The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Surface Structure Dependent Electrocatalytic Activity of Co3O4 Anchored on Graphene Sheets toward Oxygen Reduction Reaction
Open accessAbstract
Catalytic activity is primarily a surface phenomenon, however, little is known about Co 3 O 4 nanocrystals in terms of the relationship between the oxygen reduction reaction (ORR) catalytic activity and surface structure, especially when dispersed on a highly conducting support to improve the electrical conductivity and so to enhance the catalytic activity. Herein, we report a controllable synthesis of Co 3 O 4 nanorods (NR), nanocubes (NC) and nano-octahedrons (OC) with the different exposed nanocrystalline surfaces ({110}, {100} and {111}), uniformly anchored on graphene sheets, which has allowed us to investigate the effects of the surface structure on the ORR activity. Results show that the catalytically active sites for ORR should be the surface Co 2+ ions, whereas the surface Co 3+ ions catalyze CO oxidation and the catalytic ability is closely related to the density of the catalytically active sites. These results underscore the importance of morphological control in the design of highly efficient ORR catalysts.
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In Operando Identification of Geometrical-Site-Dependent Water Oxidation Activity of Spinel Co3O4
Wang, H.-Y., Hung, S.-F., Chen, H.-Y., Chan, T.-S., Chen, H. M., & Liu, B. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10525 · Cited by 1,120
A review on detection of heavy metal ions in water—An electrochemical approach
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Metal–organic framework composites and their electrochemical applications
Xue, Y., Zheng, S., Xue, H., & Pang, H. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta12178h · Cited by 389
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Metadata
- Authors
- Xiao, J., Kuang, Q., Yang, S., Xiao, F., Wang, S., & Guo, L.
- Venue
- Scientific Reports
- Published
- 2013-07-29
- Volume
- 3
- Issue
- 1
- Pages
- 2300-2300
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2002176920
- Cited by
- 332
- References
- 32
- FWCI
- 10.46
- Type
- journal article
- Language
- en
- Open access
- gold
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- Xiao, J., Kuang, Q., Yang, S., Xiao, F., Wang, S., & Guo, L. (2013). Surface Structure Dependent Electrocatalytic Activity of Co3O4 Anchored on Graphene Sheets toward Oxygen Reduction Reaction. Scientific Reports. https://doi.org/10.1038/srep02300
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