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An Azine-Linked Covalent Organic Framework
Abstract
Condensation of hydrazine with 1,3,6,8-tetrakis(4-formylphenyl)pyrene under solvothermal conditions yields highly crystalline two-dimensional covalent organic frameworks. The pyrene units occupy the vertices and the diazabutadiene (-C═N-N═C-) linkers locate the edges of rohmbic-shaped polygon sheets, which further stack in an AA-stacking mode to constitute periodically ordered pyrene columns and one-dimensional microporous channels. The azine-linked frameworks feature permanent porosity with high surface area and exhibit outstanding chemical stability. By virtue of the pyrene columnar ordering, the azine-linked frameworks are highly luminescent, whereas the azine units serve as open docking sites for hydrogen-bonding interactions. These synergestic functions of the vertices and edge units endow the azine-linked pyrene frameworks with extremely high sensitivity and selectivity in chemosensing, for example, the selective detection of 2,4,6-trinitrophenol explosive. We anticipate that the extension of the present azine-linked strategy would not only increase the structural diversity but also expand the scope of functions based on this highly stable class of covalent organic frameworks.
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Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
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Sun, X., Wang, Y., & Lei, Y. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00496a · Cited by 1,243
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Self-citationPost-synthetic modification of covalent organic frameworks
Segura, J. L., Royuela, S., & Mar Ramos, M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00978c · Cited by 832
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Self-citationFan, H., Mundstock, A., Feldhoff, A., Knebel, A., Gu, J., Meng, H., & Caro, J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b05136 · Cited by 758
Zhang, F., Sheng, J., Yang, Z., Sun, X., Tang, H., Lu, M., Dong, H., Shen, F., Liu, J., & Lan, Y. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806862 · Cited by 719
Chen, R., Shi, J., Ma, Y., Lin, G., Lang, X., & Wang, C. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201902543 · Cited by 697
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Wang, J., & Zhuang, S. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213046 · Cited by 677
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Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
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Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
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Jiang, J., Zhao, Y., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10666 · Cited by 448
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Zou, L., Sun, Y., Che, S., Yang, X., Wang, X., Bosch, M., Wang, Q., Li, H., Smith, M., Yuan, S., et al. (2017) · Advanced Materials · doi:10.1002/adma.201700229 · Cited by 432
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Zhang, T., Xing, G., Chen, W., & Chen, L. (2020) · Materials Chemistry Frontiers · doi:10.1039/c9qm00633h · Cited by 420
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Skorjanc, T., Shetty, D., & Valant, M. (2021) · ACS Sensors · doi:10.1021/acssensors.1c00183 · Cited by 420
Polymer Networks: From Plastics and Gels to Porous Frameworks
Gu, Y., Zhao, J., & Johnson, J. A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201902900 · Cited by 388
Wan, Y., Wang, L., Xu, H., Wu, X., & Yang, J. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00564 · Cited by 363
Porous organic polymers as a platform for sensing applications
Wang, S., Li, H., Huang, H., Cao, X., Chen, X., & Cao, D. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00059h · Cited by 363
Fast Ion Transport Pathway Provided by Polyethylene Glycol Confined in Covalent Organic Frameworks
Guo, Z., Zhang, Y., Dong, Y., Li, J., Li, S., Shao, P., Feng, X., & Wang, B. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b13551 · Cited by 331
An Elastic Hydrogen-Bonded Cross-Linked Organic Framework for Effective Iodine Capture in Water
Lin, Y., Jiang, X., Kim, S. T., Alahakoon, S. B., Hou, X., Zhang, Z., Thompson, C. M., Smaldone, R. A., & Ke, C. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03204 · Cited by 319
Zhang, C., Zhang, S., Yan, Y., Xia, F., Huang, A., & Xian, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b16423 · Cited by 304
EL-Mahdy, A. F. M., Kuo, C.-H., Alshehri, A., Young, C., Yamauchi, Y., Kim, J., & Kuo, S.-W. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta04781b · Cited by 253
Metadata
- Authors
- Dalapati, S., Jin, S., Gao, J., Xu, Y., Nagai, A., & Jiang, D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-11-05
- Volume
- 135
- Issue
- 46
- Pages
- 17310-17313
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2317898558
- Cited by
- 924
- References
- 0
- FWCI
- 14.06
- Type
- journal article
- Language
- en
- Open access
- closed
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