The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Hierarchical N-Doped Carbon as CO2 Adsorbent with High CO2 Selectivity from Rationally Designed Polypyrrole Precursor
Abstract
Carbon capture and sequestration from point sources is an important component in the CO2 emission mitigation portfolio. In particular, sorbents with both high capacity and selectivity are required for reducing the cost of carbon capture. Although physisorbents have the advantage of low energy consumption for regeneration, it remains a challenge to obtain both high capacity and sufficient CO2/N2 selectivity at the same time. Here, we report the controlled synthesis of a novel N-doped hierarchical carbon that exhibits record-high Henry's law CO2/N2 selectivity among physisorptive carbons while having a high CO2 adsorption capacity. Specifically, our synthesis involves the rational design of a modified pyrrole molecule that can co-assemble with the soft Pluronic template via hydrogen bonding and electrostatic interactions to give rise to mesopores followed by carbonization. The low-temperature carbonization and activation processes allow for the development of ultrasmall pores (d < 0.5 nm) and preservation of nitrogen moieties, essential for enhanced CO2 affinity. Furthermore, our described work provides a strategy to initiate developments of rationally designed porous conjugated polymer structures and carbon-based materials for various potential applications.
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Cites
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Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
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Trends in Solid Adsorbent Materials Development for CO 2 Capture
Pardakhti, M., Jafari, T., Tobin, Z., Dutta, B., Moharreri, E., Shemshaki, N. S., Suib, S., & Srivastava, R. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b08487 · Cited by 357
The N-doped activated carbon derived from sugarcane bagasse for CO2 adsorption
Han, J., Zhang, L., Zhao, B., Qin, L., Wang, Y., & Xing, F. (2019) · Industrial Crops and Products · doi:10.1016/j.indcrop.2018.11.028 · Cited by 267
Recent developments and consideration issues in solid adsorbents for CO2 capture from flue gas
Nie, L., Mu, Y., Jin, J., Chen, J., & Mi, J. (2018) · Chinese Journal of Chemical Engineering · doi:10.1016/j.cjche.2018.07.012 · Cited by 122
Metadata
- Authors
- To, J. W. F., He, J., Mei, J., Haghpanah, R., Chen, Z., Kurosawa, T., Chen, S., Bae, W.-G., Pan, L., Tok, J. B.-H., Wilcox, J., & Bao, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-13
- Volume
- 138
- Issue
- 3
- Pages
- 1001-1009
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2197762370
- Cited by
- 475
- References
- 7
- FWCI
- 43.15
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Hierarchical N-Doped Carbon as CO2 Adsorbent with High CO2 Selectivity from Rationally Designed Polypyrrole Precursor. https://app.cochat.ai/papers/10.1021/jacs.5b11955
- The paper
- To, J. W. F., He, J., Mei, J., Haghpanah, R., Chen, Z., Kurosawa, T., Chen, S., Bae, W.-G., Pan, L., Tok, J. B.-H., Wilcox, J., & Bao, Z. (2016). Hierarchical N-Doped Carbon as CO2 Adsorbent with High CO2 Selectivity from Rationally Designed Polypyrrole Precursor. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11955
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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