Cited by 434Biofuel production and bioconversionIonic liquids properties and applicationsCatalysis for Biomass Conversion

Advances on biomass pretreatment using ionic liquids: An overview

Tadesse, Haregewine, Luque, Rafael·2011·Energy & Environmental Science

Abstract

Petroleum is currently being used as a major source for chemicals, materials, and fuels, but poses major concerns in terms of its future utilisation due to resource limitation, increasing costs and associated environmental issues. An alternative raw material for chemicals and biofuels production is lignocellulosic biomass. The conversion of biomass to biofuels begins with biomass pretreatment in which chemical and/or physical treatments are utilised to remove or weaken the tight linkages among cell-wall components, making biomass easier to degrade. The use of ionic liquids–salts (mixtures of cations and anions that melt below 100 °C) has been described as a new potentially viable development in this area due to the increasing interest in the use of such compounds to pretreat lignocellulosic materials and to catalyse the dissolution of cellulose. This manuscript aims to provide an overview on the major representative progress and development of the use of ionic liquids systems for biomass pretreatment and cellulose dissolution. A comparison of the environmental impact of different ionic liquids for the conversion of carbohydrates into useful biofuel intermediates will be described, with their inherent advantages for biomass valorisation processes in terms of unique and tuneable physico-chemical properties.

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Crossref · 10.1039/c0ee00667j

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162 of 162 references verified0 citation errors · 0 not checkable

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  • The lignin crust is one of the major obstacles for an energy-efficient biomass deconstruction process.

    “The lignin crust has been identified as one of the major obstacles for an energy-efficient biomass deconstruction process.8”
  • Deconstruction of lignocellulose is likely to account for an important fraction of the energy requirement for biomass processing.

    “The deconstruction of lignocellulose is likely to account for an important fraction of the energy requirement for biomass processing.8”

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Authors
Tadesse, H., & Luque, R.
Affiliations
  • Environmental Protection Agency (US)
  • University of Córdoba (ES)
Corresponding author
  • Tadesse, Haregewine
  • Luque, Rafael
Venue
Energy & Environmental Science
Published
2011
Volume
4
Issue
10
Pages
3913
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W1973515306
Cited by
434
References
162
Citations by year
2026: 7 · 2025: 17 · 2024: 15 · 2023: 16 · 2022: 22 · 2021: 23 · 2020: 43 · 2019: 31 · 2018: 38 · 2017: 30 · 2016: 38 · 2015: 36 · 2014: 43 · 2013: 37 · 2012: 35
FWCI
22.32
Type
journal article
Language
en
Open access
closed
Locations
Energy & Environmental Science (publishedVersion)
Topics
  • Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
  • Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
  • Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
Keywords
ionic liquids, biomass pretreatment, lignocellulosic biomass, cellulose dissolution, biofuels, carbohydrate conversion, biomass valorization, cell wall degradation

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