The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Tandem Amine and Ruthenium-Catalyzed Hydrogenation of CO2to Methanol
Abstract
This Communication describes the hydrogenation of carbon dioxide to methanol via tandem catalysis with dimethylamine and a homogeneous ruthenium complex. Unlike previous examples with homogeneous catalysts, this CO2-to-CH3OH process proceeds under basic reaction conditions. The dimethylamine is proposed to play a dual role in this system. It reacts directly with CO2 to produce dimethylammonium dimethylcarbamate, and it also intercepts the intermediate formic acid to generate dimethylformamide. With the appropriate selection of catalyst and reaction conditions, >95% conversion of CO2 was achieved to form a mixture of CH3OH and dimethylformamide.
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Cites
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Conversion of CO2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst
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Li-CO2 Electrochemistry: A New Strategy for CO2 Fixation and Energy Storage
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Highly Efficient Ruthenium‐Catalyzed N‐Formylation of Amines with H2 and CO2
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Catalytic reduction of CO2into fuels and fine chemicals
Modak, A., Bhanja, P., Dutta, S., Chowdhury, B., & Bhaumik, A. (2020) · Green Chemistry · doi:10.1039/d0gc01092h · Cited by 267
Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
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Metadata
- Authors
- Rezayee, N. M., Huff, C. A., & Sanford, M. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-01-16
- Volume
- 137
- Issue
- 3
- Pages
- 1028-1031
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2064658006
- Cited by
- 461
- References
- 48
- FWCI
- 21.44
- Type
- journal article
- Language
- en
- Open access
- closed
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