The Fumed Silica Surface: A Study by NMR
Abstract
High-resolution solid-state NMR techniques were used to investigate the surface structure of Cab-O-Sil fumed silica. 1 H NMR results obtained from CRAMPS, MAS-only and relaxation studies reveal the existence of both hydrogen-bonded silanols and isolated silanols on the Cab-O-Sil surface. A systematic dehydration study of fumed silica was carried out, with results on the quantity of each type of silanol on the surface at various dehydration stages. 29 Si CP-MAS experiments, including CP spin dynamics studies and various other relaxation studies, were employed to probe hydrogen bonding and the local structural environments of various hydroxyl groups of silica surfaces. 29 Si CP-MAS experiments on water-treated and deuterium-exchanged Cab-O-Sil indicate the existence of interparticle silanols and internal silanols in fumed silica. 1 H and 29 Si NMR show that for fumed silica both isolated and hydrogen-bonded silanols are present on the surface of an untreated sample, in contrast to the case of silica gel, where all silanols of an untreated sample are hydrogen bonded.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The breadth and chemical shifts of additional peaks in 29Si CP NMR are consistent with formation of an amorphous silicate phase.
“The breadth of additional peaks and their chemical shifts are consistent with the formation of an amorphous silicate phase [5, 29, 30].”
From Mechanochemical formation of highly stable amorphous calcium carbonate in calcium silicates: Potential long-term storage of CO2 in cement (2024) · cites this paper as [29]
Cites
Proton-enhanced NMR of dilute spins in solids
Pines, A., Gibby, M. G., & Waugh, J. S. (1973) · The Journal of Chemical Physics · doi:10.1063/1.1680061 · Cited by 2,507 · see citing works
Concentration of hydroxyl groups on the surface of amorphous silicas
Zhuravlev, L. T. (1987) · Langmuir · doi:10.1021/la00075a004 · Cited by 1,032 · see citing works
Spin Temperature and Nuclear Magnetic Resonance in Solids
Andrew, E. R. (1971) · Physics Bulletin · doi:10.1088/0031-9112/22/3/030 · Cited by 640 · see citing works
Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
Maciel, G. E., & Sindorf, D. W. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00545a056 · Cited by 521 · see citing works
Self-citationBergna, H. E. (1994) · Advances in chemistry series · doi:10.1021/ba-1994-0234.ch001 · Cited by 491 · see citing works
Surface Functionality of Amorphous Silica by Infrared Spectroscopy
McDONALD, R. S. (1958) · The Journal of Physical Chemistry · doi:10.1021/j150568a004 · Cited by 441 · see citing works
Sindorf, D. W., & Maciel, G. E. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00344a012 · Cited by 398 · see citing works
Self-citationAndrew, E. R. (1971) · Progress in Nuclear Magnetic Resonance Spectroscopy · doi:10.1016/0079-6565(71)80001-8 · Cited by 397 · see citing works
Sindorf, D. W., & Maciel, G. E. (1982) · The Journal of Physical Chemistry · doi:10.1021/j100223a029 · Cited by 347 · see citing works
Self-citationInfrared Study of OH and NH 2 Groups on the Surface of a Dry Silica Aerogel
Peri, J. B. (1966) · The Journal of Physical Chemistry · doi:10.1021/j100881a037 · Cited by 325 · see citing works
Sindorf, D. W., & Maciel, G. E. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00350a003 · Cited by 324 · see citing works
Self-citationSurface vibrational modes of silanol groups on silica
Morrow, B. A., & McFarlan, A. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100182a068 · Cited by 317 · see citing works
Proton NMR study of dehydration of the silica gel surface
Bronnimann, C. E., Zeigler, R. C., & Maciel, G. E. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00215a001 · Cited by 312 · see citing works
Self-citationNMR of Chemically Exchanging Systems
(1980) · Elsevier eBooks · doi:10.1016/b978-0-12-397550-8.x5001-0 · Cited by 276 · see citing works
Surface characterization of amorphous silica—a review of work from the former USSR
Zhuravlev, L. T. (1993) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/0927-7757(93)80399-y · Cited by 267 · see citing works
Study of the surface and bulk hydroxyl groups of silica by infra-red spectra and D2O-exchange
Davydov, V. Y., Kiselev, A. V., & Zhuravlev, L. T. (1964) · Transactions of the Faraday Society · doi:10.1039/tf9646002254 · Cited by 260 · see citing works
HYDROXYL CONTENT IN SILICA GEL “AEROSIL”
Fripiat, J. J., & Uytterhoeven, J. B. (1962) · The Journal of Physical Chemistry · doi:10.1021/j100811a007 · Cited by 222 · see citing works
Analysis of nitrogen adsorption isotherms on porous and nonporous silicas by the BET and αs methods
Bhambhani, M. R., Cutting, P. A., Sing, K. S. W., et al. (1972) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(72)90226-3 · Cited by 220 · see citing works
Hoffmann, P., & Knözinger, E. (1987) · Surface Science · doi:10.1016/s0039-6028(87)80150-4 · Cited by 218 · see citing works
Gerstein, B. C., Pembleton, R. G., Wilson, R. C., et al. (1977) · The Journal of Chemical Physics · doi:10.1063/1.433638 · Cited by 212 · see citing works
Determination of the Si–O–Si bond angle distribution in vitreous silica by magic angle spinning NMR
Dupree, R., & Pettifer, R. F. (1984) · Nature · doi:10.1038/308523a0 · Cited by 202 · see citing works
Hoffmann, P., & Knözinger, E. (1987) · Surface Science Letters · doi:10.1016/0167-2584(87)90016-8 · Cited by 202 · see citing works
Silicon-29 CP/MAS NMR studies of methylchlorosilane reactions on silica gel
Sindorf, D. W., & Maciel, G. E. (1981) · Journal of the American Chemical Society · doi:10.1021/ja00404a055 · Cited by 194 · see citing works
Self-citationBurneau, A., Barrès, O., Gallas, J. P., et al. (1990) · Langmuir · doi:10.1021/la00098a008 · Cited by 194 · see citing works
Water and the silica surface as studied by variable-temperature high-resolution proton NMR
Kinney, D. R., Chuang, I.-S., & Maciel, G. E. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00068a041 · Cited by 192 · see citing works
Self-citationSpectral spin diffusion in polycrystalline solids under magic-angle spinning
Kubo, A., & MCDOWELL, C. A. (1988) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19888403713 · Cited by 175 · see citing works
Morrow, B. A., & Cody, I. A. (1976) · The Journal of Physical Chemistry · doi:10.1021/j100559a010 · Cited by 173 · see citing works
Chemical reactions at silica surfaces
Morrow, B. A., & McFarlan, A. (1990) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(90)90191-n · Cited by 162 · see citing works
Growth and Structure of Combustion Aerosols: Fumed Silica
Schaefer, D. W., & Hurd, A. J. (1990) · Aerosol Science and Technology · doi:10.1080/02786829008959400 · Cited by 162 · see citing works
Morrow, B. A., & McFarlan, A. (1991) · Langmuir · doi:10.1021/la00056a022 · Cited by 160 · see citing works
Spin-Lattice Relaxation in Periodically Perturbed Systems
Haeberlen, U., & Waugh, J. S. (1969) · Physical Review · doi:10.1103/physrev.185.420 · Cited by 149 · see citing works
Legrand, A. P., Hommel, H., Tuel, A., Vidal, A., Balard, H., Papirer, E., Levitz, P., Czernichowski, M., Erre, R., Damme, H. V., et al. (1990) · Advances in Colloid and Interface Science · doi:10.1016/0001-8686(90)80027-w · Cited by 147 · see citing works
Silicon-29 NMR study of silica
Leonardelli, S., Facchini, L., Frétigny, C., et al. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00042a018 · Cited by 146 · see citing works
Ghiotti, G., Garrone, E., Morterra, C., et al. (1979) · The Journal of Physical Chemistry · doi:10.1021/j100485a012 · Cited by 133 · see citing works
Sindorf, D. W., & Maciel, G. E. (1983) · The Journal of Physical Chemistry · doi:10.1021/j150644a041 · Cited by 128 · see citing works
Self-citationMichael, G. E., Sindorf, D. W., & Bartuska, V. J. (1981) · Journal of Chromatography A · doi:10.1016/s0021-9673(00)82673-4 · Cited by 127 · see citing works
Pulsed Nuclear Magnetic Resonance in Rotating Solids
Kessemeier, H., & Norberg, R. E. (1967) · Physical Review · doi:10.1103/physrev.155.321 · Cited by 124 · see citing works
de Haan, J. W., van den Bogaert, H. M., Ponjeé, J. J., & van de Ven, L. J. M. (1986) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(86)90411-x · Cited by 118 · see citing works
Interior hydroxyls of the silica gel system as studied by silicon-29 CP-MAS NMR spectroscopy
Chuang, I.-S., Kinney, D. R., & Maciel, G. E. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00072a024 · Cited by 115 · see citing works
Self-citationBasic characteristics and applications of aerosil
Mathias, J., & Wannemacher, G. (1988) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(88)90054-9 · Cited by 105 · see citing works
Dehydration of silica-aluminas monitored by high-resolution solid-state proton NMR
Bronnimann, C. E., Chuang, I.-S., Hawkins, B. L., et al. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00239a043 · Cited by 99 · see citing works
Self-citationInfrared spectra of the isolated hydroxyl groups on silica
Morrow, B. A., & Cody, I. A. (1973) · The Journal of Physical Chemistry · doi:10.1021/j100630a027 · Cited by 97 · see citing works
Gallas, J. P., Lavalley, J. C., Burneau, A., et al. (1991) · Langmuir · doi:10.1021/la00054a036 · Cited by 96 · see citing works
Residual linewidths of NMR spectra of - systems under magic-angle spinning
Brunner, E., Freude, D., Gerstein, B. C., & Pfeifer, H. (1990) · Journal of Magnetic Resonance (1969) · doi:10.1016/0022-2364(90)90367-i · Cited by 68 · see citing works
High-Resolution 1H Nuclear Magnetic Resonance in Solids via CRAMPS
Maciel, G. E., Bronnimann, C. E., & Hawkins, B. L. (1990) · Advances in magnetic and optical resonance · doi:10.1016/b978-0-12-025514-6.50012-5 · Cited by 67 · see citing works
Self-citationMorrow, B. A., & Gay, I. D. (1988) · The Journal of Physical Chemistry · doi:10.1021/j100331a008 · Cited by 60 · see citing works
A silicon-29 NMR study of the silanol population at the surface of derivatized silica
Tuel, A., Hommel, H., Legrand, A. P., et al. (1990) · Langmuir · doi:10.1021/la00094a009 · Cited by 59 · see citing works
Effects of proton-proton spin exchange in the silicon-29 CP-MAS NMR spectra of the silica surface
Chuang, I.-S., Kinney, D. R., Bronnimann, C. E., et al. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100189a022 · Cited by 52 · see citing works
Self-citationMarsmann, H. C. (1974) · Zeitschrift für Naturforschung B · doi:10.1515/znb-1974-7-810 · Cited by 52 · see citing works
Zaborski, M., Vidal, A., Ligner, G., et al. (1989) · Langmuir · doi:10.1021/la00086a028 · Cited by 48 · see citing works
Preparation of Hydrated Silicon Dioxide for Reproducible Chemisorption Experiments
Gobet, J., & Kováts, E. S. (1984) · Adsorption Science & Technology · doi:10.1177/026361748400100105 · Cited by 48 · see citing works
Solid state NMR studies of precipitated and pyrogenic silicas
Tuel, A., Hommel, H., Legrand, A. P., Chevallier, Y., & Morawski, J. C. (1990) · Colloids and Surfaces · doi:10.1016/0166-6622(90)80040-b · Cited by 43 · see citing works
Infrared study of boron trichloride chemisorbed on silica gel
Bermudez, V. M. (1971) · The Journal of Physical Chemistry · doi:10.1021/j100690a009 · Cited by 43 · see citing works
Infrared evidence for two isolated silanol species on activated silicas
McFarlan, A., & Morrow, B. A. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100167a009 · Cited by 39 · see citing works
Silicon functionality distribution on the surface of amorphous silicas by 29Si solid state NMR
Legrand, A. P., Taïbi, H., Hommel, H., Tougne, P., & Leonardelli, S. (1993) · Journal of Non-Crystalline Solids · doi:10.1016/0022-3093(93)91316-u · Cited by 38 · see citing works
The influence of homonuclear dipolar interaction on the residual linewidths of MAS NMR spectra
Brunner, E., Fenzke, D., Freude, D., & Pfeifer, H. (1990) · Chemical Physics Letters · doi:10.1016/0009-2614(90)85653-t · Cited by 31 · see citing works
Investigation by infra-red spectroscopic methods of deuterium exchange properties of aerosil silicas
Hambleton, F. H., Hockey, J. A., & Taylor, J. A. G. (1966) · Transactions of the Faraday Society · doi:10.1039/tf9666200801 · Cited by 30 · see citing works
Trimethyl phosphite adsorbed on silica: an NMR and infrared study
Gay, I. D., McFarlan, A., & Morrow, B. A. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100156a061 · Cited by 27 · see citing works
Internal hydroxyl groups near the surface of silica
Doremus, R. H. (1971) · The Journal of Physical Chemistry · doi:10.1021/j100689a019 · Cited by 26 · see citing works
The porous structure of self-supporting pressed silica discs I. Infrared spectroscopic studies
TYLER, A. (1969) · Journal of Catalysis · doi:10.1016/0021-9517(69)90367-4 · Cited by 26 · see citing works
29Si solid-state NMR study of the surface structure of aerosil silica
Брей, В. В. (1994) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9949002961 · Cited by 25 · see citing works
Physical and chemical aspects of adsorbents and catalysts
Sing, K. S. W. (1972) · Journal of Catalysis · doi:10.1016/0021-9517(72)90230-8 · Cited by 13 · see citing works
High resolution proton magnetic resonance of liquids adsorbed on a pyrogenic silica
Pickett, J. H., & Rogers, L. B. (1967) · Analytical Chemistry · doi:10.1021/ac50157a065 · Cited by 11 · see citing works
Silica gel and aerosil IR spectra and structure
Chukin, G. D., & Apretova, A. I. (1989) · Journal of Applied Spectroscopy · doi:10.1007/bf00659489 · Cited by 9 · see citing works
Adsorption of isobutene on partially hydrophobized aerosil
Valencia, E., & Maldonado, A. (1990) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9908600539 · Cited by 8 · see citing works
Kiss, J. T., Pálinkó, I., & Molnár, Á. (1993) · Journal of Molecular Structure · doi:10.1016/0022-2860(93)80066-5 · Cited by 8 · see citing works
Study of trimethylsilylated aerosil by IR and29Si NMR spectroscopy
Брей, В. В. (1992) · Journal of Applied Spectroscopy · doi:10.1007/bf00659096 · Cited by 4 · see citing works
Dehydration of the surface of pyrogenic silica by 1H nuclear magnetic resonance
Gorlov, Y. I., Брей, В. В., Samoson, A., & Chuiko, A. A. (1988) · Theoretical and Experimental Chemistry · doi:10.1007/bf00531204 · Cited by 2 · see citing works
An NMR Investigation of the Adsorption of Acetaldehyde and Acetone Vapors on Silica (Cabosil)
Bowsher, L. G., & Hall, P. G. (1978) · Separation Science and Technology · doi:10.1080/01496397808057106 · Cited by 2 · see citing works
Flagged first, then by citations
Research works printed but not linked: 24
- Lygin V. I., 1988, Russ. J. Phys. Chem., 62, 1084
- Pavlov V., 1975, Teor. Eksp. Khim., 11, 415
- Davydov V. Y., 1963, Russ. J. Phys. Chem., 37, 1404
- Davydov V. Y., 1964, Russ. J. Phys. Chem., 38, 1108
- Davydov V. Y., 1974, Russian J. Phys. Chem., 48, 1342
- Lippmaa A. E. T., 1981, Dokl. Phys. Chem., 259, 639
- Nandi A. K., 1992, Indian J. Phys., 66, 281
- Chuiko A. A., 1990, Dokl. Akad. Nauk SSSR, 315, 152
- Gorlov Y. I., 1984, Teor. Eksp. Khim., 20, 754
- Gorlov Y. I., 1980, Teor. Eksp. Khim., 16, 405
- Gorlov Y. I., 1980, Teor. Eksp. Khim., 16, 333
- Gorlov Y. I., 1980, Teor. Eksp. Khim., 16, 202
- Gorlov Y. I., 1979, Teor. Eksp. Khim., 15, 446
- Parfitt, G. D.; Sing, K. S. W.CharacterizationofPowderSurfaces; Academic Press: New York, 1976; p 403.
- Gay J. D., 1984, J. Magn. Reson., 58, 413
- Liu, C. C. Solid-State1H and29Si NMR Studies on Cab-O-Sil Silicas Ph.D. Dissertation, Colorado State University, 1995.
- Liu C. C., 1996, Anal. Chem., 68, 1407
- Zhdanov S. P., 1957, Zh. Fiz. Khim., 31, 2213
- Morrow B. A., 1991, J. Langmuir, 7, 1695, 10.1021/la00056a022 · DOI
- Mehring, M.NMR,BasicPrinciplesandProgress; Springer Verlag: Berlin Heidelberg, New York, 1976; p 138.
- Slichter, C. P.PrinciplesofMagneticReconance, 3rd ed.; Springer-Verlag: New York, 1989; p 79.
- Parfitt, G. D.; Sing, K. S. W.CharacterizationofPowderSurfacesAcademic Press: London, New York, San Francisco, 1976; pp 353−420.
- Brunner E., 1990, J. Magn. Reson., 90, 90
- Wells, F. A.StructuralInorganicChemistry5th ed.; Claredon Press: Oxford, UK, 1984; p 1000.
Cited by
Sorted by citations
The surface chemistry of amorphous silica. Zhuravlev model
Zhuravlev, L. T. (2000) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/s0927-7757(00)00556-2 · Cited by 2,489 · see citing works
Metal Oxide Surfaces and Their Interactions with Aqueous Solutions and Microbial Organisms
Brown, G. E., Henrich, V. E., Casey, W. H., Clark, D. L., Eggleston, C. M., Felmy, A. R., Goodman, D. W., Grätzel, M., Maciel, G. E., McCarthy, M. I., et al. (1998) · Chemical Reviews · doi:10.1021/cr980011z · Cited by 1,090 · see citing works
Self-citationCopéret, C., Comas‐Vives, A., Conley, M. P., Estes, D. P., Fedorov, A., Mougel, V., Nagae, H., Núñez‐Zarur, F., & Zhizhko, P. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00373 · Cited by 903 · see citing works
Rimola, A., Costa, D., Sodupe, M., Lambert, J., & Ugliengo, P. (2013) · Chemical Reviews · doi:10.1021/cr3003054 · Cited by 645 · see citing works
Synthetic amorphous silica nanoparticles: toxicity, biomedical and environmental implications
Croissant, J. G., Butler, K. S., Zink, J. I., & Brinker, C. J. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-0230-0 · Cited by 427 · see citing works
A Detailed Model of Local Structure and Silanol Hydrogen Bonding of Silica Gel Surfaces
Chuang, I.-S., & Maciel, G. E. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9629046 · Cited by 267 · see citing works
Self-citationAb Initio Study of the Hydroxylated Surface of Amorphous Silica: A Representative Model
Tielens, F., Gervais, C., Lambert, J., Mauri, F., & Costa, D. (2008) · Chemistry of Materials · doi:10.1021/cm8001173 · Cited by 266 · see citing works
The hydroxyl species and acid sites on diatomite surface: a combined IR and Raman study
Yuan, P., Wu, D. Q., He, H., & Lin, Z. Y. (2003) · Applied Surface Science · doi:10.1016/j.apsusc.2003.10.031 · Cited by 218 · see citing works
Aqueous suspension of fumed oxides: particle size distribution and zeta potential
Гунько, В. М., Zarko, V. I., Leboda, R., et al. (2001) · Advances in Colloid and Interface Science · doi:10.1016/s0001-8686(99)00026-3 · Cited by 213 · see citing works
Surface chemical heterogeneity modulates silica surface hydration
Schrader, A. M., Monroe, J. I., Sheil, R., et al. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1722263115 · Cited by 190 · see citing works
Comas‐Vives, A. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp00602g · Cited by 179 · see citing works
Protsak, I. S., Morozov, Y. M., Dong, W., et al. (2019) · Nanoscale Research Letters · doi:10.1186/s11671-019-2982-2 · Cited by 176 · see citing works
Investigation of the states of water and OH groups on the surface of silica
Liu, P., Qisui, W., Li, X., & Chaocan, Z. (2008) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2008.10.028 · Cited by 156 · see citing works
Ide, M., El-Roz, M., Canck, E. D., Vicente, A., Planckaert, T., Bogaerts, T., Driessche, I. V., Lynen, F., Speybroeck, V. V., Thibault‐Starzyk, F., et al. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp42811c · Cited by 148 · see citing works
Yuan, P., Liu, D., Tan, D., et al. (2012) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2012.11.030 · Cited by 143 · see citing works
Multinuclear Solid-State NMR Studies of Ordered Mesoporous Bioactive Glasses
Leonova, E., Izquierdo‐Barba, I., Arcos, D., et al. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp7107973 · Cited by 136 · see citing works
Surface chemistry and trimethylsilyl functionalization of Stöber silica sols
Suratwala, T. I., Hanna, M. L., Miller, E. L., et al. (2003) · Journal of Non-Crystalline Solids · doi:10.1016/s0022-3093(02)01629-0 · Cited by 130 · see citing works
Tonelli, M., Martini, F., Calucci, L., et al. (2016) · Dalton Transactions · doi:10.1039/c5dt03545g · Cited by 126 · see citing works
Mason, H. E., Du Frane, W. L., Walsh, S. D. C., Dai, Z., Charnvanichborikarn, S., & Carroll, S. A. (2013) · Environmental Science & Technology · doi:10.1021/es3039906 · Cited by 128 · see citing works
Merle, N., Trébosc, J., Baudouin, A., et al. (2012) · Journal of the American Chemical Society · doi:10.1021/ja301085m · Cited by 112 · see citing works
Effect of Calcium Source on Structure and Properties of Sol–Gel Derived Bioactive Glasses
Yu, B., Turdean-Ionescu, C. A., Martin, R. A., Newport, R. J., Hanna, J. V., Smith, M. E., & Jones, J. R. (2012) · Langmuir · doi:10.1021/la303768b · Cited by 111 · see citing works
Angeli, F., Gaillard, M., Jollivet, P., et al. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.02.023 · Cited by 110 · see citing works
Uchino, T., Kurumoto, N., & Sagawa, N. (2006) · Physical Review B · doi:10.1103/physrevb.73.233203 · Cited by 109 · see citing works
Courtier‐Murias, D., Farooq, H., Masoom, H., Botana, A., Soong, R., Longstaffe, J. G., Simpson, M. J., Maas, W. E., Fey, M., Andrew, B., et al. (2012) · Journal of Magnetic Resonance · doi:10.1016/j.jmr.2012.02.009 · Cited by 108 · see citing works
Mechanism and Kinetics of Hexamethyldisilazane Reaction with a Fumed Silica Surface
Гунько, В. М., Vedamuthu, M. S., Henderson, G., et al. (2000) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2000.6934 · Cited by 104 · see citing works
Microscopic structure of nanometer-sized silica particles
Uchino, T., Aboshi, A., Kohara, S., et al. (2004) · Physical Review B · doi:10.1103/physrevb.69.155409 · Cited by 99 · see citing works
DFT study of the adsorption of microsolvated glycine on a hydrophilic amorphous silica surface
Costa, D., Tougerti, A., Tielens, F., et al. (2008) · Physical Chemistry Chemical Physics · doi:10.1039/b806501b · Cited by 97 · see citing works
Bioactive Glasses: From Macro to Nano
Izquierdo‐Barba, I., Salinas, A. J., & Vallet‐Regí, M. (2013) · International Journal of Applied Glass Science · doi:10.1111/ijag.12028 · Cited by 97 · see citing works
Origins of the Non-DLVO Force between Glass Surfaces in Aqueous Solution
Adler, J. J., Rabinovich, Y. I., & Moudgil, B. M. (2001) · Journal of Colloid and Interface Science · doi:10.1006/jcis.2001.7466 · Cited by 96 · see citing works
Dehydration, Dehydroxylation, and Rehydroxylation of Single-Walled Aluminosilicate Nanotubes
Kang, D., Zang, J., Wright, E., McCanna, A. L., Jones, C. W., & Nair, S. (2010) · ACS Nano · doi:10.1021/nn101211y · Cited by 93 · see citing works
Kim, H. N., & Lee, S. K. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.05.047 · Cited by 92 · see citing works
Silva, A. A., Dahmouche, K., & Soares, B. G. (2011) · Applied Clay Science · doi:10.1016/j.clay.2011.08.002 · Cited by 92 · see citing works
Interface Properties of Nanosilica-Modified Waterborne Epoxy Cement Repairing System
Pang, B., Zhang, Y., Liu, G., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b04092 · Cited by 91 · see citing works
Radiolysis of Confined Water: Hydrogen Production at a High Dose Rate
Caër, S. L., Rotureau, P., Brunet, F., Charpentier, T., Blain, G., Renault, J., & Mialocq, J. (2005) · ChemPhysChem · doi:10.1002/cphc.200500185 · Cited by 87 · see citing works
Flame resistance of geopolymer foam coatings for the fire protection of steel
Sarazin, J., Davy, C. A., Bourbigot, S., Tricot, G., Hosdez, J., Lambertin, D., & Fontaine, G. (2021) · Composites Part B Engineering · doi:10.1016/j.compositesb.2021.109045 · Cited by 85 · see citing works
Folliet, N., Roiland, C., Bégu, S., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201002r · Cited by 83 · see citing works
Li, B., Xu, L., Wu, Q., et al. (2007) · Macromolecules · doi:10.1021/ma070485c · Cited by 80 · see citing works
Domínguez‐Garay, A., Berná, A., Ortiz-Bernad, I., et al. (2013) · Environmental Science & Technology · doi:10.1021/es303436x · Cited by 80 · see citing works
Overcoming the disadvantages of fumed silica as filler in elastomer composites
Mora‐Barrantes, I., Rodríguez, A., Ibarra, L., González, L. A., & Valentin, J. L. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10410a · Cited by 77 · see citing works
Looking over Liquid Silicone Rubbers: (1) Network Topology vs Chemical Formulations
Delebecq, E., & Ganachaud, F. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am300502r · Cited by 78 · see citing works
Raftery, D., MacNamara, E., Fisher, G. L., et al. (1997) · Journal of the American Chemical Society · doi:10.1021/ja972035d · Cited by 78 · see citing works
Perras, F. A., Chaudhary, U., Slowing, I. I., et al. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b02579 · Cited by 77 · see citing works
Evaluation of silica-water surface chemistry using NMR spectroscopy
Carroll, S. A., Maxwell, R. S., Bourcier, W. L., et al. (2002) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(01)00827-4 · Cited by 77 · see citing works
Water Adsorption on Pyrogenic Silica Followed by1H MAS NMR
de Lacaillerie, J.-B. D., Aimeur, M. R., Kortobi, Y. E., & Legrand, A. P. (1997) · Journal of Colloid and Interface Science · doi:10.1006/jcis.1997.5126 · Cited by 76 · see citing works
Kinetics of chlorite dissolution at elevated temperatures and CO2 conditions
Smith, M. M., Wolery, T. J., & Carroll, S. A. (2013) · Chemical Geology · doi:10.1016/j.chemgeo.2013.02.017 · Cited by 74 · see citing works
Synthesis of heteropolyacid (H3PW12O40)/SiO2 nanoparticles and their catalytic properties
Kim, H.-J., Shul, Y., & Han, H. (2005) · Applied Catalysis A General · doi:10.1016/j.apcata.2005.10.010 · Cited by 70 · see citing works
Yuan, P., Yang, D., Lin, Z., et al. (2006) · Journal of Non-Crystalline Solids · doi:10.1016/j.jnoncrysol.2006.05.035 · Cited by 69 · see citing works
Engineered silica nanomaterials in pesticide delivery: Challenges and perspectives
Zhang, J., Kothalawala, S. G., & Yu, C. (2023) · Environmental Pollution · doi:10.1016/j.envpol.2023.121045 · Cited by 64 · see citing works
Florek, J., Larivière, D., Kählig, H., et al. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c16282 · Cited by 63 · see citing works
Investigating Lysine Adsorption on Fumed Silica Nanoparticles
Guo, C., & Holland, G. P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp508627h · Cited by 63 · see citing works
Hydration in silica based mesoporous materials: a DFT model
Gierada, M., Petit, I., Handzlik, J., & Tielens, F. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp05460a · Cited by 63 · see citing works
Sankar, M., Ajithkumar, T. G., Sankar, G., et al. (2014) · Catalysis Communications · doi:10.1016/j.catcom.2014.10.026 · Cited by 62 · see citing works
Aboshi, A., Kurumoto, N., Yamada, T., et al. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp0718505 · Cited by 62 · see citing works
Characterization of diatomaceous silica by Raman spectroscopy
Yuan, P., He, H., Wu, D. Q., et al. (2004) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2004.02.005 · Cited by 62 · see citing works
Gunawidjaja, P. N., Mathew, R., Lo, A. Y. H., et al. (2012) · Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences · doi:10.1098/rsta.2011.0257 · Cited by 62 · see citing works
Anjiki, A., & Uchino, T. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp303359v · Cited by 60 · see citing works
The Surface of Nanoparticle Silicon as Studied by Solid-State NMR
Faulkner, R. A., DiVerdi, J. A., Yang, Y., et al. (2012) · Materials · doi:10.3390/ma6010018 · Cited by 58 · see citing works
Self-citationSurface properties of poly(dimethylsiloxane)-based inorganic/organic hybrid materials
Li, Z., Han, W., Kozodaev, D. A., et al. (2006) · Polymer · doi:10.1016/j.polymer.2005.12.057 · Cited by 58 · see citing works
Understanding the Acidic Properties of the Amorphous Hydroxylated Silica Surface
Gierada, M., Proft, F. D., Sulpizi, M., & Tielens, F. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b04137 · Cited by 58 · see citing works
Ab initio cluster calculations of silica surface sites
Murashov, V. V. (2003) · Journal of Molecular Structure · doi:10.1016/s0022-2860(03)00098-x · Cited by 57 · see citing works
Interfacial phenomena at a surface of individual and complex fumed nanooxides
Гунько, В. М., Turov, V. V., Zarko, V. I., et al. (2016) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2016.06.003 · Cited by 56 · see citing works
Switching Optimally Balanced Fe–N Interaction Enables Extremely Stable Energy Storage
Zhao, Z., Zhang, W., Liu, M., et al. (2021) · Energy & environment materials · doi:10.1002/eem2.12342 · Cited by 55 · see citing works
Speciation of Silanol Groups in Precipitated Silica Nanoparticles by 1H MAS NMR Spectroscopy
Hartmeyer, G., Marichal, C., Lebeau, B., Rigolet, S., Caullet, P., & Hernandez, J. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp071490l · Cited by 55 · see citing works
Yamada, T., Nakajima, M., Suemoto, T., et al. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp072312v · Cited by 55 · see citing works
Consolidated silica glass from nanoparticles
Mayerhöfer, T. G., Shen, Z. J., Leonova, E., et al. (2008) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2008.06.011 · Cited by 54 · see citing works
Davidowski, S. K., & Holland, G. P. (2016) · Langmuir · doi:10.1021/acs.langmuir.5b03933 · Cited by 54 · see citing works
Fedel, M., Callone, E., Fabbian, M., et al. (2017) · Applied Surface Science · doi:10.1016/j.apsusc.2017.04.071 · Cited by 54 · see citing works
Humidity‐Initiated Gas Sensors for Volatile Organic Compounds Sensing
Robinson, M. T., Tung, J., Gharahcheshmeh, M. H., & Gleason, K. K. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202101310 · Cited by 53 · see citing works
Aziz, B., Zhao, G., & Hedin, N. (2011) · Langmuir · doi:10.1021/la104629m · Cited by 53 · see citing works
White light emission from transparent SiO2 glass prepared from nanometer-sized silica particles
Uchino, T., & Yamada, T. (2004) · Applied Physics Letters · doi:10.1063/1.1782263 · Cited by 53 · see citing works
1H MAS NMR spectra of hydroxyl species on diatomite surface
Peng, Y., Daqing, W., Zhong, C., Zhiwei, C., Zhongyu, L., Diao, G., & Jinlian, P. (2001) · Chinese Science Bulletin · doi:10.1007/bf02900691 · Cited by 53 · see citing works
Turdean-Ionescu, C. A., Stevensson, B., Izquierdo‐Barba, I., et al. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b12490 · Cited by 52 · see citing works
Wanglee, Y.-J., Hu, J., White, R. E., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja207838j · Cited by 50 · see citing works
Mathew, R., Turdean-Ionescu, C. A., Yu, Y., et al. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b03469 · Cited by 50 · see citing works
Yang, H., Walton, R. I., Antonijevic, S., et al. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp037887g · Cited by 49 · see citing works
13C and 29Si Solid-State NMR of Rubber−Silica Composite Materials
Simonutti, R., Comotti, A., Negroni, F., & Sozzani, P. (1999) · Chemistry of Materials · doi:10.1021/cm9807539 · Cited by 46 · see citing works
Ab initio calculations of Si solid state NMR chemical shifts of silane and silanol groups in silica
Casanovas, J., Illas, F., & Pacchioni, G. (2000) · Chemical Physics Letters · doi:10.1016/s0009-2614(00)00818-6 · Cited by 46 · see citing works
Microstructure evolution in Stöber-type silica nanoparticles and their in vitro apatite deposition
Chen, S., Osaka, A., Hayakawa, S., et al. (2008) · Journal of Sol-Gel Science and Technology · doi:10.1007/s10971-008-1823-z · Cited by 45 · see citing works
Belgamwar, R., Rankin, A. G. M., Maity, A., et al. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c04148 · Cited by 44 · see citing works
Guo, C., & Holland, G. P. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b10236 · Cited by 43 · see citing works
Interfacial phenomena at a surface of individual and complex fumed nanooxides
Гунько, В. М., Turov, V. V., Goncharuk, O. V., et al. (2019) · Poverhnostʹ · doi:10.15407/surface.2019.11.003 · Cited by 42 · see citing works
Avolio, R., Gentile, G., Avella, M., et al. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24377 · Cited by 42 · see citing works
Brus, J., & Dybal, J. (2002) · Macromolecules · doi:10.1021/ma0204249 · Cited by 42 · see citing works
Tang, H., & Jiang, S. P. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp8066662 · Cited by 41 · see citing works
Differentiating and characterizing geminal silanols in silicas by 29Si NMR spectroscopy
Murray, D. K. (2010) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2010.08.045 · Cited by 41 · see citing works
Proton Dynamics at the Water–Silica Interface via Dissociative Molecular Dynamics
Lockwood, G. K., & Garofalini, S. H. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp507640y · Cited by 41 · see citing works
Brus, J. (2002) · Journal of Sol-Gel Science and Technology · doi:10.1023/a:1016032809131 · Cited by 41 · see citing works
Kaphan, D. M., Klet, R. C., Perras, F. A., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00855 · Cited by 39 · see citing works
Uniform Si‐Infused UiO‐66 as a Robust Catalyst Host for Efficient CO2 Hydrogenation to Methanol
Wang, C., Kosari, M., Xi, S., & Zeng, H. C. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202212478 · Cited by 39 · see citing works
The performance of a silica-based mixed gel electrolyte in lead acid batteries
Pan, K., Shi, G., Li, A., et al. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.02.101 · Cited by 39 · see citing works
Guo, C., Jordan, J. S., Yarger, J. L., & Holland, G. P. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b04887 · Cited by 38 · see citing works
Mora‐Barrantes, I., Ibarra, L., Rodríguez, A., González, L. A., & Valentin, J. L. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm12106e · Cited by 38 · see citing works
Electron spin resonance probing of fundamental point defects in nanometer-sized silica particles
Stesmans, A. L., Clémer, K., & Afanas'ev, V. V. (2005) · Physical Review B · doi:10.1103/physrevb.72.155335 · Cited by 38 · see citing works
Buchanan, A. C., Britt, P. F., Skeen, J. T., et al. (1998) · The Journal of Organic Chemistry · doi:10.1021/jo9816717 · Cited by 37 · see citing works
Bound fractions of methacrylate polymers adsorbed on silica using FTIR
Krisanangkura, P., Packard, A. M., Burgher, J., et al. (2010) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.22066 · Cited by 37 · see citing works
Chen, M., Chen, H. Y., Shu, D., et al. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.03.009 · Cited by 36 · see citing works
Civalleri, B., Garrone, E., & Ugliengo, P. (1999) · Chemical Physics Letters · doi:10.1016/s0009-2614(98)01301-3 · Cited by 36 · see citing works
Effect of Particle Structure and Surface Chemistry on PMMA Adsorption to Silica Nanoparticles
Madathingal, R. R., & Wunder, S. L. (2010) · Langmuir · doi:10.1021/la903505y · Cited by 35 · see citing works
Effects of combined neutron and gamma irradiation upon silicone foam
Liu, B., Wang, P., Ao, Y., et al. (2016) · Radiation Physics and Chemistry · doi:10.1016/j.radphyschem.2016.12.005 · Cited by 35 · see citing works
Bound carbonyls in PMMA adsorbed on silica using transmission FTIR
Kulkeratiyut, S., Kulkeratiyut, S., & Blum, F. D. (2006) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.20871 · Cited by 35 · see citing works
- Authors
- Liu, C. C., & Maciel, G. E.
- Affiliations
- Colorado State University (US)
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 118
- Issue
- 21
- Pages
- 5103-5119
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2021813021
- Semantic Scholar
- 9465212bcbf114a724343bd385bbff265d6f40fd
- Cited by
- 303
- References
- 69
- Citations by year
- 2026: 6 · 2025: 9 · 2024: 13 · 2023: 13 · 2022: 17 · 2021: 20 · 2020: 9 · 2019: 10 · 2018: 8 · 2017: 9 · 2016: 17 · 2015: 8 · 2014: 8 · 2013: 15 · 2012: 16
- FWCI
- 3.89
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Spectroscopy › Advanced NMR Techniques and Applications
- Physical Sciences › Physics and Astronomy › Nuclear and High Energy Physics › NMR spectroscopy and applications
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- fumed silica, Cab-O-Sil, silanols, hydrogen bonding, dehydration, silica gel, 1H NMR, spin dynamics, hydroxyl groups
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review