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Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

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Álvarez, Andrea, Bansode, Atul, Urakawa, Atsushi, Bavykina, Anastasiya V., Wezendonk, Tim A., Makkee, Michiel, Gascon, Jorge, Kapteijn, Freek·2017·Chemical Reviews
DOI 10.1021/acs.chemrev.6b00816
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Abstract

The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design considerations. After introducing the main motivation for the development of such processes, we first summarize the most important aspects of CO2 capture and green routes to produce H2. Once the scene in terms of feedstocks is introduced, we carefully summarize the state of the art in the development of heterogeneous catalysts for these important hydrogenation reactions. Finally, in an attempt to give an order of magnitude regarding CO2 valorization, we critically assess economical aspects of the production of methanol and DME and outline future research and development directions.

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Research works printed but not linked: 261

  1. Princiotta, 2011, Global Climate Change─The Technology Challenge, 420, 10.1007/978-90-481-3153-2 · DOI
  2. 2011, 2011 Technology Map of the European Strategic Energy Technology Plan (SET-Plan)
  3. 2011, The Global Status of CCS: 2011
  4. Rubin, 2012, The Outlook for Improved Carbon Capture Technology, Prog. Energy Combust. Sci., 38, 630, 10.1016/j.pecs.2012.03.003 · DOI · Paper page
  5. Merkel, 2010, Power Plant Post-Combustion Carbon Dioxide Capture: An Opportunity for Membranes, J. Membr. Sci., 359, 126, 10.1016/j.memsci.2009.10.041 · DOI · Paper page
  6. Franz, 2014, Economic Evaluation of Pre-Combustion CO2-capture in IGCC Power Plants by Porous Ceramic Membranes, Appl. Energy, 130, 532, 10.1016/j.apenergy.2014.02.021 · DOI
  7. Ku, 2011, Membrane Performance Requirements for Carbon Dioxide Capture using Hydrogen-selective Membranes in Integrated Gasification Combined Cycle (IGCC) Power Plants, J. Membr. Sci., 367, 233, 10.1016/j.memsci.2010.10.066 · DOI
  8. Lin, 2015, CO2-Selective Membranes for Hydrogen Production and CO2 Capture – Part II: Techno-Economic Analysis, J. Membr. Sci., 493, 794, 10.1016/j.memsci.2015.02.042 · DOI
  9. EPRI., 2008, Program on Technology Innovation: Post-combustion CO2 Capture Technology Development, 136
  10. Acar, 2014, Comparative Assessment of Hydrogen Production Methods from Renewable and Non-Renewable Sources, Int. J. Hydrogen Energy, 39, 1, 10.1016/j.ijhydene.2013.10.060 · DOI · Paper page
  11. Holladay, 2009, An Overview of Hydrogen Production Technologies, Catal. Today, 139, 244, 10.1016/j.cattod.2008.08.039 · DOI · Paper page
  12. Parthasarathy, 2014, Hydrogen Production from Steam Gasification of Biomass: Influence of Process Parameters on Hydrogen Yield – A Review, Renewable Energy, 66, 570, 10.1016/j.renene.2013.12.025 · DOI · Paper page
  13. Gaudernack, 1998, Hydrogen from Natural Gas without Release of CO2 to the Atmosphere, Int. J. Hydrogen Energy, 23, 1087, 10.1016/S0360-3199(98)00004-4 · DOI
  14. Nasir Uddin, 2013, Potential Hydrogen and Non-Condensable Gases Production from Biomass Pyrolysis: Insights into the Process Variables, Renewable Sustainable Energy Rev., 27, 204, 10.1016/j.rser.2013.06.031 · DOI
  15. Ursua, 2012, Hydrogen Production From Water Electrolysis: Current Status and Future Trends, Proc. IEEE, 100, 410, 10.1109/JPROC.2011.2156750 · DOI · Paper page
  16. Dincer, 2012, Green Methods for Hydrogen Production, Int. J. Hydrogen Energy, 37, 1954, 10.1016/j.ijhydene.2011.03.173 · DOI · Paper page
  17. Dincer, 2015, Review and Evaluation of Hydrogen Production Methods for Better Sustainability, Int. J. Hydrogen Energy, 40, 11094, 10.1016/j.ijhydene.2014.12.035 · DOI · Paper page
  18. Wang, 2014, The Intensification Technologies to Water Electrolysis for Hydrogen Production – A Review, Renewable Sustainable Energy Rev., 29, 573, 10.1016/j.rser.2013.08.090 · DOI · Paper page
  19. Carmo, 2013, A Comprehensive Review on PEM Water Electrolysis, Int. J. Hydrogen Energy, 38, 4901, 10.1016/j.ijhydene.2013.01.151 · DOI · Paper page
  20. Zeng, 2010, Recent Progress in Alkaline Water Electrolysis for Hydrogen Production and Applications, Prog. Energy Combust. Sci., 36, 307, 10.1016/j.pecs.2009.11.002 · DOI · Paper page
  21. Kalinci, 2009, Biomass-based Hydrogen Production: A Review and Analysis, Int. J. Hydrogen Energy, 34, 8799, 10.1016/j.ijhydene.2009.08.078 · DOI · Paper page
  22. Zhu, 2016, Effects of Reaction Time and Catalyst on Gasification of Glucose in Supercritical Water: Detailed Reaction Pathway and Mechanisms, Int. J. Hydrogen Energy, 41, 6630, 10.1016/j.ijhydene.2016.03.035 · DOI
  23. Ni, 2006, An Overview of Hydrogen Production from Biomass, Fuel Process. Technol., 87, 461, 10.1016/j.fuproc.2005.11.003 · DOI · Paper page
  24. Teets, 2011, Photocatalytic Hydrogen Production, Chem. Commun., 47, 9268, 10.1039/c1cc12390d · DOI · Paper page
  25. Khan, 2002, Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2, Science, 297, 2243, 10.1126/science.1075035 · DOI · Paper page
  26. Kudo, 2009, Heterogeneous Photocatalyst Materials for Water Splitting, Chem. Soc. Rev., 38, 253, 10.1039/B800489G · DOI · Paper page
  27. Xiao, 2016, Boosting Photocatalytic Hydrogen Production of a Metal–Organic Framework Decorated with Platinum Nanoparticles: The Platinum Location Matters, Angew. Chem., Int. Ed., 55, 9389, 10.1002/anie.201603990 · DOI · Paper page
  28. Li, 2011, Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets, J. Am. Chem. Soc., 133, 10878, 10.1021/ja2025454 · DOI · Paper page
  29. Jing, 2010, Efficient Solar Hydrogen Production by Photocatalytic Water Splitting: From Fundamental Study to Pilot Demonstration, Int. J. Hydrogen Energy, 35, 7087, 10.1016/j.ijhydene.2010.01.030 · DOI · Paper page
  30. Grasemann, 2012, Formic Acid as a Hydrogen Source - Recent Developments and Future Trends, Energy Environ. Sci., 5, 8171, 10.1039/c2ee21928j · DOI · Paper page
  31. Reutemann, 2000, Formic Acid, 10.1002/14356007.a12_013 · DOI
  32. Wang, 2012, Hydrogenation
  33. Xu, W.; Ma, L.; Huang, B.; Cui, X.; Niu, X.; Zhang, H. In Thermodynamic Analysis of Formic Acid Synthesis from CO2 Hydrogenation, 2011 International Conference on Materials for Renewable Energy & Environment, 20–22 May 2011; 2011; pp 1473–1477. · doi:10.1109/icmree.2011.5930612
  34. Jessop, 1999, Homogeneous Catalysis in Supercritical Fluids, Chem. Rev., 99, 475, 10.1021/cr970037a · DOI · Paper page
  35. Inoue, 1976, Catalytic Fixation of Carbon Dioxide to Formic Acid by Transition-Metal Complexes under Mild Conditions, Chem. Lett., 5, 863, 10.1246/cl.1976.863 · DOI · Paper page
  36. Wang, 2015, CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction, Chem. Rev., 115, 12936, 10.1021/acs.chemrev.5b00197 · DOI · Paper page
  37. Jessop, 1995, Homogeneous Hydrogenation of Carbon-Dioxide, Chem. Rev., 95, 259, 10.1021/cr00034a001 · DOI · Paper page
  38. Klankermayer, 2016, Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry, Angew. Chem., Int. Ed., 55, 7296, 10.1002/anie.201507458 · DOI · Paper page
  39. Leitner, 1995, Carbon-Dioxide as A Raw-Material - The Synthesis of Formic-Acid and its Derivatives from CO2, Angew. Chem., Int. Ed. Engl., 34, 2207, 10.1002/anie.199522071 · DOI · Paper page
  40. Jessop, 2004, Recent Advances in the Homogeneous Hydrogenation of Carbon Dioxide, Coord. Chem. Rev., 248, 2425, 10.1016/j.ccr.2004.05.019 · DOI · Paper page
  41. Filonenko, 2014, Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst, ChemCatChem, 6, 1526, 10.1002/cctc.201402119 · DOI · Paper page
  42. Gunasekar, 2016, Recent Developments in the Catalytic Hydrogenation of CO2 to Formic Acid/Formate using Heterogeneous Catalysts, Inorg. Chem. Front., 3, 882, 10.1039/C5QI00231A · DOI
  43. Bredig, 1914, Katalytische Synthese der Ameisensäure unter Druck, Ber. Dtsch. Chem. Ges., 47, 541, 10.1002/cber.19140470188 · doi:10.1002/cber.19140470188
  44. Farlow, 1935, The Hydrogenation of Carbon Dioxide and a Correction of the Reported Synthesis of Urethans, J. Am. Chem. Soc., 57, 2222, 10.1021/ja01314a054 · DOI
  45. Srivastava, 2014, In Situ Generation of Ru Nanoparticles to Catalyze CO2 Hydrogenation to Formic Acid, Catal. Lett., 144, 1745, 10.1007/s10562-014-1321-6 · doi:10.1007/s10562-014-1321-6
  46. Umegaki, 2016, Metallic Ruthenium Nanoparticles for Hydrogenation of Supercritical Carbon Dioxide, Catal. Sci. Technol., 6, 409, 10.1039/C5CY00994D · doi:10.1039/c5cy00994d
  47. Stalder, 1983, Supported Palladium Catalysts for the Reduction of Sodium Bicarbonate to Sodium Formate in Aqueous Solution at Room Temperature and One Atmosphere of Hydrogen, J. Am. Chem. Soc., 105, 6318, 10.1021/ja00358a026 · DOI
  48. Su, 2015, Highly Efficient Hydrogen Storage System Based on Ammonium Bicarbonate/Formate Redox Equilibrium over Palladium Nanocatalysts, ChemSusChem, 8, 813, 10.1002/cssc.201403251 · DOI · Paper page
  49. Bi, 2014, An Aqueous Rechargeable Formate-Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis, Angew. Chem., Int. Ed., 53, 13583, 10.1002/anie.201409500 · DOI · Paper page
  50. Lee, 2014, Carbon Dioxide Mediated, Reversible Chemical Hydrogen Storage using a Pd Nanocatalyst Supported on Mesoporous Graphitic Carbon Nitride, J. Mater. Chem. A, 2, 9490, 10.1039/c4ta01133c · DOI · Paper page
  51. Joo, 1999, Homogeneous Hydrogenation of Aqueous Hydrogen Carbonate to Formate under Exceedingly Mild Conditions-a Novel Possibility of Carbon Dioxide Activation, Chem. Commun., 11, 971, 10.1039/a902368b · doi:10.1039/a902368b
  52. Su, 2015, High Yield Production of Formate by Hydrogenating CO2 Derived Ammonium Carbamate/Carbonate at Room Temperature, Green Chem., 17, 2769, 10.1039/C5GC00397K · doi:10.1039/c5gc00397k
  53. Preti, 2011, Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst, Angew. Chem., Int. Ed., 50, 12551, 10.1002/anie.201105481 · DOI · Paper page
  54. Preti, 2012, Conversion of Syngas into Formic Acid, ChemCatChem, 4, 469, 10.1002/cctc.201200046 · DOI
  55. Filonenko, 2016, On the Activity of Supported Au Catalysts in the Liquid Phase Hydrogenation of CO2 to Formates, J. Catal., 343, 97, 10.1016/j.jcat.2015.10.002 · DOI
  56. Hao, 2011, Hydrogenation of CO2 to Formic Acid on Supported Ruthenium Catalysts, Catal. Today, 160, 184, 10.1016/j.cattod.2010.05.034 · DOI · Paper page
  57. Nguyen, 2015, Catalytic CO2 Hydrogenation to Formic Acid over Carbon Nanotube-Graphene Supported PdNi Alloy Catalysts, RSC Adv., 5, 105560, 10.1039/C5RA21017H · DOI
  58. Takahashi, 2006, CO2 Reduction using Hydrothermal Method for the Selective Formation of Organic Compounds, J. Mater. Sci., 41, 1585, 10.1007/s10853-006-4649-5 · DOI
  59. Federsel, 2010, State-of-the-Art Catalysts for Hydrogenation of Carbon Dioxide, Angew. Chem., Int. Ed., 49, 6254, 10.1002/anie.201000533 · DOI · Paper page
  60. Filonenko, 2014, Mechanism of CO2 Hydrogenation to Formates by Homogeneous Ru-PNP Pincer Catalyst: from a Theoretical Description to Performance Optimization, Catal. Sci. Technol., 4, 3474, 10.1039/C4CY00568F · DOI
  61. Huff, 2013, Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex, ACS Catal., 3, 2412, 10.1021/cs400609u · DOI · Paper page
  62. Hull, 2012, Reversible Hydrogen Storage using CO2 and a Proton-Switchable Iridium Catalyst in Aqueous Media under Mild Temperatures and Pressures, Nat. Chem., 4, 383, 10.1038/nchem.1295 · DOI · Paper page
  63. Moret, 2014, Direct Synthesis of Formic Acid from Carbon Dioxide by Hydrogenation in Acidic Media, Nat. Commun., 5, 4017, 10.1038/ncomms5017 · DOI · Paper page
  64. Tanaka, 2009, Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)–Pincer Complexes, J. Am. Chem. Soc., 131, 14168, 10.1021/ja903574e · DOI · Paper page
  65. Urakawa, 2007, Towards a Rational Design of Ruthenium CO2 Hydrogenation Catalysts by Ab Initio Metadynamics, Chem. - Eur. J., 13, 6828, 10.1002/chem.200700254 · DOI
  66. Urakawa, 2007, Carbon Dioxide Hydrogenation Catalyzed by a Ruthenium Dihydride: A DFT and High-Pressure Spectroscopic Investigation, Chem. - Eur. J., 13, 3886, 10.1002/chem.200601339 · DOI
  67. Hübner, 2016, Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts?, Adv. Synth. Catal., 358, 3, 10.1002/adsc.201500846 · DOI · Paper page
  68. Jessop, 1996, Homogeneous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides, J. Am. Chem. Soc., 118, 344, 10.1021/ja953097b · DOI · Paper page
  69. Jessop, 1995, Homogeneous Catalysis In Supercritical Fluids, Science, 269, 1065, 10.1126/science.269.5227.1065 · DOI · Paper page
  70. Jessop, 1994, Homogeneous Catalytic-Hydrogenation Of Supercritical Carbon-Dioxide, Nature, 368, 231, 10.1038/368231a0 · DOI · Paper page
  71. Krocher, 1997, Highly Active Ruthenium Complexes with Bidentate Phosphine Ligands for the Solvent-free Catalytic Synthesis of N,N-dimethylformamide and Methyl Formate, Chem. Commun., 5, 453, 10.1039/a608150i · DOI · Paper page
  72. Rohr, 2005, Evaluation of Strategies for the Immobilization of Bidentate Ruthenium–phosphine Complexes used for the Reductive Amination of Carbon Dioxide, Appl. Catal., A, 296, 238, 10.1016/j.apcata.2005.08.025 · doi:10.1016/j.apcata.2005.08.025
  73. Schmid, 2000, Silica Xerogels Containing Bidentate Phosphine Ruthenium Complexes: Textural Properties and Catalytic Behaviour in the Synthesis of N,N-dimethylformamide from Carbon Dioxide, Microporous Mesoporous Mater., 35–36, 181, 10.1016/S1387-1811(99)00219-X · doi:10.1016/s1387-1811(99)00219-x
  74. Schmid, 1999, A Mesoporous Ruthenium Silica Hybrid Aerogel with Outstanding Catalytic Properties in the Synthesis of N,N-diethylformamide from CO2, H2 and Diethylamine, Chem. Commun., 22, 2303, 10.1039/a906956i · DOI
  75. Zhang, 2004, Silica Immobilized Ruthenium Catalyst used for Carbon Dioxide Hydrogenation to Formic Acid (I): the Effect of Functionalizing Group and Additive on the Catalyst Performance, Catal. Commun., 5, 643, 10.1016/j.catcom.2004.08.001 · DOI
  76. Yu, 2006, MCM-41 Bound Ruthenium Complex as Heterogeneous Catalyst for Hydrogenation I: Effect of Support, Ligand and Solvent on the Catalyst Performance, Chin. J. Chem., 24, 840, 10.1002/cjoc.200690160 · doi:10.1002/cjoc.200690160
  77. Yu, 2005, Silica Immobilized Ruthenium Catalyst for Formic Acid Synthesis from Supercritical Carbon Dioxide Hydrogenation II: Effect of Reaction Conditions on the Catalyst Performance, Chin. J. Chem., 23, 977, 10.1002/cjoc.200590977 · DOI
  78. Baffert, 2011, Tailored Ruthenium–N-Heterocyclic Carbene Hybrid Catalytic Materials for the Hydrogenation of Carbon Dioxide in the Presence of Amine, ChemSusChem, 4, 1762, 10.1002/cssc.201100223 · DOI
  79. Xu, 2013, Catalytic Hydrogenation of CO2 to Formic Acid with Silica-Tethered Iridium Catalysts, ChemCatChem, 5, 1769, 10.1002/cctc.201200839 · DOI
  80. McNamara, 2014, CO2 Capture and Conversion with a Multifunctional Polyethyleneimine-Tethered Iminophosphine Iridium Catalyst/Adsorbent, ChemSusChem, 7, 1114, 10.1002/cssc.201301231 · DOI
  81. Zhang, 2008, Hydrogenation of Carbon Dioxide is Promoted by a Task-Specific Ionic Liquid, Angew. Chem., Int. Ed., 47, 1127, 10.1002/anie.200704487 · DOI · Paper page
  82. Zhang, 2009, Hydrogenation of CO2 to Formic Acid Promoted by a Diamine-Functionalized Ionic Liquid, ChemSusChem, 2, 234, 10.1002/cssc.200800252 · DOI
  83. Feng, 2012, Covalent Organic Frameworks, Chem. Soc. Rev., 41, 6010, 10.1039/c2cs35157a · DOI · Paper page
  84. Rogge, 2017, Metal-organic and Covalent Organic Frameworks as Single-site Catalysts, Chem. Soc. Rev., 46, 3134, 10.1039/C7CS00033B · DOI · Paper page
  85. Redondo, 2015, Functionalized Ruthenium-Phosphine Metal-Organic Framework for Continuous Vapor-Phase Dehydrogenation of Formic Acid, ACS Catal., 5, 7099, 10.1021/acscatal.5b01987 · DOI
  86. Yang, 2015, A Troger’s Base-derived Microporous Organic Polymer: Design and Applications in CO2/H2 Capture and Hydrogenation of CO2 to Formic Acid, Chem. Commun., 51, 1271, 10.1039/C4CC08295H · DOI
  87. Park, 2015, A Highly Efficient Heterogenized Iridium Complex for the Catalytic Hydrogenation of Carbon Dioxide to Formate, ChemSusChem, 8, 3410, 10.1002/cssc.201500436 · DOI
  88. Gunniya Hariyanandam, 2016, An Effective Heterogeneous Ir(III) Catalyst, Immobilized on a Heptazine-based Organic Framework, for the Hydrogenation of CO2 to Formate, Catal. Today, 265, 52, 10.1016/j.cattod.2015.10.037 · DOI
  89. Li, 2008, Air-Stable and Phosphine-Free Iridium Catalysts for Highly Enantioselective Hydrogenation of Quinoline Derivatives, Org. Lett., 10, 5265, 10.1021/ol802016w · doi:10.1021/ol802016w
  90. Ogo, 2006, Mechanistic Investigation of CO2 Hydrogenation by Ru(ii) and Ir(iii) Aqua Complexes under Acidic Conditions: Two Catalytic Systems Differing in the Nature of the Rate Determining Step, Dalton Transactions, 39, 4657, 10.1039/b607993h · DOI
  91. Ogo, 1999, pH-Dependent Transfer Hydrogenation of Water-Soluble Carbonyl Compounds with [Cp*IrIII(H2O)3]2+ (Cp* = η5-C5Me5) as a Catalyst Precursor and HCOONa as a Hydrogen Donor in Water, Organometallics, 18, 5470, 10.1021/om9903689 · doi:10.1021/om9903689
  92. Yamaguchi, 2009, Homogeneous Catalytic System for Reversible Dehydrogenation–Hydrogenation Reactions of Nitrogen Heterocycles with Reversible Interconversion of Catalytic Species, J. Am. Chem. Soc., 131, 8410, 10.1021/ja9022623 · DOI
  93. Kuhn, 2008, Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis, Angew. Chem., Int. Ed., 47, 3450, 10.1002/anie.200705710 · DOI · Paper page
  94. Bavykina, 2015, Efficient Production of Hydrogen from Formic Acid using a Covalent Triazine Framework Supported Molecular Catalyst, ChemSusChem, 8, 809, 10.1002/cssc.201403173 · DOI
  95. Bavykina, 2016, Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid, ChemCatChem, 8, 2217, 10.1002/cctc.201600419 · doi:10.1002/cctc.201600419
  96. Peng, 2012, CO2 Hydrogenation to Formic Acid on Ni(111), J. Phys. Chem. C, 116, 3001, 10.1021/jp210408x · DOI
  97. Olah, 2009, Chemical Recycling of Carbon Dioxide to Methanol and DME: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons, J. Org. Chem., 74, 487, 10.1021/jo801260f · DOI · Paper page
  98. Arcoumanis, 2008, The Ootential of di-methyl Ether (DME) as an Alternative Fuel for Compression-ignition Engines: A review, Fuel, 87, 1014, 10.1016/j.fuel.2007.06.007 · DOI · Paper page
  99. Arena, 2014, Latest Advances in the Catalytic Hydrogenation of Carbon Dioxide to Methanol/Dimethylether, 103, 10.1007/978-3-642-44988-8_5 · DOI
  100. Ganesh, 2014, Conversion of Carbon Dioxide into Methanol – a Potential Liquid Fuel: Fundamental Challenges and Opportunities (a Review), Renewable Sustainable Energy Rev., 31, 221, 10.1016/j.rser.2013.11.045 · DOI · Paper page
  101. Dubois, 1992, Conversion of CO2 to Dimethylether and Methanol over Hybrid Catalysts, Chem. Lett., 21, 1115, 10.1246/cl.1992.1115 · doi:10.1246/cl.1992.1115
  102. Chen, 2012, One-step Synthesis of Dimethyl Ether from the Gas Mixture Containing CO2 with High Space Velocity, Appl. Energy, 98, 92, 10.1016/j.apenergy.2012.02.082 · DOI
  103. Graaf, 1986, Chemical Equilibria in Methanol Synthesis, Chem. Eng. Sci., 41, 2883, 10.1016/0009-2509(86)80019-7 · DOI
  104. Graaf, 2016, Chemical Equilibria in Methanol Synthesis Including the Water–Gas Shift Reaction: A Critical Reassessment, Ind. Eng. Chem. Res., 55, 5854, 10.1021/acs.iecr.6b00815 · DOI
  105. Graaf, 1988, Kinetics of Low-pressure Methanol Synthesis, Chem. Eng. Sci., 43, 3185, 10.1016/0009-2509(88)85127-3 · DOI · Paper page
  106. Bussche, 1996, A Steady-State Kinetic Model for Methanol Synthesis and the Water Gas Shift Reaction on a Commercial Cu/ZnO/Al2O3Catalyst, J. Catal., 161, 1, 10.1006/jcat.1996.0156 · DOI · Paper page
  107. Gallucci, 2007, A Theoretical Analysis of Methanol Synthesis from CO2 and H2 in a Ceramic Membrane Reactor, Int. J. Hydrogen Energy, 32, 5050, 10.1016/j.ijhydene.2007.07.067 · DOI
  108. Fornero, 2011, CO2 Capture via Catalytic Hydrogenation to Methanol: Thermodynamic Limit vs. ‘Kinetic Limit’, Catal. Today, 172, 158, 10.1016/j.cattod.2011.02.036 · doi:10.1016/j.cattod.2011.02.036
  109. Van-Dal, 2013, Design and Simulation of a Methanol Production Plant from CO2 Hydrogenation, J. Cleaner Prod., 57, 38, 10.1016/j.jclepro.2013.06.008 · DOI · Paper page
  110. Meyer, 2016, Modeling of a Methanol Synthesis Reactor for Storage of Renewable Energy and Conversion of CO2 – Comparison of Two Kinetic Models, Chem. Eng. Technol., 39, 233, 10.1002/ceat.201500084 · DOI
  111. Gaikwad, 2016, High-pressure Advantages in Stoichiometric Hydrogenation of Carbon Dioxide to Methanol, J. Catal., 343, 127, 10.1016/j.jcat.2016.02.005 · DOI · Paper page
  112. Bennekom, 2012, Modeling and Experimental Studies on Phase and Chemical Equilibria in High-Pressure Methanol Synthesis, Ind. Eng. Chem. Res., 51, 12233, 10.1021/ie3017362 · DOI
  113. van Bennekom, 2013, Methanol Synthesis beyond Chemical Equilibrium, Chem. Eng. Sci., 87, 204, 10.1016/j.ces.2012.10.013 · DOI
  114. Bansode, 2014, Towards Full One-pass Conversion of Carbon Dioxide to Methanol and Methanol-derived Products, J. Catal., 309, 66, 10.1016/j.jcat.2013.09.005 · DOI · Paper page
  115. Shen, 2000, Thermodynamic Investigation of Methanol and Dimethyl Ether Synthesis from CO2 Hydrogenation, Korean J. Chem. Eng., 17, 210, 10.1007/BF02707145 · DOI
  116. Aguayo, 2007, Kinetic Modeling of Dimethyl Ether Synthesis in a Single Step on a CuO–ZnO–Al2O3/γ-Al2O3 Catalyst, Ind. Eng. Chem. Res., 46, 5522, 10.1021/ie070269s · DOI
  117. Qin, 2015, Experimental and Theoretical Study of the Intrinsic Kinetics for Dimethyl Ether Synthesis from CO2 over Cu–Fe–Zr/HZSM-5, AIChE J., 61, 1613, 10.1002/aic.14743 · DOI
  118. Ereña, 2011, Kinetic Modelling of Dimethyl Ether Synthesis from (H2 + CO2) by Considering Catalyst Deactivation, Chem. Eng. J., 174, 660, 10.1016/j.cej.2011.09.067 · DOI
  119. Jia, 2006, Comparative Study on the Thermodynamics of Dimethyl Ether Synthesis from CO Hydrogenation and CO2 Hydrogenation, Ind. Eng. Chem. Res., 45, 1152, 10.1021/ie050499b · DOI
  120. Jadhav, 2014, Catalytic Carbon Dioxide Hydrogenation to Methanol: A Review of Recent Studies, Chem. Eng. Res. Des., 92, 2557, 10.1016/j.cherd.2014.03.005 · DOI · Paper page
  121. Liu, 2003, Recent Advances in Catalyst for Methanol Synthesis via Hydrogenation od CO and CO2, Ind. Eng. Chem. Res., 42, 6518, 10.1021/ie020979s · DOI · Paper page
  122. Saito, 1998, R&D Activities in Japan on Methanol Synthesis from CO2 and H2, Catal. Surv. Jpn., 2, 175, 10.1023/A:1019082525994 · doi:10.1023/a:1019082525994
  123. Chinchen, 1987, The Measurement of Copper Surface Areas by Reactive Frontal Chromatography, J. Catal., 103, 79, 10.1016/0021-9517(87)90094-7 · doi:10.1016/0021-9517(87)90094-7
  124. Twigg, 2001, Deactivation of Supported Copper Metal Catalysts for Hydrogenation Reactions, Appl. Catal., A, 212, 161, 10.1016/S0926-860X(00)00854-1 · doi:10.1016/s0926-860x(00)00854-1
  125. Behrens, 2013, How to Prepare a Good Cu/ZnO Catalyst or the Role of Solid State Chemistry for the Synthesis of Nanostructured Catalysts, Z. Anorg. Allg. Chem., 639, 2683, 10.1002/zaac.201300356 · doi:10.1002/zaac.201300356
  126. Kasatkin, 2007, Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al(2)O(3) Catalysts for Methanol Synthesis, Angew. Chem., Int. Ed., 46, 7324, 10.1002/anie.200702600 · DOI · Paper page
  127. Kuld, 2016, Quantifying the Promotion of Cu Catalysts by ZnO for Methanol Synthesis, Science, 352, 969, 10.1126/science.aaf0718 · DOI · Paper page
  128. Le Valant, 2015, The Cu–ZnO Synergy in Methanol Synthesis from CO2, Part 1: Origin of Active Site Explained by Experimental Studies and a Sphere Contact Quantification Model on Cu+ZnO Mechanical Mixtures, J. Catal., 324, 41, 10.1016/j.jcat.2015.01.021 · DOI · Paper page
  129. Ertl, 1997, Handbook of Heterogeneous Catalysis, 10.1002/9783527619474 · DOI · Paper page
  130. de Jong, 2009, Synthesis of Solid Catalysts, 10.1002/9783527626854 · DOI · Paper page
  131. Behrens, 2013, The Effect of Al-doping on ZnO Nanoparticles Applied as Catalyst Support, Phys. Chem. Chem. Phys., 15, 1374, 10.1039/C2CP41680H · DOI
  132. Behrens, 2011, Understanding the Complexity of a Catalyst Synthesis: Co-precipitation of Mixed Cu,Zn,Al Hydroxycarbonate Precursors for Cu/ZnO/Al2O3 Catalysts Investigated by Titration Experiments, Appl. Catal., A, 392, 93, 10.1016/j.apcata.2010.10.031 · doi:10.1016/j.apcata.2010.10.031
  133. Behrens, 2009, Meso- and Nano-structuring of Industrial Cu/ZnO/(Al2O3) catalysts, J. Catal., 267, 24, 10.1016/j.jcat.2009.07.009 · doi:10.1016/j.jcat.2009.07.009
  134. Behrens, 2009, Minerals as Model Compounds for Cu/ZnO Catalyst Precursors: Structural and Thermal Properties and IR Spectra of Mineral and Synthetic (Zincian) Malachite, Rosasite and Aurichalcite and a Catalyst Precursor Mixture, Eur. J. Inorg. Chem., 2009, 1347, 10.1002/ejic.200801216 · doi:10.1002/ejic.200801216
  135. Behrens, 2010, Structural Effects of Cu/Zn Substitution in the Malachite-Rosasite System, Z. Anorg. Allg. Chem., 636, 919, 10.1002/zaac.201000028 · DOI
  136. Baltes, 2008, Correlations between Synthesis, Precursor, and Catalyst Structure and Activity of a Large Set of CuO/ZnO/Al2O3 Catalysts for Methanol Synthesis, J. Catal., 258, 334, 10.1016/j.jcat.2008.07.004 · DOI · Paper page
  137. Fan, 2010, Preparation of Cu/ZnO/Al2O3 Catalyst under Microwave Irradiation for Slurry Methanol Synthesis, Front. Chem. Eng. China, 4, 445, 10.1007/s11705-010-0521-x · doi:10.1007/s11705-010-0521-x
  138. Jung, 2010, The Importance of the Aging Time to Prepare Cu/ZnO/Al2O3 Catalyst with High Surface Area in Methanol Synthesis, Bull. Korean Chem. Soc., 31, 1241, 10.5012/bkcs.2010.31.5.1241 · doi:10.5012/bkcs.2010.31.5.1241
  139. Kühl, 2014, Cu-Based Catalyst Resulting from a Cu,Zn,Al Hydrotalcite-Like Compound: A Microstructural, Thermoanalytical, and In Situ XAS Study, Chem. - Eur. J., 20, 3782, 10.1002/chem.201302599 · doi:10.1002/chem.201302599
  140. Prieto, 2013, Towards ‘Greener’ Catalyst Manufacture: Reduction of Wastewater from the Preparation of Cu/ZnO/Al2O3 Methanol Synthesis Catalysts, Catal. Today, 215, 142, 10.1016/j.cattod.2013.03.033 · doi:10.1016/j.cattod.2013.03.033
  141. Behrens, 2011, Knowledge-based Development of a Nitrate-free Synthesis Route for Cu/ZnO Methanol Synthesis Catalystsviaformate Precursors, Chem. Commun., 47, 1701, 10.1039/c0cc04933f · doi:10.1039/c0cc04933f
  142. Wang, 2011, Characterization and Performance of Cu/ZnO/Al2O3 Catalysts Prepared via Decomposition of M(Cu, Zn)-ammonia Complexes under Sub-atmospheric Pressure for Methanol Synthesis from H2 and CO2, J. Nat. Gas Chem., 20, 629, 10.1016/S1003-9953(10)60246-0 · doi:10.1016/s1003-9953(10)60246-0
  143. Kondrat, 2016, Stable Amorphous Georgeite as a Precursor to a High-activity Catalyst, Nature, 531, 83, 10.1038/nature16935 · DOI
  144. Arena, 2007, Synthesis, Characterization and Activity Pattern of Cu–ZnO/ZrO2 Catalysts in the Hydrogenation of Carbon Dioxide to Methanol, J. Catal., 249, 185, 10.1016/j.jcat.2007.04.003 · DOI · Paper page
  145. Jiang, 2015, Bimetallic Pd–Cu Catalysts for Selective CO2 Hydrogenation to Methanol, Appl. Catal., B, 170–171, 173, 10.1016/j.apcatb.2015.01.010 · DOI · Paper page
  146. Wambach, 1999, CO2 Hydrogenation over Metal/zirconia Catalysts, Phys. Chem. Chem. Phys., 1, 5071, 10.1039/a904923a · DOI
  147. Raudaskoski, 2007, The Effect of Ageing Time on co-precipitated Cu/ZnO/ZrO2 Catalysts used in Methanol Synthesis from CO2 and H2, Top. Catal., 45, 57, 10.1007/s11244-007-0240-9 · DOI
  148. Frei, 2014, The Influence of the Precipitation/Ageing Temperature on a Cu/ZnO/ZrO2 Catalyst for Methanol Synthesis from H2 and CO2, ChemCatChem, 6, 1721, 10.1002/cctc.201300665 · doi:10.1002/cctc.201300665
  149. Li, 2015, Highly Selective Hydrogenation of CO2 to Methanol over CuO–ZnO–ZrO2 Catalysts Prepared by a Surfactant-assisted co-precipitation Method, J. Power Sources, 279, 394, 10.1016/j.jpowsour.2014.12.142 · DOI
  150. Samson, 2014, Influence of ZrO2 Structure and Copper Electronic State on Activity of Cu/ZrO2 Catalysts in Methanol Synthesis from CO2, ACS Catal., 4, 3730, 10.1021/cs500979c · DOI · Paper page
  151. Witoon, 2016, CO2 Hydrogenation to Methanol over Cu/ZrO2 Catalysts: Effects of Zirconia Phases, Chem. Eng. J., 293, 327, 10.1016/j.cej.2016.02.069 · DOI · Paper page
  152. Angelo, 2015, Study of CuZnMOx Oxides (M = Al, Zr, Ce, CeZr) for the Catalytic Hydrogenation of CO2 into Methanol, C. R. Chim., 18, 250, 10.1016/j.crci.2015.01.001 · DOI
  153. Graciani, 2014, Highly Active Copper-ceria and Copper-ceria-titania Catalysts for Methanol Synthesis from CO2, Science, 345, 546, 10.1126/science.1253057 · DOI · Paper page
  154. Fornero, 2013, Performance of Ternary Cu–Ga2O3–ZrO2 Catalysts in the Synthesis of Methanol using CO2-rich gas Mixtures, Catal. Today, 213, 163, 10.1016/j.cattod.2013.03.012 · doi:10.1016/j.cattod.2013.03.012
  155. Kikuzono, 1981, Selective Hydrogenation of Carbon Monoxide on Palladium Catalysts, Faraday Discuss. Chem. Soc., 72, 135, 10.1039/dc9817200135 · doi:10.1039/dc9817200135
  156. Gotti, 1998, Basic Metal Oxides as Cocatalysts for Cu/SiO2 Catalysts in the Conversion of Synthesis Gas to Methanol, J. Catal., 178, 511, 10.1006/jcat.1998.2167 · doi:10.1006/jcat.1998.2167
  157. Fujitani, 1995, Development of an Active Ga2O3 Supported Palladium Catalyst for the Synthesis of Methanol from Carbon Dioxide and Hydrogen, Appl. Catal., A, 125, L199, 10.1016/0926-860X(95)00049-6 · doi:10.1016/0926-860x(95)00049-6
  158. Collins, 2004, An Infrared Study of the Intermediates of Methanol Synthesis from Carbon Dioxide over Pd/β-Ga2O3, J. Catal., 226, 410, 10.1016/j.jcat.2004.06.012 · DOI · Paper page
  159. Collins, 2012, The role of Pd–Ga Bimetallic Particles in the Bifunctional Mechanism of Selective Methanol Synthesis via CO2 Hydrogenation on a Pd/Ga2O3 Catalyst, J. Catal., 292, 90, 10.1016/j.jcat.2012.05.005 · doi:10.1016/j.jcat.2012.05.005
  160. Collins, 2005, Hydrogen Spillover in Ga2O3–Pd/SiO2 Catalysts for Methanol Synthesis from CO2/H2, Catal. Lett., 103, 83, 10.1007/s10562-005-6507-5 · DOI
  161. Chiavassa, 2009, Methanol Synthesis from CO2/H2 using Ga2O3–Pd/silica Catalysts: Kinetic Modeling, Chem. Eng. J., 150, 204, 10.1016/j.cej.2009.02.013 · DOI
  162. Oyola-Rivera, 2015, CO2 Hydrogenation to Methanol and Dimethyl Ether by Pd–Pd2Ga Catalysts Supported over Ga2O3 Polymorphs, Journal of CO2 Utilization, 9, 8, 10.1016/j.jcou.2014.11.003 · DOI
  163. Koizumi, 2012, Effects of Mesoporous Silica Supports and Alkaline Promoters on Activity of Pd Catalysts in CO2 Hydrogenation for Methanol Synthesis, Catal. Today, 194, 16, 10.1016/j.cattod.2012.08.007 · DOI
  164. Díez-Ramírez, 2016, CO2 Hydrogenation to Methanol at Atmospheric Pressure: Influence of the Preparation Method of Pd/ZnO Catalysts, Catal. Lett., 146, 373, 10.1007/s10562-015-1627-z · doi:10.1007/s10562-015-1627-z
  165. Bahruji, 2016, Pd/ZnO Catalysts for Direct CO2 Hydrogenation to Methanol, J. Catal., 343, 133, 10.1016/j.jcat.2016.03.017 · DOI · Paper page
  166. Xu, 2016, Methanol Synthesis from CO2 and H2 over Pd/ZnO/Al2O3: Catalyst Structure Dependence of Methanol Selectivity, Appl. Catal., A, 514, 51, 10.1016/j.apcata.2016.01.006 · doi:10.1016/j.apcata.2016.01.006
  167. Melaet, 2014, Cobalt Particle Size Effects in the Fischer–Tropsch Synthesis and in the Hydrogenation of CO2 Studied with Nanoparticle Model Catalysts on Silica, Top. Catal., 57, 500, 10.1007/s11244-013-0206-z · DOI
  168. Alayoglu, 2011, CO2 Hydrogenation Studies on Co and CoPt Bimetallic Nanoparticles under Reaction Conditions using TEM, XPS and NEXAFS, Top. Catal., 54, 778, 10.1007/s11244-011-9695-9 · DOI
  169. Hartadi, 2016, Methanol Synthesis via CO2 Hydrogenation over a Au/ZnO Catalyst: an Isotope Labelling Study on the Role of CO in the Reaction Process, Phys. Chem. Chem. Phys., 18, 10781, 10.1039/C5CP06888F · doi:10.1039/c5cp06888f
  170. Pasupulety, 2015, Studies on Au/Cu–Zn–Al Catalyst for Methanol Synthesis from CO2, Appl. Catal., A, 504, 308, 10.1016/j.apcata.2015.01.036 · doi:10.1016/j.apcata.2015.01.036
  171. Studt, 2014, Discovery of a Ni-Ga Catalyst for Carbon Dioxide Reduction to Methanol, Nat. Chem., 6, 320, 10.1038/nchem.1873 · DOI · Paper page
  172. Martin, 2016, Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation, Angew. Chem., Int. Ed., 55, 6261, 10.1002/anie.201600943 · DOI · Paper page
  173. Fujimoto, 1987, Selective Synthesis of C2-C5 Hydrocarbons from Carbon Dioxide Utilizing a Hybrid Catalyst Composed of a Methanol Synthesis Catalyst and Zeolite, Appl. Catal., 31, 13, 10.1016/S0166-9834(00)80663-6 · DOI
  174. Sofianos, 1991, Conversion of Synthesis Gas to Dimethyl Ether over Bifunctional Catalytic Systems, Ind. Eng. Chem. Res., 30, 2372, 10.1021/ie00059a002 · doi:10.1021/ie00059a002
  175. Sartipi, 2014, Catalysis Engineering of Bifunctional Solids for the one-Step Synthesis of Liquid fuels from Syngas: a Review, Catal. Sci. Technol., 4, 893, 10.1039/c3cy01021j · DOI
  176. Liu, 2006, Role of Nanosized Zirconia on the Properties of Cu/Ga2O3/ZrO2 Catalysts for Methanol Synthesis, Chin. J. Chem., 24, 172, 10.1002/cjoc.200690033 · doi:10.1002/cjoc.200690033
  177. Tidona, 2013, CO2 Hydrogenation to Methanol at Pressures up to 950bar, J. Supercrit. Fluids, 78, 70, 10.1016/j.supflu.2013.03.027 · DOI
  178. Zhan, 2014, Methanol Synthesis from CO2 Hydrogenation over La–M–Cu–Zn–O (M = Y, Ce, Mg, Zr) Catalysts Derived from Perovskite-type Precursors, J. Power Sources, 251, 113, 10.1016/j.jpowsour.2013.11.037 · DOI
  179. Angelo, 2016, Catalyst Synthesis by Continuous coprecipitation under Micro-fluidic Conditions: Application to the Preparation of Catalysts for Methanol Synthesis from CO2/H2, Catal. Today, 270, 59, 10.1016/j.cattod.2015.09.028 · doi:10.1016/j.cattod.2015.09.028
  180. Xu, 1997, Synthesis of Dimethyl Ether (DME) from Methanol over Solid-acid Catalysts, Appl. Catal., A, 149, 289, 10.1016/S0926-860X(96)00275-X · DOI · Paper page
  181. Aguayo, 2005, Deactivation and Regeneration of Hybrid Catalysts in the Single-step Synthesis of Dimethyl Ether from Syngas and CO2, Catal. Today, 106, 265, 10.1016/j.cattod.2005.07.144 · DOI
  182. Jun, 1998, The CO2 Hydrogenation toward the Mixture of Methanol and Dimethyl Ether: Investigation of Hybrid Catalysts, Bull. Korean Chem. Soc., 19, 466
  183. Sun, 1993, The Catalytic Conversion of Methyl Chloride to Ethylene and Propylene over Phosphorus-Modified Mg-ZSM-5 Zeolites, J. Catal., 143, 32, 10.1006/jcat.1993.1251 · doi:10.1006/jcat.1993.1251
  184. Topsøe, 1981, Infrared and Temperature-programmed Desorption Study of the Acidic Properties of ZSM-5-type Zeolites, J. Catal., 70, 41, 10.1016/0021-9517(81)90315-8 · DOI · Paper page
  185. Stöcker, 1999, Methanol-to-hydrocarbons: Catalytic Materials and their Behavior, Microporous Mesoporous Mater., 29, 3, 10.1016/S1387-1811(98)00319-9 · DOI · Paper page
  186. Son-Ki, 2003, CO2 Hydrogenation over Copper-Based Hybrid Catalysts for the Synthesis of Oxygenates, 183
  187. Ge, 1999, New Bifunctional Catalyst For Direct Synthesis Of Dimethyl Ether, J. Nat. Gas Chem., 8, 280
  188. Bonura, 2013, Hybrid Cu–ZnO–ZrO2/H-ZSM5 System for the Direct Synthesis of DME by CO2 Hydrogenation, Appl. Catal., B, 140–141, 16, 10.1016/j.apcatb.2013.03.048 · DOI
  189. Gao, 2013, Dimethyl Ether Synthesis from CO2 Hydrogenation on La-modified CuO-ZnO-Al2O3/HZSM-5 bifunctional Catalysts, J. Rare Earths, 31, 470, 10.1016/S1002-0721(12)60305-6 · DOI
  190. Zhao, 2007, Effects of ZrO2 on the Performance of CuO-ZnO-Al2O3/HZSM-5 Catalyst for Dimethyl Ether Synthesis from CO2 Hydrogenation, J. Nat. Gas Chem., 16, 389, 10.1016/S1003-9953(08)60009-2 · doi:10.1016/s1003-9953(08)60009-2
  191. Liu, 2013, Synthesis of Dimethyl Ether from CO2 and H2 Using a Cu–Fe–Zr/HZSM-5 Catalyst System, Ind. Eng. Chem. Res., 52, 16648, 10.1021/ie401763g · DOI
  192. Wang, 2009, Dimethyl Ether Synthesis via CO2 Hydrogenation over CuO–TiO2–ZrO2/HZSM-5 Bifunctional Catalysts, Catal. Commun., 10, 1367, 10.1016/j.catcom.2009.02.001 · DOI
  193. Zhang, 2013, Pd/CNT-promoted CuZrO2/HZSM-5 hybrid Catalysts for direct Synthesis of DME from CO2/H2, Appl. Catal., A, 451, 28, 10.1016/j.apcata.2012.10.038 · DOI
  194. Zha, 2013, Multi-walled Carbon Nanotubes as Catalyst Promoter for Dimethyl Ether Synthesis from CO2 Hydrogenation, Appl. Surf. Sci., 285, 945, 10.1016/j.apsusc.2013.06.150 · DOI
  195. Witoon, 2015, Direct Synthesis of Dimethyl Ether from CO2 Hydrogenation over Cu-ZnO-ZrO2/SO42-ZrO2 hybrid Catalysts: Effects of Sulfur-to-zirconia Ratios, Catal. Sci. Technol., 5, 2347, 10.1039/C4CY01568A · DOI
  196. Naito, 1972, Formation of Dimethyl Ether from Hydrogen and Carbon Dioxide over a Graphite-PdCl2-Na Catalyst, J. Chem. Soc., Chem. Commun., 23, 1266, 10.1039/C39720001266 · DOI
  197. Frusteri, 2015, Stepwise Tuning of Metal-oxide and Acid Sites of CuZnZr-MFI hybrid Catalysts for the Direct DME Synthesis by CO2 Hydrogenation, Appl. Catal., B, 176–177, 522, 10.1016/j.apcatb.2015.04.032 · DOI
  198. Sun, 2004, Low-temperature Synthesis of DME from CO2/H2 over Pd-modified CuO–ZnO–Al2O3–ZrO2/HZSM-5 Catalysts, Catal. Commun., 5, 367, 10.1016/j.catcom.2004.03.012 · DOI
  199. Zhang, 2014, V-modified CuO–ZnO–ZrO2/HZSM-5 Catalyst for Efficient Direct Synthesis of DME from CO2 Hydrogenation, Catal. Commun., 55, 49, 10.1016/j.catcom.2014.05.026 · doi:10.1016/j.catcom.2014.05.026
  200. Qi, 2001, DME Synthesis from Carbon Dioxide and Hydrogen over Cu–Mo/HZSM-5, Catal. Lett., 72, 121, 10.1023/A:1009049513834 · DOI

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Metadata

Authors
Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A. V., Wezendonk, T. A., Makkee, M., Gascon, J., & Kapteijn, F.
Venue
Chemical Reviews
Publisher
American Chemical Society (ACS)
Published
2017-06-28
Volume
117
Issue
14
Pages
9804-9838
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
DOI
10.1021/acs.chemrev.6b00816
OpenAlex
W2725648806
Cited by
1,600
References
9
FWCI
2.67
Type
journal article
Language
en
Open access
hybrid
Licence
pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html (vor, 14 d)
Funders
  • Generalitat de Catalunya (2014 SGR 893)
  • Ministerio de Economía y Competitividad (CTQ2012-34153, SEV-2013-0319)

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CoChat. (2026). Citation check: Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes. https://app.cochat.ai/papers/10.1021/acs.chemrev.6b00816
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Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A. V., Wezendonk, T. A., Makkee, M., Gascon, J., & Kapteijn, F. (2017). Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00816

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