The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization
Open accessAbstract
It is shown that surface NMR spectra can be greatly enhanced using dynamic nuclear polarization. Polarization is transferred from the protons of the solvent to the rare nuclei (here carbon-13 at natural isotopic abundance) at the surface, yielding at least a 50-fold signal enhancement for surface species covalently incorporated into a silica framework.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Silica‐Based Mesoporous Organic–Inorganic Hybrid Materials
Hoffmann, F., Cornelius, M., Morell, J., & Fröba, M. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503075 · Cited by 3,089
An Improved Broadband Decoupling Sequence for Liquid Crystals and Solids
Fung, B. M., Khitrin, A. K., & Ermolaev, K. (2000) · Journal of Magnetic Resonance · doi:10.1006/jmre.1999.1896 · Cited by 1,987
Marion, D., Ikura, M., Tschudin, R., & Bax, A. (1989) · Journal of Magnetic Resonance (1969) · doi:10.1016/0022-2364(89)90152-2 · Cited by 1,397
Direct Syntheses of Ordered SBA-15 Mesoporous Silica Containing Sulfonic Acid Groups
Margolese, D. I., Melero, J. A., Christiansen, S. C., Chmelka, B. F., & Stucky, G. D. (2000) · Chemistry of Materials · doi:10.1021/cm0010304 · Cited by 975
Dynamic nuclear polarization at high magnetic fields
Maly, T., Debelouchina, G. T., Bajaj, V. S., Hu, K.-N., Joo, C.-G., Mak–Jurkauskas, M. L., Sirigiri, J. R., van der Wel, P. C. A., Herzfeld, J., Temkin, R. J., et al. (2008) · The Journal of Chemical Physics · doi:10.1063/1.2833582 · Cited by 919
Polarization-Enhanced NMR Spectroscopy of Biomolecules in Frozen Solution
Hall, D. A., Maus, D. C., Gerfen, G. J., Inati, S. J., Becerra, L. R., Dahlquist, F. W., & Griffin, R. G. (1997) · Science · doi:10.1126/science.276.5314.930 · Cited by 553
TOTAPOL: A Biradical Polarizing Agent for Dynamic Nuclear Polarization Experiments in Aqueous Media
Song, C., Hu, K.-N., Joo, C.-G., Swager, T. M., & Griffin, R. G. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061284b · Cited by 550
Macquarrie, D. J. (1996) · Chem. Commun. · doi:10.1039/cc9960001961 · Cited by 426
Solid-state dynamic nuclear polarization at 263 GHz: spectrometer design and experimental results
Rosay, M., Tometich, L., Pawsey, S., Bader, R., Schauwecker, R., Blank, M., Borchard, P. M., Cauffman, S. R., Felch, K. L., Weber, R. T., et al. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c003685b · Cited by 370
High-Field Dynamic Nuclear Polarization for Solid and Solution Biological NMR
Barnes, A. B., De Paëpe, G., van der Wel, P. C. A., Hu, K.-N., Joo, C.-G., Bajaj, V. S., Mak-Jurkauskas, M. L., Sirigiri, J. R., Herzfeld, J., Temkin, R. J., et al. (2008) · Applied Magnetic Resonance · doi:10.1007/s00723-008-0129-1 · Cited by 359
Mercier, L., & Pinnavaia, T. J. (2000) · Chemistry of Materials · doi:10.1021/cm990532i · Cited by 327
van der Wel, P. C. A., Hu, K.-N., Lewandowski, J., & Griffin, R. G. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0626685 · Cited by 294
Hu, K.-N., Song, C., Yu, H.-H., Swager, T. M., & Griffin, R. G. (2008) · The Journal of Chemical Physics · doi:10.1063/1.2816783 · Cited by 190
Dinitrogen Dissociation on an Isolated Surface Tantalum Atom
Avenier, P., Taoufik, M., Lesage, A., Solans-Monfort, X., Baudouin, A., de Mallmann, A., Veyre, L., Basset, J.-M., Eisenstein, O., Emsley, L., et al. (2007) · Science · doi:10.1126/science.1143078 · Cited by 187
Self-citationHansen, E. W., Stöcker, M., & Schmidt, R. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp951772y · Cited by 181
Debelouchina, G. T., Bayro, M. J., van der Wel, P. C. A., Caporini, M. A., Barnes, A. B., Rosay, M., Maas, W. E., & Griffin, R. G. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c003661g · Cited by 134
Self-citationMolecular chemistry and nanosciences: on the way to interactive materials
Corriu, R. J. P., Mehdi, A., & Reyé, C. (2005) · Journal of Materials Chemistry · doi:10.1039/b504536n · Cited by 93
Self-citationWater-Saturated Mesoporous MCM-41 Systems Characterized by 1H NMR
Akporiaye, D. E., Hansen, E. W., Schmidt, R., & Stöcker, M. (1994) · The Journal of Physical Chemistry · doi:10.1021/j100058a034 · Cited by 89
Water-Saturated Mesoporous MCM-41 Systems Characterized by 1H NMR Spin-Lattice Relaxation Times
Hansen, E. W., Schmidt, R., Stoecker, M., & Akporiaye, D. E. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100012a040 · Cited by 77
Cited by
Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
Lilly Thankamony, A. S., Wittmann, J. J., Kaushik, M., & Corzilius, B. (2017) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/j.pnmrs.2017.06.002 · Cited by 544
Highly Efficient, Water‐Soluble Polarizing Agents for Dynamic Nuclear Polarization at High Frequency
Sauvée, C., Rosay, M., Casano, G., Aussenac, F., Weber, R. T., Ouari, O., & Tordo, P. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201304657 · Cited by 503
Kachala, V. V., Khemchyan, L. L., Kashin, A. S., Orlov, N. V., Grachev, A. A., Zalesskiy, S. S., & Ananikov, V. P. (2013) · Russian Chemical Reviews · doi:10.1070/rc2013v082n07abeh004413 · Cited by 262
Mentink-Vigier, F., Marin-Montesinos, I., Jagtap, A. P., Halbritter, T., van Tol, J., Hediger, S., Lee, D., Sigurdsson, S. T., & De Paëpe, G. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04911 · Cited by 171
Takahashi, H., Ayala, I., Bardet, M., De Paëpe, G., Simorre, J.-P., & Hediger, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja312501d · Cited by 149
Metadata
- Authors
- Lesage, A., Lelli, M., Gajan, D., Caporini, M. A., Vitzthum, V., Miéville, P., Alauzun, J., Roussey, A., Thieuleux, C., Mehdi, A., Bodenhausen, G., Coperet, C., & Emsley, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-10
- Volume
- 132
- Issue
- 44
- Pages
- 15459-15461
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1965194735
- Cited by
- 585
- References
- 19
- FWCI
- 13.13
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
