The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF3
Abstract
Scandium trifluoride maintains a cubic ReO(3) type structure down to at least 10 K, although the pressure at which its cubic to rhombohedral phase transition occurs drops from >0.5 GPa at ∼300 K to 0.1-0.2 GPa at 50 K. At low temperatures it shows strong negative thermal expansion (NTE) (60-110 K, α(l) ≈ -14 ppm K(-1)). On heating, its coefficient of thermal expansion (CTE) smoothly increases, leading to a room temperature CTE that is similar to that of ZrW(2)O(8) and positive thermal expansion above ∼1100 K. While the cubic ReO(3) structure type is often used as a simple illustration of how negative thermal expansion can arise from the thermally induced rocking of rigid structural units, ScF(3) is the first material with this structure to provide a clear experimental illustration of this mechanism for NTE.
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Cites
The classification of tilted octahedra in perovskites
Glazer, A. M. (1972) · Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry · doi:10.1107/s0567740872007976 · Cited by 3,901
Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW 2 O 8
Mary, T. A., Evans, J. S. O., Vogt, T., & Sleight, A. W. (1996) · Science · doi:10.1126/science.272.5258.90 · Cited by 1,584
Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides
Takenaka, K., & Takagi, H. (2005) · Applied Physics Letters · doi:10.1063/1.2147726 · Cited by 632
Negative thermal expansion materials †
Evans, J. S. O. (1999) · Journal of the Chemical Society, Dalton Transactions · doi:10.1039/a904297k · Cited by 601
Exceptional Negative Thermal Expansion in Isoreticular Metal–Organic Frameworks
Dubbeldam, D., Walton, K. S., Ellis, D. E., & Snurr, R. Q. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200700218 · Cited by 331
A versatile sample-environment cell for non-ambient X-ray scattering experiments
Chupas, P. J., Chapman, K. W., Kurtz, C., Hanson, J. C., Lee, P. L., & Grey, C. P. (2008) · Journal of Applied Crystallography · doi:10.1107/s0021889808020165 · Cited by 311
Self-citationNegative Thermal Expansion in the Metal–Organic Framework Material Cu3(1,3,5‐benzenetricarboxylate)2
Wu, Y., Kobayashi, A., Halder, G. J., Peterson, V. K., Chapman, K. W., Lock, N., Southon, P. D., & Kepert, C. J. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803925 · Cited by 304
Self-citationChapman, K. W., Chupas, P. J., & Kepert, C. J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060916r · Cited by 272
Self-citationThe widespread occurrence of negative thermal expansion in zeolites
Lightfoot, P., Woodcock, D. A., Maple, M. J., Villaescusa, L. A., & Wright, P. A. (2001) · Journal of Materials Chemistry · doi:10.1039/b002950p · Cited by 202
Hepworth, M. A., Jack, K. H., Peacock, R. D., & Westland, G. J. (1957) · Acta Crystallographica · doi:10.1107/s0365110x57000158 · Cited by 196
Metal−Organic Frameworks Provide Large Negative Thermal Expansion Behavior
Han, S. S., & Goddard, W. A. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp075389s · Cited by 189
Temperature-induced valence transition and associated lattice collapse in samarium fulleride
Arvanitidis, J., Papagelis, K., Margadonna, S., Prassides, K., & Fitch, A. N. (2003) · Nature · doi:10.1038/nature01994 · Cited by 168
The role of rigid unit modes in negative thermal expansion
Tao, J., & Sleight, A. W. (2003) · Journal of Solid State Chemistry · doi:10.1016/s0022-4596(03)00140-3 · Cited by 145
Chatterji, T. K., Henry, P. F., Mittal, R., et al. (2008) · Physical Review B · doi:10.1103/physrevb.78.134105 · Cited by 90
Polymorphism in NaSbO3: Structure and Bonding in Metal Oxides
Mizoguchi, H., Woodward, P. M., Byeon, S., & Parise, J. B. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038365h · Cited by 87
Daniel, P., Bulou, A., Rousseau, M., et al. (1990) · Physical review. B, Condensed matter · doi:10.1103/physrevb.42.10545 · Cited by 51
Powder X-ray diffraction study of the rhombohedral to cubic phase transition in TiF3
Kennedy, B. J., & Vogt, T. (2002) · Materials Research Bulletin · doi:10.1016/s0025-5408(01)00800-5 · Cited by 43
Cited by
Dynamic Stereochemical Activity of the Sn2+ Lone Pair in Perovskite CsSnBr3
Fabini, D. H., Laurita, G., Bechtel, J. S., Stoumpos, C. C., Evans, H. A., Kontos, A. G., Raptis, Y. S., Falaras, P., Van der Ven, A., Kanatzidis, M. G., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b06287 · Cited by 334
Dove, M. T., & Fang, H. (2016) · Reports on Progress in Physics · doi:10.1088/0034-4885/79/6/066503 · Cited by 313
First-principles study of phonon anharmonicity and negative thermal expansion in ScF 3
Oba, Y., Tadano, T., Akashi, R., & Tsuneyuki, S. (2019) · Physical Review Materials · doi:10.1103/physrevmaterials.3.033601 · Cited by 126
Metadata
- Authors
- Greve, B. K., Martin, K. L., Lee, P. L., Chupas, P. J., Chapman, K. W., & Wilkinson, A. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-19
- Volume
- 132
- Issue
- 44
- Pages
- 15496-15498
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2094890981
- Cited by
- 494
- References
- 17
- FWCI
- 4.17
- Type
- journal article
- Language
- en
- Open access
- closed
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