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Columnar Structure in Bulk Heterojunction in Solution-Processable Three-Layered p-i-n Organic Photovoltaic Devices Using Tetrabenzoporphyrin Precursor and Silylmethyl[60]fullerene
Abstract
A new solution-processable fabrication protocol using a soluble tetrabenzoporphyrin (BP) precursor and bis(dimethylphenylsilylmethyl)[60]fullerene (SIMEF) created three-layered p-i-n photovoltaic devices, in which the i-layer possesses a well-defined bulk heterojunction structure in which columnar BP crystals grow vertically from the bottom p-layer. The device showed a power conversion efficiency of 5.2% (V(OC) = 0.75 V; J(SC) = 10.5 mA/cm(2); FF = 0.65).
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Dimers usually show a higher efficiency in comparison with monomers.
“Dimers usually show a higher e ffi ciency in comparison with monomers.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [114]
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Metadata
- Authors
- Matsuo, Y., Sato, Y., Niinomi, T., Soga, I., Tanaka, H., & Nakamura, E.
- Affiliations
- Japan Science and Technology Agency (JP)
- Corresponding author
- Matsuo, Yutaka
- Sato, Yoshiharu
- Nakamura, Eiichi
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-16
- Volume
- 131
- Issue
- 44
- Pages
- 16048-16050
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2028229263
- Cited by
- 488
- References
- 29
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 3 · 2023: 8 · 2022: 8 · 2021: 10 · 2020: 18 · 2019: 13 · 2018: 23 · 2017: 30 · 2016: 37 · 2015: 45 · 2014: 60 · 2013: 62 · 2012: 76
- FWCI
- 42.58
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Chemistry › Organic Chemistry › Fullerene Chemistry and Applications
- Keywords
- organic solar cells, bulk heterojunction, columnar crystal growth, tetrabenzoporphyrin, p-i-n devices, solution processing, power conversion efficiency, fullerene acceptors
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