The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Biologically Inspired Highly Durable Iron Phthalocyanine Catalysts for Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells
Abstract
In the present work, we have designed and synthesized a new highly durable iron phtalocyanine based nonprecious oxygen reduction reaction (ORR) catalyst (Fe-SPc) for polymer electrolyte membrane fuel cells (PEMFCs). The Fe-SPc, with a novel structure inspired by that of naturally occurring oxygen activation catalysts, is prepared by a nonpyrolyzing method, allowing adequate control of the atomic structure and surface properties of the material. Significantly improved ORR stability of the Fe-SPc is observed compared with the commercial Fe-Pc catalysts. The Fe-SPc has similar activity to that of the commercial Fe-Pc initially, while the Fe-SPc displays 4.6 times higher current density than that of the commercial Fe-Pc after 10 sweep potential cycles, and a current density that is 7.4 times higher after 100 cycles. This has been attributed to the incorporation of electron-donating functional groups, along with a high degree of steric hindrance maintaining active site isolation. Nonprecious Fe-SPc is promising as a potential alternative ORR electrocatalyst for PEMFCs.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Huang, S.-Y., Ganesan, P., Park, S., & Popov, B. N. (2009) · Journal of the American Chemical Society · doi:10.1021/ja904810h · Cited by 513
Cited by
Jiang, W.-J., Gu, L., Li, L., Zhang, Y., Zhang, X., Zhang, L.-J., Wang, J.-Q., Hu, J.-S., Wei, Z., & Wan, L.-J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00757 · Cited by 1,765
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z.-L., Xu, D., Xu, J.-J., & Zhang, X.-B. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60248f · Cited by 1,447
Interacting Carbon Nitride and Titanium Carbide Nanosheets for High‐Performance Oxygen Evolution
Ma, T. Y., Cao, J. L., Jaroniec, M., & Qiao, S. Z. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509758 · Cited by 733
Chen, K., Liu, K., An, P., Li, H., Lin, Y., Hu, J., Jia, C., Fu, J., Li, H., Liu, H., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-18062-y · Cited by 678
Self-citationZhang, Z., Sun, J., Wang, F., & Dai, L. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201804958 · Cited by 592
Metadata
- Authors
- Li, W., Yu, A., Higgins, D. C., Llanos, B. G., & Chen, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-12
- Volume
- 132
- Issue
- 48
- Pages
- 17056-17058
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2317156118
- Cited by
- 291
- References
- 2
- FWCI
- 6.67
- Type
- journal article
- Language
- en
- Open access
- closed
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