The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Hydrolysis of Cellulose by Amorphous Carbon Bearing SO3H, COOH, and OH Groups
Abstract
The hydrolysis of cellulose into saccharides using a range of solid catalysts is investigated for potential application in the environmentally benign saccharification of cellulose. Crystalline pure cellulose is not hydrolyzed by conventional strong solid Brønsted acid catalysts such as niobic acid, H-mordenite, Nafion and Amberlyst-15, whereas amorphous carbon bearing SO 3H, COOH, and OH function as an efficient catalyst for the reaction. The apparent activation energy for the hydrolysis of cellulose into glucose using the carbon catalyst is estimated to be 110 kJ mol (-1), smaller than that for sulfuric acid under optimal conditions (170 kJ mol (-1)). The carbon catalyst can be readily separated from the saccharide solution after reaction for reuse in the reaction without loss of activity. The catalytic performance of the carbon catalyst is attributed to the ability of the material to adsorb beta-1,4 glucan, which does not adsorb to other solid acids.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Interpretation of Raman spectra of disordered and amorphous carbon
Ferrari, A. C., & Robertson, J. (2000) · Physical Review B · doi:10.1103/physrevb.61.14095 · Cited by 15,651
Spectrometric Identification of Organic Compounds
Silverstein, R. M., & Bassler, G. C. (1962) · Journal of Chemical Education · doi:10.1021/ed039p546 · Cited by 14,272
The Path Forward for Biofuels and Biomaterials
Ragauskas, A. J., Williams, C. K., Davison, B. H., Britovsek, G., Cairney, J., Eckert, C. A., Frederick, W. J., Hallett, J. P., Leak, D. J., Liotta, C. L., et al. (2006) · Science · doi:10.1126/science.1114736 · Cited by 5,741
Zhang, Y. P., & Lynd, L. R. (2004) · Biotechnology and Bioengineering · doi:10.1002/bit.20282 · Cited by 1,893
Bio-ethanol – the fuel of tomorrow from the residues of today
Hahn-Hägerdal, B., Galbe, M., Gorwa-Grauslund, M. F., Lidén, G., & Zacchi, G. (2006) · Trends in Biotechnology · doi:10.1016/j.tibtech.2006.10.004 · Cited by 1,513
Water-Tolerant Solid Acid Catalysts
Okuhara, T. (2002) · Chemical Reviews · doi:10.1021/cr0103569 · Cited by 1,165
Biodiesel made with sugar catalyst
Toda, M., Takagaki, A., Okamura, M., Kondo, J. N., Hayashi, S., Domen, K., & Hara, M. (2005) · Nature · doi:10.1038/438178a · Cited by 823
Self-citationCatalytic Conversion of Cellulose into Sugar Alcohols
Fukuoka, A., & Dhepe, P. L. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200601921 · Cited by 761
Dissolution and Hydrolysis of Cellulose in Subcritical and Supercritical Water
Sasaki, M., Fang, Z., Fukushima, Y., Adschiri, T., & Arai, K. (2000) · Industrial & Engineering Chemistry Research · doi:10.1021/ie990690j · Cited by 691
Solid Acids for Green Chemistry
Clark, J. H. (2002) · Accounts of Chemical Research · doi:10.1021/ar010072a · Cited by 665
A Carbon Material as a Strong Protonic Acid
Hara, M., Yoshida, T., Takagaki, A., Takata, T., Kondo, J. N., Hayashi, S., & Domen, K. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200453947 · Cited by 579
Self-citationAcid-Catalyzed Reactions on Flexible Polycyclic Aromatic Carbon in Amorphous Carbon
Okamura, M., Takagaki, A., Toda, M., Kondo, J. N., Domen, K., Tatsumi, T., Hara, M., & Hayashi, S. (2006) · Chemistry of Materials · doi:10.1021/cm0605623 · Cited by 570
Self-citationKinetic Study on the Acid-Catalyzed Hydrolysis of Cellulose to Levulinic Acid
Girisuta, B., Janssen, L. P. B. M., & Heeres, H. J. (2007) · Industrial & Engineering Chemistry Research · doi:10.1021/ie061186z · Cited by 501
Buzzoni, R., Bordiga, S., Ricchiardi, G., Spoto, G., & Zecchina, A. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100031a023 · Cited by 267
Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas
Dhepe, P. L., Ohashi, M., Inagaki, S., Ichikawa, M., & Fukuoka, A. (2005) · Catalysis Letters · doi:10.1007/s10562-005-5850-x · Cited by 142
Development of the Scholler Process in the United States
Faith, W. L. (1945) · Industrial & Engineering Chemistry · doi:10.1021/ie50421a004 · Cited by 99
Harris, E. E., & Beglinger, E. (1946) · Industrial & Engineering Chemistry · doi:10.1021/ie50441a012 · Cited by 93
Review of Processes in the United States Prior to World War II
Sherrard, E. C., & Kressman, F. W. (1945) · Industrial & Engineering Chemistry · doi:10.1021/ie50421a003 · Cited by 72
Cited by
Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels
Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., & Beltramini, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15124j · Cited by 1,420
Hydrogenolysis Goes Bio: From Carbohydrates and Sugar Alcohols to Platform Chemicals
Ruppert, A. M., Weinberg, K., & Palkovits, R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201105125 · Cited by 836
Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass
Kobayashi, H., & Fukuoka, A. (2013) · Green Chemistry · doi:10.1039/c3gc00060e · Cited by 489
Advances on biomass pretreatment using ionic liquids: An overview
Tadesse, H., & Luque, R. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00667j · Cited by 434
Heterogeneous Catalysis for Tandem Reactions
Climent, M. J., Corma, A., Iborra, S., & Sabater, M. J. (2014) · ACS Catalysis · doi:10.1021/cs401052k · Cited by 361
Metadata
- Authors
- Suganuma, S., Nakajima, K., Kitano, M., Yamaguchi, D., Kato, H., Hayashi, S., & Hara, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-08-29
- Volume
- 130
- Issue
- 38
- Pages
- 12787-12793
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1976708215
- Cited by
- 1,020
- References
- 18
- FWCI
- 25.79
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
