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Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
Open accessAbstract
Herein we report a metal-free method for the direct anti-Markovnikov hydroamination of unsaturated amines. Irradiation of the amine substrates with visible light in the presence of catalytic quantities of easily synthesized 9-mesityl-10-methylacridinium tetrafluoroborate and thiophenol as a hydrogen-atom donor furnished the nitrogen-containing heterocycles with complete regiocontrol. Two examples of intermolecular anti-Markovnikov alkene hydroamination are also disclosed.
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Cited by
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Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
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Matsui, J. K., Primer, D. N., & Molander, G. A. (2017) · Chemical Science · doi:10.1039/c7sc00283a · Cited by 284
Wang, Z. J., Ghasimi, S., Landfester, K., & Zhang, K. A. I. (2015) · Advanced Materials · doi:10.1002/adma.201502735 · Cited by 278
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Metadata
- Authors
- Nguyen, T. M., & Nicewicz, D. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-19
- Volume
- 135
- Issue
- 26
- Pages
- 9588-9591
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2074545790
- Cited by
- 331
- References
- 0
- FWCI
- 14.01
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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