The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Copper Oxide Nanocrystals
Abstract
It is well-known that inorganic nanocrystals are a benchmark model for nanotechnology, given that the tunability of optical properties and the stabilization of specific phases are uniquely possible at the nanoscale. Copper (I) oxide (Cu(2)O) is a metal oxide semiconductor with promising applications in solar energy conversion and catalysis. To understand the Cu/Cu(2)O/CuO system at the nanoscale, we have developed a method for preparing highly uniform monodisperse nanocrystals of Cu(2)O. The procedure also serves to demonstrate our development of a generalized method for the synthesis of transition metal oxide nanocrystals. Cu nanocrystals are initially formed and subsequently oxidized to form highly crystalline Cu(2)O. The volume change during phase transformation can induce crystal twinning. Absorption in the visible region of the spectrum gave evidence for the presence of a thin, epitaxial layer of CuO, which is blue-shifted, and appears to increase in energy as a function of decreasing particle size. XPS confirmed the thin layer of CuO, calculated to have a thickness of approximately 5 A. We note that the copper (I) oxide phase is surprisingly well-stabilized at this length scale.
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Cites
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Cited by
Hoang, T. T. H., Verma, S., Ma, S., Fister, T. T., Timoshenko, J., Frenkel, A. I., Kenis, P. J. A., & Gewirth, A. A. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01868 · Cited by 852
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.124 · Cited by 488
Highly Dense Cu Nanowires for Low-Overpotential CO 2 Reduction
Raciti, D., Livi, K. J., & Wang, C. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03298 · Cited by 395
Nanoporous Copper Films by Additive-Controlled Electrodeposition: CO2 Reduction Catalysis
Hoang, T. T. H., Ma, S., Gold, J. I., Kenis, P. J. A., & Gewirth, A. A. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03613 · Cited by 296
Begildayeva, T., Lee, S. J., Yu, Y., Park, J., Kim, T. H., Theerthagiri, J., Ahn, A., Jung, H. J., & Choi, M. Y. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.124412 · Cited by 101
Dizajghorbani Aghdam, H., Azadi, H., Esmaeilzadeh, M., Moemen Bellah, S., & Malekfar, R. (2019) · Optical Materials · doi:10.1016/j.optmat.2019.03.027 · Cited by 40
Metadata
- Authors
- Yin, M., Wu, C.-K., Lou, Y., Burda, C., Koberstein, J. T., Zhu, Y., & O'Brien, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-06-10
- Volume
- 127
- Issue
- 26
- Pages
- 9506-9511
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2011679767
- Cited by
- 986
- References
- 2
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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