The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2to Methanol
Abstract
This Communication describes the hydrogenation of carbon dioxide to methanol via tandem catalysis with dimethylamine and a homogeneous ruthenium complex. Unlike previous examples with homogeneous catalysts, this CO2-to-CH3OH process proceeds under basic reaction conditions. The dimethylamine is proposed to play a dual role in this system. It reacts directly with CO2 to produce dimethylammonium dimethylcarbamate, and it also intercepts the intermediate formic acid to generate dimethylformamide. With the appropriate selection of catalyst and reaction conditions, >95% conversion of CO2 was achieved to form a mixture of CH3OH and dimethylformamide.
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Citations
Cites
Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program
Figueroa, J. D., Fout, T., Plasynski, S., McIlvried, H., & Srivastava, R. D. (2008) · International Journal of Greenhouse Gas Control · doi:10.1016/s1750-5836(07)00094-1 · Cited by 2,281
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
An overview of CO2 capture technologies
MacDowell, N., Florin, N., Buchard, A., Hallett, J., Galindo, A., Jackson, G., Adjiman, C. S., Williams, C. K., Shah, N., & Fennell, P. (2010) · Energy & Environmental Science · doi:10.1039/c004106h · Cited by 1,636
Cited by
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
He, Z., Qian, Q., Ma, J., Meng, Q., Zhou, H., Song, J., Liu, Z., & Han, B. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507585 · Cited by 313
Metadata
- Authors
- Rezayee, N. M., Huff, C. A., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-16
- Volume
- 137
- Issue
- 3
- Pages
- 1028-1031
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2064658006
- Cited by
- 461
- References
- 3
- FWCI
- 21.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rezayee, N. M., Huff, C. A., & Sanford, M. S. (2015). Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2to Methanol. Journal of the American Chemical Society. https://doi.org/10.1021/ja511329m
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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