The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
A Rechargeable Li–O2 Battery Using a Lithium Nitrate/N,N-Dimethylacetamide Electrolyte
Abstract
A major challenge in the development of rechargeable Li-O(2) batteries is the identification of electrolyte materials that are stable in the operating environment of the O(2) electrode. Straight-chain alkyl amides are one of the few classes of polar, aprotic solvents that resist chemical degradation in the O(2) electrode, but these solvents do not form a stable solid-electrolyte interphase (SEI) on the Li anode. The lack of a persistent SEI leads to rapid and sustained solvent decomposition in the presence of Li metal. In this work, we demonstrate for the first time successful cycling of a Li anode in the presence of the solvent, N,N-dimethylacetamide (DMA), by employing a salt, lithium nitrate (LiNO(3)), that stabilizes the SEI. A Li-O(2) cell containing this electrolyte composition is shown to cycle for more than 2000 h (>80 cycles) at a current density of 0.1 mA/cm(2) with a consistent charging profile, good capacity retention, and O(2) detected as the primary gaseous product formed during charging. The discovery of an electrolyte system that is compatible with both electrodes in a Li-O(2) cell may eliminate the need for protecting the anode with a ceramic membrane.
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Citations
Cites
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries
Aurbach, D., Pollak, E., Elazari, R., Salitra, G., Kelley, C. S., & Affinito, J. (2009) · Journal of The Electrochemical Society · doi:10.1149/1.3148721 · Cited by 1,443
Reactions in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes
Freunberger, S. A., Chen, Y., Peng, Z., Griffin, J. M., Hardwick, L. J., Bardé, F., Novák, P., & Bruce, P. G. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2021747 · Cited by 1,270
The Lithium–Oxygen Battery with Ether‐Based Electrolytes
Freunberger, S. A., Chen, Y., Drewett, N. E., Hardwick, L. J., Bardé, F., & Bruce, P. G. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102357 · Cited by 1,099
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O2 Batteries
McCloskey, B. D., Speidel, A., Scheffler, R., Miller, D. C., Viswanathan, V., Hummelshøj, J. S., Nørskov, J. K., & Luntz, A. C. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz300243r · Cited by 1,073
Solvents’ Critical Role in Nonaqueous Lithium–Oxygen Battery Electrochemistry
McCloskey, B. D., Bethune, D. S., Shelby, R. M., Girishkumar, G., & Luntz, A. C. (2011) · The Journal of Physical Chemistry Letters · doi:10.1021/jz200352v · Cited by 1,010
Screening for Superoxide Reactivity in Li-O2 Batteries: Effect on Li2O2/LiOH Crystallization
Black, R., Oh, S. H., Lee, J.-H., Yim, T., Adams, B., & Nazar, L. F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2111543 · Cited by 695
Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte
Liang, X. M., Wen, Z., Liu, Y., Wu, M., Jin, J. H., Zhang, H., & Wu, X. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.08.027 · Cited by 506
Li–O2 Battery with a Dimethylformamide Electrolyte
Chen, Y., Freunberger, S. A., Peng, Z., Bardé, F., & Bruce, P. G. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302178w · Cited by 387
Bryantsev, V. S., Giordani, V., Walker, W., Blanco, M., Zecevic, S., Sasaki, K., Uddin, J., Addison, D., & Chase, G. V. (2011) · The Journal of Physical Chemistry A · doi:10.1021/jp2073914 · Cited by 355
Self-citationThe Identification of Stable Solvents for Nonaqueous Rechargeable Li-Air Batteries
Bryantsev, V. S., Uddin, J., Giordani, V., Walker, W., Addison, D., & Chase, G. V. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.027302jes · Cited by 194
Self-citation
Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z.-L., Xu, D., Xu, J.-J., & Zhang, X.-B. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60248f · Cited by 1,447
Lithium–Oxygen Batteries and Related Systems: Potential, Status, and Future
Kwak, W.-J., Rosy, Sharon, D., Xia, C., Kim, H., Johnson, L. R., Bruce, P. G., Nazar, L. F., Sun, Y.-K., Frimer, A. A., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00609 · Cited by 1,009
Nonaqueous Li–Air Batteries: A Status Report
Luntz, A. C., & McCloskey, B. D. (2014) · Chemical Reviews · doi:10.1021/cr500054y · Cited by 925
Progress of enhancing the safety of lithium ion battery from the electrolyte aspect
Wang, Q., Jiang, L., Yu, Y., & Sun, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2018.10.035 · Cited by 915
Metadata
- Authors
- Walker, W., Giordani, V., Uddin, J., Bryantsev, V. S., Chase, G. V., & Addison, D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-02-01
- Volume
- 135
- Issue
- 6
- Pages
- 2076-2079
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2328301981
- Cited by
- 355
- References
- 11
- FWCI
- 18.37
- Type
- journal article
- Language
- en
- Open access
- closed
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