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Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
Abstract
The covalent modification of the metal−organic framework IRMOF-3 has been achieved using acetic anhydride. Mass spectrometry and 1 H NMR evidence shows that the free amine groups in IRMOF-3 are converted to amides in high yields. Control experiments and X-ray diffraction studies suggest that this reaction occurs on the intact framework with preservation of crystallinity. This finding opens up new possibilities for the preparation of novel MOFs using a postsynthetic modification strategy.
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Metadata
- Authors
- Wang, Z., & Cohen, S. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-20
- Volume
- 129
- Issue
- 41
- Pages
- 12368-12369
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2030333142
- Cited by
- 644
- References
- 0
- FWCI
- 26.39
- Type
- journal article
- Language
- en
- Open access
- closed
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