The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Strong Metal–Support Interactions between Gold Nanoparticles and ZnO Nanorods in CO Oxidation
Abstract
The catalytic performances of supported gold nanoparticles depend critically on the nature of support. Here, we report the first evidence of strong metal-support interactions (SMSI) between gold nanoparticles and ZnO nanorods based on results of structural and spectroscopic characterization. The catalyst shows encapsulation of gold nanoparticles by ZnO and the electron transfer between gold and the support. Detailed characterizations of the interaction between Au nanoparticles and ZnO were done with transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), electron paramagnetic resonance (EPR), and FTIR study of adsorbed CO. The significance of the SMSI effect is further investigated by probing the efficiency of CO oxidation over the Au/ZnO-nanorod. In contrast to the classical reductive SMSI in the TiO(2) supported group VIII metals which appears after high temperature reduction in H(2) with electron transfer from the support to metals, the oxidative SMSI in Au/ZnO-nanorod system gives oxygen-induced burial and electron transfer from gold to support. In CO oxidation, we found that the oxidative SMSI state is associated with positively charged gold nanoparticles with strong effect on its catalytic activity before and after encapsulation. The oxidative SMSI can be reversed by hydrogen treatment to induce AuZn alloy formation, de-encapsulation, and electron transfer from support to Au. Our discovery of the SMSI effects in Au/ZnO nanorods gives new understandings of the interaction between gold and support and provides new way to control the interaction between gold and the support as well as catalytic activity.
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Cites
ATHENA,ARTEMIS,HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT
Ravel, B., & Newville, M. (2005) · Journal of Synchrotron Radiation · doi:10.1107/s0909049505012719 · Cited by 16,965
Single-atom catalysis of CO oxidation using Pt1/FeOx
Qiao, B., Wang, A., Yang, X., Allard, L. F., Jiang, Z., Cui, Y., Liu, J., Li, J., & Zhang, T. (2011) · Nature Chemistry · doi:10.1038/nchem.1095 · Cited by 7,526
Size- and support-dependency in the catalysis of gold
Haruta, M. (1997) · Catalysis Today · doi:10.1016/s0920-5861(96)00208-8 · Cited by 4,123
Mechanisms behind green photoluminescence in ZnO phosphor powders
Vanheusden, K., Warren, W. L., Seager, C. H., Tallant, D. R., Voigt, J. A., & Gnade, B. E. (1996) · Journal of Applied Physics · doi:10.1063/1.362349 · Cited by 3,682
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C
Haruta, M., Kobayashi, T., Sano, H., & Yamada, N. (1987) · Chemistry Letters · doi:10.1246/cl.1987.405 · Cited by 3,162
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
Fu, Q., Saltsburg, H., & Flytzani-Stephanopoulos, M. (2003) · Science · doi:10.1126/science.1085721 · Cited by 2,954
The Structure of Catalytically Active Gold on Titania
Chen, M. S., & Goodman, D. W. (2004) · Science · doi:10.1126/science.1102420 · Cited by 1,620
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
Strong metal-support interactions
Tauster, S. J. (1987) · Accounts of Chemical Research · doi:10.1021/ar00143a001 · Cited by 1,473
Cited by
Parastaev, A., Muravev, V., Huertas Osta, E., van Hoof, A. J. F., Kimpel, T. F., Kosinov, N., & Hensen, E. J. M. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0459-4 · Cited by 613
Strong Metal–Support Interactions between Pt Single Atoms and TiO2
Han, B., Guo, Y., Huang, Y., Xi, W., Xu, J., Luo, J., Qi, H., Ren, Y., Liu, X., Qiao, B., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202003208 · Cited by 586
Self-citationLi, Y., Zhang, Y., Qian, K., & Huang, W. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c04854 · Cited by 538
Strong Metal–Support Interaction in Heterogeneous Catalysts
Luo, Z., Zhao, G., Pan, H., & Sun, W. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202201395 · Cited by 469
Wu, B., & Zheng, N. (2013) · Nano Today · doi:10.1016/j.nantod.2013.02.006 · Cited by 461
Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides
Tang, H., Wei, J., Liu, F., Qiao, B., Pan, X., Li, L., Liu, J., Wang, J., & Zhang, T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11306 · Cited by 458
Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis
Leybo, D., Etim, U. J., Monai, M., Bare, S. R., Zhong, Z., & Vogt, C. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00527a · Cited by 417
Xin, H., Lin, L., Li, R., Li, D., Song, T., Mu, R., Fu, Q., & Bao, X. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c12603 · Cited by 403
Essential Role of the Support for Nickel-Based CO2 Methanation Catalysts
Shen, L., Xu, J., Zhu, M., & Han, Y.-F. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03471 · Cited by 386
New Strategies for the Preparation of Sinter‐Resistant Metal‐Nanoparticle‐Based Catalysts
Wang, L., Wang, L., Meng, X., & Xiao, F. (2019) · Advanced Materials · doi:10.1002/adma.201901905 · Cited by 384
Tuning/exploiting Strong Metal-Support Interaction (SMSI) in Heterogeneous Catalysis
Pan, C.-J., Tsai, M.-C., Su, W.-N., Rick, J., Akalework, N. G., Agegnehu, A. K., Cheng, S.-Y., & Hwang, B.-J. (2017) · Journal of the Taiwan Institute of Chemical Engineers · doi:10.1016/j.jtice.2017.02.012 · Cited by 366
Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions
Zhang, Y., Liu, J., Qian, K., Jia, A., Li, D., Shi, L., Hu, J., Zhu, J., & Huang, W. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101928 · Cited by 341
Defect engineering of ZnO: Review on oxygen and zinc vacancies
Gurylev, V., & Perng, T. P. (2021) · Journal of the European Ceramic Society · doi:10.1016/j.jeurceramsoc.2021.03.031 · Cited by 336
Wang, J., Li, K., Zhong, H., Xu, D., Wang, Z., Jiang, Z., Wu, Z., & Zhang, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201504358 · Cited by 323
Pu, T., Zhang, W., & Zhu, M. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202212278 · Cited by 304
Luo, L., Gong, Z., Xu, Y., Ma, J., Liu, H., Xing, J., & Tang, J. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c09141 · Cited by 298
Catalysis Chemistry of Dimethyl Ether Synthesis
Sun, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2014) · ACS Catalysis · doi:10.1021/cs500967j · Cited by 286
Pulsed Laser in Liquids Made Nanomaterials for Catalysis
Forsythe, R. C., Cox, C. P., Wilsey, M. K., & Müller, A. M. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01069 · Cited by 259
Yang, X., Li, Q., Lu, E., Wang, Z., Gong, X., Yu, Z., Guo, Y., Wang, L., Guo, Y., Zhan, W., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09662-4 · Cited by 257
Zhan, W., He, Q., Liu, X., Guo, Y., Wang, Y., Wang, L., Guo, Y., Borisevich, A. Y., Zhang, J., Lu, G., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10472 · Cited by 256
Self-citationle Saché, E., & Reina, T. R. (2022) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2021.100970 · Cited by 253
Ueda, T., Oide, N., Kamada, K., Hyodo, T., & Shimizu, Y. (2022) · ECS Sensors Plus · doi:10.1149/2754-2726/ac63d2 · Cited by 84
Strong Metal‐Support Interactions through Sulfur‐Anchoring of Metal Catalysts on Carbon Supports
Yin, P., Yan, Q., & Liang, H. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202302819 · Cited by 80
Chen, K., Wang, Z., Wang, L., Wu, X., Hu, B., Liu, Z., & Wu, M. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00662-y · Cited by 77
Metadata
- Authors
- Liu, X., Liu, M.-H., Luo, Y.-C., Mou, C.-Y., Lin, S. D., Cheng, H., Chen, J.-M., Lee, J.-F., & Lin, T.-S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-01
- Volume
- 134
- Issue
- 24
- Pages
- 10251-10258
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313538464
- Cited by
- 658
- References
- 44
- FWCI
- 12.74
- Type
- journal article
- Language
- en
- Open access
- closed
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