The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Grain-Boundary-Rich Copper for Efficient Solar-Driven Electrochemical CO2 Reduction to Ethylene and Ethanol
Abstract
The grain boundary in copper-based electrocatalysts has been demonstrated to improve the selectivity of solar-driven electrochemical CO 2 reduction toward multicarbon products. However, the approach to form grain boundaries in copper is still limited. This paper describes a controllable grain growth of copper electrodeposition via poly(vinylpyrrolidone) used as an additive. A grain-boundary-rich metallic copper could be obtained to convert CO 2 into ethylene and ethanol with a high selectivity of 70% over a wide potential range. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy unveils that the existence of grain boundaries enhances the adsorption of the key intermediate (*CO) on the copper surface to boost the further CO 2 reduction. When coupling with a commercially available Si solar cell, the device achieves a remarkable solar-to-C2-products conversion efficiency of 3.88% at a large current density of 52 mA·cm –2 . This low-cost and efficient device is promising for large-scale application of solar-driven CO 2 reduction.
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Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
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What Should We Make with CO2 and How Can We Make It?
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Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
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Grain-Boundary-Dependent CO 2 Electroreduction Activity
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Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
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Tuned Chemical Bonding Ability of Au at Grain Boundaries for Enhanced Electrochemical CO2 Reduction
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Defect Chemistry in Heterogeneous Catalysis: Recognition, Understanding, and Utilization
Xie, C., Yan, D., Li, H., Du, S., Chen, W., Wang, Y., Zou, Y., Chen, R., & Wang, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03034 · Cited by 623
Copper‐Based Plasmonic Catalysis: Recent Advances and Future Perspectives
Xin, Y., Yu, K., Zhang, L., Yang, Y., Yuan, H., Li, H., Wang, L., & Zeng, J. (2021) · Advanced Materials · doi:10.1002/adma.202008145 · Cited by 319
High‐Entropy Nanomaterials for Advanced Electrocatalysis
Lee, S. A., Bu, J., Lee, J., & Jang, H. W. (2023) · Small Science · doi:10.1002/smsc.202200109 · Cited by 95
Begildayeva, T., Chinnadurai, D., Lee, S. J., Yu, Y., Song, J. K., & Choi, M. Y. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2021.163446 · Cited by 27
Metadata
- Authors
- Chen, Z., Wang, T., Liu, B., Cheng, D., Hu, C., Zhang, G., Zhu, W., Wang, H., Zhao, Z.-J., & Gong, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-27
- Volume
- 142
- Issue
- 15
- Pages
- 6878-6883
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3014036038
- Cited by
- 447
- References
- 10
- FWCI
- 12.29
- Type
- journal article
- Language
- en
- Open access
- closed
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