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Solubilization of Carbon Nanotubes by Nafion toward the Preparation of Amperometric Biosensors
Abstract
The ability to solubilize single-wall and multiwall carbon nanotubes (CNT) in the presence of the perfluorinated polymer Nafion is described. Such use of Nafion as a solubilizing agent for CNT overcomes a major obstacle for creating CNT-based biosensing devices. Their association with Nafion does not impair the electrocatalytic properties of CNT. The resulting CNT/Nafion modified glassy-carbon electrodes exhibit a strong and stable electrocatalytic response toward hydrogen peroxide. The marked acceleration of the hydrogen peroxide redox process is very attractive for the operation of oxidase-based amperometric biosensors, as illustrated for the highly selective low-potential (-0.05 V vs Ag/AgCl) biosensing of glucose. These findings open the door for using CNT in a wide range of chemical sensors and nanoscale electronic devices.
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Metadata
- Authors
- Wang, J., Musameh, M., & Lin, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-02-08
- Volume
- 125
- Issue
- 9
- Pages
- 2408-2409
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2026052512
- Cited by
- 1,382
- References
- 13
- FWCI
- 80.11
- Type
- journal article
- Language
- en
- Open access
- closed
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