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Fluorous Metal−Organic Frameworks for High-Density Gas Adsorption
Abstract
A fluorous metal−organic framework, FMOF-1, is obtained by reaction of Ag(I) with 3,5-bis(trifluoromethyl)-1,2,4-triazolate, giving rise to a neutral, hydrogen-free, extended 3D nanotubular porous framework consisting of tetranuclear clusters [Ag 4 Tz 6 ] connected by three-coordinate Ag(I) centers. The fluoro-lined channels and cavities of the framework show hysteretic adsorption of H 2 with a volumetric capacity of 41 kg/m 3 at 77 K and 64 bar. The framework also exhibits very high adsorptions for O 2 and N 2 with volumetric uptake of ∼550 and 400 kg/m 3 at 77 K even at very low pressures (<10 -2 bar).
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Metadata
- Authors
- Yang, C., Wang, X., & Omary, M. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-23
- Volume
- 129
- Issue
- 50
- Pages
- 15454-15455
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2058877670
- Cited by
- 352
- References
- 0
- FWCI
- 16.62
- Type
- journal article
- Language
- en
- Open access
- closed
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