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Hydrogen Adsorption in Nanoporous Nickel(II) Phosphates
Abstract
Hydrogen sorption in the nanoporous nickel phosphates VSB-1 and VSB-5 has been studied with a combination of BET, temperature programmed desorption (TPD), and inelastic neutron scattering (INS) measurements. H(2) BET isotherms for VSB-1 are similar to those seen in nanoporous zeolites, while VSB-5 adsorbs substantially more hydrogen due to a steep initial uptake at low partial pressures. TPD data show that hydrogen interacts strongly with VSB-5, with desorption peaks at 109 and 149 K in a nitrogen flow, whereas the absence of similar peaks for VSB-1 suggests a weaker interaction. INS spectra of the rotational tunnel transition of the adsorbed H(2) also reveal a strong interaction with the VSB-5 host. These data strongly suggest the existence of coordinatively unsaturated Ni(2+) sites accessible to H(2) molecules in the pores of VSB-5.
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Metadata
- Authors
- Forster, P. M., Eckert, J., Chang, J.-S., Park, S.-E., Férey, G., & Cheetham, A. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-01-10
- Volume
- 125
- Issue
- 5
- Pages
- 1309-1312
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2041706198
- Cited by
- 263
- References
- 0
- FWCI
- 19.55
- Type
- journal article
- Language
- en
- Open access
- closed
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