The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Metal-Free Atom Transfer Radical Polymerization
Open accessAbstract
Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Significantly, block copolymer formation was facile and could be combined with other controlled radical processes leading to structural and synthetic versatility. We believe that these new organic-based photoredox catalysts will enable new applications for controlled radical polymerizations and also be of further value in both small molecule and polymer chemistry.
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Metadata
- Authors
- Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-31
- Volume
- 136
- Issue
- 45
- Pages
- 16096-16101
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1998350146
- Cited by
- 939
- References
- 34
- FWCI
- 33.24
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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