The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
When the Signal Is Not from the Original Molecule To Be Detected: Chemical Transformation of para-Aminothiophenol on Ag during the SERS Measurement
Abstract
Surface-enhanced Raman spectroscopy (SERS) has long been considered as a noninvasive technique that can obtain the fingerprint vibrational information of surface species. We demonstrated in this paper that a laser with a power level considered to be low in the traditional SERS measurement can already lead to a significant surface reaction. para-Aminothiophenol, an important probe molecule in SERS, was found to be oxidized to form 4,4'-dimercaptoazobenzene (DMAB) on a roughened silver surface during the SERS measurement. The assumption was confirmed experimentally by surface mass spectroscopy and SERS as well as electrochemistry of the synthesized DMAB, which agrees well with theoretical calculations. A defocusing method was used to avoid the laser induced surface reaction and perform reliable SERS characterization and identification, which can effectively avoid erroneous interpretation of the distorted experimental result.
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Cites
Raman spectra of pyridine adsorbed at a silver electrode
Fleischmann, M., Hendra, P. J., & McQuillan, A. J. (1974) · Chemical Physics Letters · doi:10.1016/0009-2614(74)85388-1 · Cited by 7,172
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Wu, D.-Y., Liu, X.-M., Huang, Y.-F., Ren, B., Xu, X., & Tian, Z.-Q. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9050929 · Cited by 311
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Cited by
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z.-L., Xu, D., Xu, J.-J., & Zhang, X.-B. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60248f · Cited by 1,447
A Review on Surface-Enhanced Raman Scattering
Pilot, R., Signorini, R., Durante, C., Orian, L., Bhamidipati, M., & Fabris, L. (2019) · Biosensors · doi:10.3390/bios9020057 · Cited by 1,010
Single-Molecule Chemistry with Surface- and Tip-Enhanced Raman Spectroscopy
Zrimsek, A. B., Chiang, N., Mattei, M., Zaleski, S., McAnally, M. O., Chapman, C. T., Henry, A.-I., Schatz, G. C., & Van Duyne, R. P. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00552 · Cited by 720
Fundamental understanding and applications of plasmon-enhanced Raman spectroscopy
Wang, X., Huang, S.-C., Hu, S., Yan, S., & Ren, B. (2020) · Nature Reviews Physics · doi:10.1038/s42254-020-0171-y · Cited by 689
Self-citationCatalytic processes monitored at the nanoscale with tip-enhanced Raman spectroscopy
van Schrojenstein Lantman, E. M., Deckert-Gaudig, T., Mank, A. J. G., Deckert, V., & Weckhuysen, B. M. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.131 · Cited by 630
Metadata
- Authors
- Huang, Y.-F., Zhu, H.-P., Liu, G.-K., Wu, D.-Y., Ren, B., & Tian, Z.-Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-06-08
- Volume
- 132
- Issue
- 27
- Pages
- 9244-9246
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1988668502
- Cited by
- 764
- References
- 3
- FWCI
- 16.49
- Type
- journal article
- Language
- en
- Open access
- closed
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