The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Ternary Hybrid Material for High-Performance Lithium–Sulfur Battery
Abstract
The rechargeable lithium-sulfur battery is a promising option for energy storage applications because of its low cost and high energy density. The electrochemical performance of the sulfur cathode, however, is substantially compromised because of fast capacity decay caused by polysulfide dissolution/shuttling and low specific capacity caused by the poor electrical conductivities of the active materials. Herein we demonstrate a novel strategy to address these two problems by designing and synthesizing a carbon nanotube (CNT)/NiFe2O4-S ternary hybrid material structure. In this unique material architecture, each component synergistically serves a specific purpose: The porous CNT network provides fast electron conduction paths and structural stability. The NiFe2O4 nanosheets afford strong binding sites for trapping polysulfide intermediates. The fine S nanoparticles well-distributed on the CNT/NiFe2O4 scaffold facilitate fast Li(+) storage and release for energy delivery. The hybrid material exhibits balanced high performance with respect to specific capacity, rate capability, and cycling stability with outstandingly high Coulombic efficiency. Reversible specific capacities of 1350 and 900 mAh g(-1) are achieved at rates of 0.1 and 1 C respectively, together with an unprecedented cycling stability of ∼0.009% capacity decay per cycle over more than 500 cycles.
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Cites
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A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
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Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
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Self-citationWang, H., Yang, Y., Liang, Y., Robinson, J. T., Li, Y., Jackson, A., Cui, Y., & Dai, H. (2011) · Nano Letters · doi:10.1021/nl200658a · Cited by 2,119
Self-citationWei Seh, Z., Li, W., Cha, J. J., Zheng, G., Yang, Y., McDowell, M. T., Hsu, P.-C., & Cui, Y. (2013) · Nature Communications · doi:10.1038/ncomms2327 · Cited by 2,107
A highly efficient polysulfide mediator for lithium–sulfur batteries
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Nanostructured sulfur cathodes
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Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries
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Cited by
Designing high-energy lithium–sulfur batteries
Seh, Z. W., Sun, Y., Zhang, Q., & Cui, Y. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00410a · Cited by 2,573
Self-citationNanostructured Metal Oxides and Sulfides for Lithium–Sulfur Batteries
Liu, X., Huang, J., Zhang, Q., & Mai, L. (2017) · Advanced Materials · doi:10.1002/adma.201601759 · Cited by 1,616
Advances in Lithium–Sulfur Batteries: From Academic Research to Commercial Viability
Chen, Y., Wang, T., Tian, H., Su, D., Zhang, Q., & Wang, G. (2021) · Advanced Materials · doi:10.1002/adma.202003666 · Cited by 870
Surface Chemistry in Cobalt Phosphide-Stabilized Lithium–Sulfur Batteries
Zhong, Y., Yin, L., He, P., Liu, W., Wu, Z., & Wang, H. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b11434 · Cited by 458
Self-citationLi-S Batteries: Challenges, Achievements and Opportunities
Raza, H., Bai, S., Cheng, J., Majumder, S., Zhu, H., Liu, Q., Zheng, G., Li, X., & Chen, G. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00188-4 · Cited by 406
Metadata
- Authors
- Fan, Q., Liu, W., Weng, Z., Sun, Y., & Wang, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-30
- Volume
- 137
- Issue
- 40
- Pages
- 12946-12953
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2410422296
- Cited by
- 264
- References
- 40
- FWCI
- 19.09
- Type
- journal article
- Language
- en
- Open access
- closed
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