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para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property
Abstract
Condensation of 1,4-dimethoxybenzene (DMB) with paraformaldehyde in the presence of BF3.O(C2H5)2 gave novel para-bridged pentacyclic pillar DMB (DMpillar[5]arene). Moreover, para-bridged pentacyclic hydroquinone (pillar[5]arene) was prepared. Pillar[5]arene formed 1:1 host-guest complexes with dialkyl viologen and alkyl pyridinium derivatives. However, pillar[5]arene did not form complexes with the diadamantyl viologen derivative since a bulky adamantyl group was unable to thread the cavity of pillar[5]arene.
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Metadata
- Authors
- Ogoshi, T., Kanai, S., Fujinami, S., Yamagishi, T.-A., & Nakamoto, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-22
- Volume
- 130
- Issue
- 15
- Pages
- 5022-5023
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2088252867
- Cited by
- 2,200
- References
- 0
- FWCI
- 9.08
- Type
- journal article
- Language
- en
- Open access
- closed
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