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Cited by 419

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Fatty Acid Salts as Stabilizers in Size- and Shape-Controlled Nanocrystal Synthesis: The Case of Inverse Spinel Iron Oxide

Kovalenko, Maksym V., Bodnarchuk, Maryna I., Lechner, Rainer T., Hesser, Günter, Schäffler, Friedrich, Heiss, Wolfgang·2007·Journal of the American Chemical Society

Abstract

Various oleic acid salts are demonstrated to act as stabilizers for high-quality iron oxide nanocrystals, synthesized by thermal decomposition of ferric oleate. Changing the cation species in oleic acid salts allows different degrees of dissociation at high temperatures to be obtained, resulting in various stabilizer performances: Sodium oleate as stabilizer results in monodisperse iron oxide nanocrystals of cubic shape with precisely adjustable edge lengths between 7 and 23 nm. Dibutylammonium oleate and oleic acid, in contrast, induce growth of spherical nanocrystals in the same size range. Further adjustment of the growth conditions leads to {100}-bound bipyramidal nanocrystals with a single, (111) oriented twin plane. While the nanocrystal size is related to their superparamagnetic blocking temperature, the shape influences their magnetization hysteresis properties observed at low temperatures.

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Metadata

Authors
Kovalenko, M. V., Bodnarchuk, M. I., Lechner, R. T., Hesser, G., Schäffler, F., & Heiss, W.
Venue
Journal of the American Chemical Society
Published
2007-05-01
Volume
129
Issue
20
Pages
6352-6353
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2030340917
Cited by
419
References
1
FWCI
9.69
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Fatty Acid Salts as Stabilizers in Size- and Shape-Controlled Nanocrystal Synthesis: The Case of Inverse Spinel Iron Oxide. https://app.cochat.ai/papers/10.1021/ja0692478
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Kovalenko, M. V., Bodnarchuk, M. I., Lechner, R. T., Hesser, G., Schäffler, F., & Heiss, W. (2007). Fatty Acid Salts as Stabilizers in Size- and Shape-Controlled Nanocrystal Synthesis: The Case of Inverse Spinel Iron Oxide. Journal of the American Chemical Society. https://doi.org/10.1021/ja0692478

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