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Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst
Abstract
A photoelectrochemical cell was designed that catalyzes the photooxidation of water using visible light as the sole energy source and a molecular catalyst, [Mn(4)O(4)L(6)](+) (1(+), L = bis(methoxyphenyl)phosphinate), synthesized from earth-abundant elements. The essential features include a photochemical charge separation system, [Ru(II)(bipy)(2)(bipy(COO)(2))], adhered to titania-coated FTO conductive glass, and 1(+) embedded within a proton-conducting membrane (Nafion). The complete photoanode represents a functional analogue of the water-oxidizing center of natural photosynthesis.
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Citations
Cites
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Metadata
- Authors
- Brimblecombe, R., Koo, A., Dismukes, G. C., Swiegers, G. F., & Spiccia, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-02-15
- Volume
- 132
- Issue
- 9
- Pages
- 2892-2894
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2025729481
- Cited by
- 430
- References
- 1
- FWCI
- 25.20
- Type
- journal article
- Language
- en
- Open access
- closed
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