One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
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In gas phase systems, catalysts that have poor CO2RR selectivity in liquid phase electrolyzers (Pt, Fe, Fe-Co, Pt-Ru, etc.) can produce methanol, isopropanol, and >C5 long chain products, although in small quantities.
“Researchers have also used catalysts that have poor CO2RR selectivity in liquid phase electrolyzers (Pt, Fe, Fe-Co, Pt-Ru, etc.) to produce products not typically observed in other flow cell systems, such as methanol, [146][147][148][149] isopropanol, [150,151] and >C5 long chain products, although in small quantities.[152,153]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [153]
The electrolyzer total current density of 200 mA/cm2 has been demonstrated in numerous laboratory reactors at roughly 2.3 V.
“The electrolyzer total current density of 200 mA/cm 2 has been demonstrated in numerous laboratory reactors at roughly 2.3 V. 70”
From General Techno-Economic Analysis of CO <sub>2</sub> Electrolysis Systems (2018) · cites this paper as [70]
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- Authors
- Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A.
- Affiliations
- Kyushu University (JP)
- University of Illinois Urbana-Champaign (US)
- Corresponding author
- Yamauchi, Miho
- Kenis, Paul J.A.
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2016-01
- Volume
- 301
- Pages
- 219-228
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W1931367894
- Cited by
- 488
- References
- 48
- Citations by year
- 2026: 15 · 2025: 42 · 2024: 35 · 2023: 50 · 2022: 59 · 2021: 70 · 2020: 59 · 2019: 79 · 2018: 43 · 2017: 25 · 2016: 11
- FWCI
- 7.32
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- www.elsevier.com/open-access/userlicense/1.0/ (am, 667 d)
- doi.org/10.15223/policy-017 (stm-asf)
- doi.org/10.15223/policy-037 (stm-asf)
- doi.org/10.15223/policy-012 (stm-asf)
- doi.org/10.15223/policy-029 (stm-asf)
- doi.org/10.15223/policy-004 (stm-asf)
- Locations
- Journal of Power Sources (acceptedVersion)
- Funders
- International Institute for Carbon-Neutral Energy Research (WPI–I2CNER)
- Japanese Ministry of Education, Culture, Sports, Science and Technology
- JST-CREST
- JSPS KAKENHI (25288030, 24655040, 24850013, 21350031)
- FMC Educational Fund
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, ethylene production, ethanol production, copper nanoparticles, alkaline electrolyzer, Faradaic efficiency, surface oxide layer, catalyst morphology, gas diffusion electrode, hydrogen suppression, renewable energy storage, electrocatalysts
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