Volume
- 124
- Issue
- 48
- Pages
- 14284-14285
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1993403734
- Cited by
- 325
- References
- 0
- FWCI
- 21.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Allen, S. D., Moore, D. R., Lobkovsky, E. B., & Coates, G. W. (2002). High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide. Journal of the American Chemical Society. https://doi.org/10.1021/ja028071g
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
