The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Strong Electronic Oxide–Support Interaction over In2O3/ZrO2 for Highly Selective CO2 Hydrogenation to Methanol
Abstract
Metal oxides are widely employed in heterogeneous catalysis, but it remains challenging to determine their exact structure and understand the reaction mechanisms at the molecular level due to their structural complexity, in particular for binary oxides. This paper describes the observation of the strong electronic interaction between In 2 O 3 and monoclinic ZrO 2 (m-ZrO 2 ) by quasi-in-situ XPS experiments combined with theoretical studies, which leads to support-dependent methanol selectivity. In 2 O 3 /m-ZrO 2 exhibits methanol selectivity up to 84.6% with a CO 2 conversion of 12.1%. Moreover, at a wide range of temperatures, the methanol yield of In 2 O 3 /m-ZrO 2 is much higher than that of In 2 O 3 /t-ZrO 2 (t-: tetragonal), which is due to the high dispersion of the In–O–In structure over m-ZrO 2 as determined by in situ Raman spectra. The electron transfer from m-ZrO 2 to In 2 O 3 is confirmed by XPS and DFT calculations and improves the electron density of In 2 O 3, which promotes H 2 dissociation and hydrogenation of formate intermediates to methanol. The concept of the electronic interaction between an oxide and a support provides guidelines to develop hydrogenation catalysts.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
Ab initio molecular dynamics for liquid metals
Kresse, G., & Hafner, J. (1993) · Physical Review B · doi:10.1103/physrevb.47.558 · Cited by 45,727
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
Henkelman, G., Uberuaga, B. P., & Jónsson, H. (2000) · The Journal of Chemical Physics · doi:10.1063/1.1329672 · Cited by 21,620
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Self-citationThe Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts
Behrens, M., Studt, F., Kasatkin, I., Kühl, S., Hävecker, M., Abild-Pedersen, F., Zander, S., Girgsdies, F., Kurr, P., Kniep, B.-L., et al. (2012) · Science · doi:10.1126/science.1219831 · Cited by 2,670
Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A. V., Wezendonk, T. A., Makkee, M., Gascon, J., & Kapteijn, F. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00816 · Cited by 1,600
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452
Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface
Kattel, S., Liu, P., & Chen, J. G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05362 · Cited by 1,259
A highly selective and stable ZnO-ZrO2solid solution catalyst for CO2hydrogenation to methanol
Wang, J., Li, G., Li, Z., Tang, C., Feng, Z., An, H., Liu, H., Liu, T., & Li, C. (2017) · Science Advances · doi:10.1126/sciadv.1701290 · Cited by 1,165
Cited by
Li, S., Feng, L., Wang, H., Lin, Y., Sun, Z., Xu, L., Xu, Y., Liu, X., Li, W.-X., Wei, S., et al. (2025) · Nature Nanotechnology · doi:10.1038/s41565-024-01824-w · Cited by 50
Metadata
- Authors
- Yang, C., Pei, C., Luo, R., Liu, S., Wang, Y., Wang, Z., Zhao, Z.-J., & Gong, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-11-06
- Volume
- 142
- Issue
- 46
- Pages
- 19523-19531
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3094911915
- Cited by
- 389
- References
- 32
- FWCI
- 6.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, C., Pei, C., Luo, R., Liu, S., Wang, Y., Wang, Z., Zhao, Z.-J., & Gong, J. (2020). Strong Electronic Oxide–Support Interaction over In2O3/ZrO2 for Highly Selective CO2 Hydrogenation to Methanol. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c07195
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