The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Metal–Organic-Frameworks-Derived General Formation of Hollow Structures with High Complexity
Abstract
Increasing the complexity of hollow structures, in terms of chemical composition and shell architecture, is highly desirable for both fundamental studies and realization of various functionalities. Starting with metal-organic frameworks (MOFs), we demonstrate a general approach toward the large-scale and facile synthesis of complex hollow microboxes via manipulation of the template-engaged reactions between the Prussian blue (PB) template and different alkaline substances. The reaction between PB microcubes with NaOH solution leads to the formation of Fe(OH)3 microboxes with controllable multishelled structure. In addition, PB microcubes will react with the conjugate bases of metal oxide based weak acids, generating multicompositional microboxes (Fe2O3/SnO2, Fe2O3/SiO2, Fe2O3/GeO2, Fe2O3/Al2O3, and Fe2O3/B2O3), which consist of uniformly dispersed oxides/hydroxides of iron and another designed element. Such complex hollow structures and atomically integrated multiple compositions might bring the usual physiochemical properties. As an example, we demonstrate that these complex hollow microboxes, especially the Fe2O3/SnO2 composite microboxes, exhibit remarkable electrochemical performance as anode materials for lithium ion batteries.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., & Tarascon, J.-M. (2000) · Nature · doi:10.1038/35035045 · Cited by 8,041
Shape-Controlled Synthesis of Gold and Silver Nanoparticles
Sun, Y., & Xia, Y. (2002) · Science · doi:10.1126/science.1077229 · Cited by 6,506
Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating
Caruso, F., Caruso, R. A., & Möhwald, H. (1998) · Science · doi:10.1126/science.282.5391.1111 · Cited by 4,135
Formation of hollow nanocrystals through the nanoscale kirkendall \neffect
Yin, Y., Rioux, R. M., Erdonmez, C. K., Hughes, S. M., Somorjai, G. A., & Alivisatos, A. P. (2004) · eScholarship (California Digital Library) · Cited by 3,537
Hollow Micro‐/Nanostructures: Synthesis and Applications
Lou, X. W. (., Archer, L. A., & Yang, Z. (2008) · Advanced Materials · doi:10.1002/adma.200800854 · Cited by 2,992
Self-citationTin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material
Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., & Miyasaka, T. (1997) · Science · doi:10.1126/science.276.5317.1395 · Cited by 2,578
Cation Exchange Reactions in Ionic Nanocrystals
Son, D. H., Hughes, S. M., Yin, Y., & Paul Alivisatos, A. (2004) · Science · doi:10.1126/science.1103755 · Cited by 1,277
The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O
Buser, H. J., Schwarzenbach, D., Petter, W., & Ludi, A. (1977) · Inorganic Chemistry · doi:10.1021/ic50177a008 · Cited by 1,015
Zhang, L., Wu, H. B., Madhavi, S., Hng, H. H., & Lou, X. W. (. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307475c · Cited by 984
Self-citationFacile synthesis of Ag nanocubes and Au nanocages
Skrabalak, S. E., Au, L., Li, X., & Xia, Y. (2007) · Nature Protocols · doi:10.1038/nprot.2007.326 · Cited by 972
Hollow Micro/Nanomaterials with Multilevel Interior Structures
Zhao, Y., & Jiang, L. (2009) · Advanced Materials · doi:10.1002/adma.200803645 · Cited by 654
Carving at the Nanoscale: Sequential Galvanic Exchange and Kirkendall Growth at Room Temperature
González, E., Arbiol, J., & Puntes, V. F. (2011) · Science · doi:10.1126/science.1212822 · Cited by 628
Ameloot, R., Vermoortele, F., Vanhove, W., Roeffaers, M. B. J., Sels, B. F., & De Vos, D. E. (2011) · Nature Chemistry · doi:10.1038/nchem.1026 · Cited by 574
Template Synthesis of Multishelled Cu2O Hollow Spheres with a Single‐Crystalline Shell Wall
Xu, H., & Wang, W. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200603895 · Cited by 498
Zhou, W., Cheng, C., Liu, J., Tay, Y. Y., Jiang, J., Jia, X., Zhang, J., Gong, H., Hng, H. H., Yu, T., et al. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201100088 · Cited by 460
Self‐Construction of Hollow SnO2 Octahedra Based on Two‐Dimensional Aggregation of Nanocrystallites
Yang, H. G., & Zeng, H. C. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200461129 · Cited by 439
Sun, Y., Wiley, B., Li, Z.-Y., & Xia, Y. (2004) · Journal of the American Chemical Society · doi:10.1021/ja048789r · Cited by 422
Fabrication of hollow porous shells of calcium carbonate from self-organizing media
Walsh, D., & Mann, S. (1995) · Nature · doi:10.1038/377320a0 · Cited by 417
Formation of SnO2 Hollow Nanospheres inside Mesoporous Silica Nanoreactors
Ding, S., Chen, J. S., Qi, G., Duan, X., Wang, Z., Giannelis, E. P., Archer, L. A., & Lou, X. W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja108720w · Cited by 399
Self-citationA general phase-transfer protocol for metal ions and its application in nanocrystal synthesis
Yang, J., Sargent, E., Kelley, S., & Ying, J. Y. (2009) · Nature Materials · doi:10.1038/nmat2490 · Cited by 373
Marinakos, S. M., Novak, J. P., Brousseau, L. C., House, A. B., Edeki, E. M., Feldhaus, J. C., & Feldheim, D. L. (1999) · Journal of the American Chemical Society · doi:10.1021/ja990945k · Cited by 335
Tailored Design of Multiple Nanoarchitectures in Metal-Cyanide Hybrid Coordination Polymers
Hu, M., Belik, A. A., Imura, M., & Yamauchi, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja3096703 · Cited by 252
Synthesis of Uniform Hollow Oxide Nanoparticles through Nanoscale Acid Etching
An, K., Kwon, S. G., Park, M., Na, H. B., Baik, S.-I., Yu, J. H., Kim, D., Son, J. S., Kim, Y. W., Song, I. C., et al. (2008) · Nano Letters · doi:10.1021/nl8019467 · Cited by 226
Chen, J. S., Li, C. M., Zhou, W. W., Yan, Q. Y., Archer, L. A., & Lou, X. W. (2009) · Nanoscale · doi:10.1039/b9nr00102f · Cited by 207
Self-citationSerial Ionic Exchange for the Synthesis of Multishelled Copper Sulfide Hollow Spheres
Xiong, S., & Zeng, H. C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201106826 · Cited by 196
Multi Ball‐In‐Ball Hybrid Metal Oxides
Cho, W., Lee, Y. H., Lee, H. J., & Oh, M. (2011) · Advanced Materials · doi:10.1002/adma.201004493 · Cited by 153
Zhang, N., Ouyang, S., Li, P., et al. (2011) · Chemical Communications · doi:10.1039/c0cc04687f · Cited by 122
A General Single‐Source Route for the Preparation of Hollow Nanoporous Metal Oxide Structures
Wang, L., Tang, F., Ozawa, K., Chen, Z., Mukherj, A., Zhu, Y., Zou, J., Cheng, H., & Lu, G. Q. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200900539 · Cited by 121
Cited by
Synthesis, Properties, and Applications of Hollow Micro-/Nanostructures
Wang, X., Feng, J., Bai, Y., Zhang, Q., & Yin, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00731 · Cited by 1,456
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Self-citationGuan, B. Y., Yu, X. Y., Wu, H. B., & Lou, X. W. (. (2017) · Advanced Materials · doi:10.1002/adma.201703614 · Cited by 733
Self-citationHan, L., Yu, X., & Lou, X. W. (. (2016) · Advanced Materials · doi:10.1002/adma.201506315 · Cited by 633
Self-citationSu, J., Ge, R., Jiang, K., Dong, Y., Hao, F., Tian, Z., Chen, G., & Chen, L. (2018) · Advanced Materials · doi:10.1002/adma.201801351 · Cited by 544
Metadata
- Authors
- Zhang, L., Wu, H. B., & Lou, X. W. (.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-12
- Volume
- 135
- Issue
- 29
- Pages
- 10664-10672
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2328939392
- Cited by
- 580
- References
- 29
- FWCI
- 29.38
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
