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Cited by 1,309

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Type-II Quantum Dots: CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures

Kim, Sungjee, Fisher, Brent, Eisler, Hans-Jürgen, Bawendi, Moungi·2003·Journal of the American Chemical Society

Abstract

Type-II band engineered quantum dots (CdTe/CdSe(core/shell) and CdSe/ZnTe(core/shell) heterostructures) are described. The optical properties of these type-II quantum dots are studied in parallel with their type-I counterparts. We demonstrate that the spatial distribution of carriers can be controlled within the type-II quantum dots, which makes their properties strongly governed by the band offset of the comprising materials. This allows access to optical transition energies that are not restricted to band gap energies. The type-II quantum dots reported here can emit at lower energies than the band gaps of comprising materials. The type-II emission can be tailored by the shell thickness as well as the core size. The enhanced control over carrier distribution afforded by these type-II materials may prove useful for many applications, such as photovoltaics and photoconduction devices.

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Metadata

Authors
Kim, S., Fisher, B., Eisler, H.-J., & Bawendi, M.
Venue
Journal of the American Chemical Society
Published
2003-08-29
Volume
125
Issue
38
Pages
11466-11467
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1996259855
Cited by
1,309
References
1
FWCI
16.32
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Type-II Quantum Dots: CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures. https://app.cochat.ai/papers/10.1021/ja0361749
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Kim, S., Fisher, B., Eisler, H.-J., & Bawendi, M. (2003). Type-II Quantum Dots: CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures. Journal of the American Chemical Society. https://doi.org/10.1021/ja0361749

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