The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
High-Index Faceted Ni3S2 Nanosheet Arrays as Highly Active and Ultrastable Electrocatalysts for Water Splitting
Abstract
Elaborate design of highly active and stable catalysts from Earth-abundant elements has great potential to produce materials that can replace the noble-metal-based catalysts commonly used in a range of useful (electro)chemical processes. Here we report, for the first time, a synthetic method that leads to in situ growth of {2̅10} high-index faceted Ni3S2 nanosheet arrays on nickel foam (NF). We show that the resulting material, denoted Ni3S2/NF, can serve as a highly active, binder-free, bifunctional electrocatalyst for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Ni3S2/NF is found to give ∼100% Faradaic yield toward both HER and OER and to show remarkable catalytic stability (for >200 h). Experimental results and theoretical calculations indicate that Ni3S2/NF's excellent catalytic activity is mainly due to the synergistic catalytic effects produced in it by its nanosheet arrays and exposed {2̅10} high-index facets.
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Cites
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Self-citationMoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
Faber, M. S., Dziedzic, R., Lukowski, M. A., Kaiser, N. S., Ding, Q., & Jin, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504099w · Cited by 1,372
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
Xu, K., Chen, P., Li, X., Tong, Y., Ding, H., Wu, X., Chu, W., Peng, Z., Wu, C., & Xie, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5119495 · Cited by 1,115
High-Index Faceted Noble Metal Nanocrystals
Quan, Z., Wang, Y., & Fang, J. (2013) · Accounts of Chemical Research · doi:10.1021/ar200293n · Cited by 582
Sun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556
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Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
Guo, Y., Park, T., Yi, J. W., Henzie, J., Kim, J., Wang, Z., Jiang, B., Bando, Y., Sugahara, Y., Tang, J., et al. (2019) · Advanced Materials · doi:10.1002/adma.201807134 · Cited by 1,402
Yan, Y., Xia, B. Y., Zhao, B., & Wang, X. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta08075h · Cited by 1,368
Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis
Yu, L., Zhu, Q., Song, S., McElhenny, B., Wang, D., Wu, C., Qin, Z., Bao, J., Yu, Y., Chen, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-13092-7 · Cited by 1,333
Zhang, H., Li, X., Hähnel, A., Naumann, V., Lin, C., Azimi, S., Schweizer, S. L., Maijenburg, A. W., & Wehrspohn, R. B. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706847 · Cited by 917
Metadata
- Authors
- Feng, L.-L., Yu, G., Wu, Y., Li, G.-D., Li, H., Sun, Y., Asefa, T., Chen, W., & Zou, X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-14
- Volume
- 137
- Issue
- 44
- Pages
- 14023-14026
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2411919296
- Cited by
- 1,783
- References
- 7
- FWCI
- 55.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- Feng, L.-L., Yu, G., Wu, Y., Li, G.-D., Li, H., Sun, Y., Asefa, T., Chen, W., & Zou, X. (2015). High-Index Faceted Ni3S2 Nanosheet Arrays as Highly Active and Ultrastable Electrocatalysts for Water Splitting. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b08186
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