The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2to Methanol
Abstract
This Communication describes the hydrogenation of carbon dioxide to methanol via tandem catalysis with dimethylamine and a homogeneous ruthenium complex. Unlike previous examples with homogeneous catalysts, this CO2-to-CH3OH process proceeds under basic reaction conditions. The dimethylamine is proposed to play a dual role in this system. It reacts directly with CO2 to produce dimethylammonium dimethylcarbamate, and it also intercepts the intermediate formic acid to generate dimethylformamide. With the appropriate selection of catalyst and reaction conditions, >95% conversion of CO2 was achieved to form a mixture of CH3OH and dimethylformamide.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Advances in CO2 capture technology—The U.S. Department of Energy's Carbon Sequestration Program
Figueroa, J. D., Fout, T., Plasynski, S., McIlvried, H., & Srivastava, R. D. (2008) · International Journal of Greenhouse Gas Control · doi:10.1016/s1750-5836(07)00094-1 · Cited by 2,281
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
An overview of CO2 capture technologies
MacDowell, N., Florin, N., Buchard, A., Hallett, J., Galindo, A., Jackson, G., Adjiman, C. S., Williams, C. K., Shah, N., & Fennell, P. (2010) · Energy & Environmental Science · doi:10.1039/c004106h · Cited by 1,636
Cited by
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Li-CO2 Electrochemistry: A New Strategy for CO2 Fixation and Energy Storage
Qiao, Y., Yi, J., Wu, S., Liu, Y., Yang, S., He, P., & Zhou, H. (2017) · Joule · doi:10.1016/j.joule.2017.07.001 · Cited by 490
Highly Efficient Ruthenium‐Catalyzed N‐Formylation of Amines with H2 and CO2
Zhang, L., Han, Z., Zhao, X., Wang, Z., & Ding, K. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201500939 · Cited by 357
He, Z., Qian, Q., Ma, J., Meng, Q., Zhou, H., Song, J., Liu, Z., & Han, B. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507585 · Cited by 313
Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
Kar, S., Goeppert, A., Kothandaraman, J., & Prakash, G. K. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02066 · Cited by 258
Metadata
- Authors
- Rezayee, N. M., Huff, C. A., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-16
- Volume
- 137
- Issue
- 3
- Pages
- 1028-1031
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2064658006
- Cited by
- 461
- References
- 3
- FWCI
- 21.44
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
