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Cited by 764

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

When the Signal Is Not from the Original Molecule To Be Detected: Chemical Transformation of para-Aminothiophenol on Ag during the SERS Measurement

Huang, Yi-Fan, Zhu, Hong-Ping, Liu, Guo-Kun, Wu, De-Yin, Ren, Bin, Tian, Zhong-Qun·2010·Journal of the American Chemical Society

Abstract

Surface-enhanced Raman spectroscopy (SERS) has long been considered as a noninvasive technique that can obtain the fingerprint vibrational information of surface species. We demonstrated in this paper that a laser with a power level considered to be low in the traditional SERS measurement can already lead to a significant surface reaction. para-Aminothiophenol, an important probe molecule in SERS, was found to be oxidized to form 4,4'-dimercaptoazobenzene (DMAB) on a roughened silver surface during the SERS measurement. The assumption was confirmed experimentally by surface mass spectroscopy and SERS as well as electrochemistry of the synthesized DMAB, which agrees well with theoretical calculations. A defocusing method was used to avoid the laser induced surface reaction and perform reliable SERS characterization and identification, which can effectively avoid erroneous interpretation of the distorted experimental result.

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Metadata

Authors
Huang, Y.-F., Zhu, H.-P., Liu, G.-K., Wu, D.-Y., Ren, B., & Tian, Z.-Q.
Venue
Journal of the American Chemical Society
Published
2010-06-08
Volume
132
Issue
27
Pages
9244-9246
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1988668502
Cited by
764
References
3
FWCI
16.49
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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