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Selective Synthesis of Co3O4 Nanocrystal with Different Shape and Crystal Plane Effect on Catalytic Property for Methane Combustion
Abstract
We have succeeded in synthesizing Co(3)O(4) nanosheets, nanobelts, and nanocubes with a hydrothermal process of cobalt hydroxide precursor and subsequent direct thermal decomposition. The predominantly exposed planes are {112}, {011}, and {001}, respectively. The methane combustion catalytic activity order of crystal planes follows {112} > {011} >> {001}. The selective synthesis of transition metal oxides with uniform and different reactive crystal planes under nanoscale conditions is expected to bring up new opportunities for design, tuning, and control of chemical activity, specificity, and selectivity.
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Citations
Cites
Chemistry and Properties of Nanocrystals of Different Shapes
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Metadata
- Authors
- Hu, L., Peng, Q., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-08
- Volume
- 130
- Issue
- 48
- Pages
- 16136-16137
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2074124696
- Cited by
- 948
- References
- 2
- FWCI
- 17.01
- Type
- journal article
- Language
- en
- Open access
- closed
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