The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Core-Shell Nanostructured “Black” Rutile Titania as Excellent Catalyst for Hydrogen Production Enhanced by Sulfur Doping
Abstract
Modification of rutile titanium dioxide (TiO2) for hydrogen generation and water cleaning is a grand challenge due to the chemical inertness of rutile, while such inertness is a desired merit for its stability in photoelectrochemical applications. Herein, we report an innovative two-step method to prepare a core-shell nanostructured S-doped rutile TiO2 (R'-TiO2-S). This modified black rutile TiO2 sample exhibits remarkably enhanced absorption in visible and near-infrared regions and efficient charge separation and transport. As a result, the unique sulfide surface (TiO(2-x):S) boosts the photocatalytic water cleaning and water splitting with a steady solar hydrogen production rate of 0.258 mmol h(-1) g(-1). The black titania is also an excellent photoelectrochemical electrode exhibiting a high solar-to-hydrogen conversion efficiency of 1.67%. The sulfided surface shell is proved to be an effective strategy for enhancing solar light absorption and photoelectric conversion.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Cited by
Engineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Defect engineering in photocatalytic materials
Bai, S., Zhang, N., Gao, C., & Xiong, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.08.058 · Cited by 1,236
Li, J., & Wu, N. (2015) · Catalysis Science & Technology · doi:10.1039/c4cy00974f · Cited by 1,068
Ordered Mesoporous Black TiO2 as Highly Efficient Hydrogen Evolution Photocatalyst
Zhou, W., Li, W., Wang, J.-Q., Qu, Y., Yang, Y., Xie, Y., Zhang, K., Wang, L., Fu, H., & Zhao, D. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504802q · Cited by 980
Recent Progress in Energy‐Driven Water Splitting
Tee, S. Y., Win, K. Y., Teo, W. S., Koh, L., Liu, S., Teng, C. P., & Han, M. (2017) · Advanced Science · doi:10.1002/advs.201600337 · Cited by 962
Li, L., Yan, J., Wang, T., Zhao, Z.-J., Zhang, J., Gong, J., & Guan, N. (2015) · Nature Communications · doi:10.1038/ncomms6881 · Cited by 847
Yang, W., Prabhakar, R. R., Tan, J., Tilley, S. D., & Moon, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00997j · Cited by 787
Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Production
Naldoni, A., Altomare, M., Zoppellaro, G., Liu, N., Kment, Š., Zbořil, R., & Schmuki, P. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04068 · Cited by 770
Progress in Developing Metal Oxide Nanomaterials for Photoelectrochemical Water Splitting
Yang, Y., Niu, S., Han, D., Liu, T., Wang, G., & Li, Y. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700555 · Cited by 655
Li, J., Cushing, S. K., Zheng, P., Senty, T., Meng, F., Bristow, A. D., Manivannan, A., & Wu, N. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503508g · Cited by 586
Li, J., Zhang, M., Guan, Z., Li, Q., He, C., & Yang, J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.01.025 · Cited by 503
Enhancing Catalytic Activity of Titanium Oxide in Lithium–Sulfur Batteries by Band Engineering
Wang, Y., Zhang, R., Chen, J., Wu, H., Lu, S., Wang, K., Li, H., Harris, C. J., Xi, K., Kumar, R. V., et al. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900953 · Cited by 447
Ye, M., Jia, J., Wu, Z., Qian, C., Chen, R., O'Brien, P. G., Sun, W., Dong, Y., & Ozin, G. A. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601811 · Cited by 417
Constructing Black Titania with Unique Nanocage Structure for Solar Desalination
Zhu, G., Xu, J., Zhao, W., & Huang, F. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b11466 · Cited by 357
Self-citationOxygen defective metal oxides for energy conversion and storage
Wang, G., Yang, Y., Han, D., & Li, Y. (2017) · Nano Today · doi:10.1016/j.nantod.2017.02.009 · Cited by 353
Black TiO2: A review of its properties and conflicting trends
Rajaraman, T. S., Parikh, S. P., & Gandhi, V. G. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123918 · Cited by 323
Su, K., Tan, L., Liu, X., Cui, Z., Zheng, Y., Li, B., Han, Y., Li, Z., Zhu, S., Liang, Y., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b08686 · Cited by 294
Thin film photoelectrodes for solar water splitting
He, Y., Hamann, T., & Wang, D. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00868j · Cited by 284
Zafar, Z., Yi, S., Li, J., Li, C., Zhu, Y., Zada, A., Yao, W., Liu, Z., & Yue, X. (2022) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12171 · Cited by 284
Advanced Catalysts for Photoelectrochemical Water Splitting
Marwat, M. A., Humayun, M., Afridi, M. W., Zhang, H., Abdul Karim, M. R., Ashtar, M., Usman, M., Waqar, S., Ullah, H., Wang, C., et al. (2021) · ACS Applied Energy Materials · doi:10.1021/acsaem.1c02548 · Cited by 191
Metadata
- Authors
- Yang, C., Wang, Z., Lin, T., Yin, H., Lü, X., Wan, D., Xu, T., Zheng, C., Lin, J., Huang, F., Xie, X., & Jiang, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-11-14
- Volume
- 135
- Issue
- 47
- Pages
- 17831-17838
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2084409156
- Cited by
- 474
- References
- 3
- FWCI
- 12.98
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
