The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Selective Ion Passage through Functionalized Graphene Nanopores
Abstract
We design functionalized nanopores in graphene monolayers and show by molecular dynamics simulations that they provide highly selective passage of hydrated ions. Only ions that can be partly stripped of their hydration shells can pass through these ultrasmall pores with diameters of ∼5 Å. For example, a fluorine−nitrogen-terminated pore allows the passage of Li +, Na +, and K + cations with the ratio 9:14:33, but it blocks the passage of anions. The hydrogen-terminated pore allows the passage of F −, Cl −, and Br − anions with the ratio 0:17:33, but it blocks the passage of cations. These nanopores could have potential applications in molecular separation, desalination, and energy storage systems.
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Self-citation
Cited by
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Metadata
- Authors
- Sint, K., Wang, B., & Král, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-14
- Volume
- 130
- Issue
- 49
- Pages
- 16448-16449
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2059611774
- Cited by
- 624
- References
- 23
- FWCI
- 7.46
- Type
- journal article
- Language
- en
- Open access
- closed
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