The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Deciphering the Spatial Arrangement of Metals and Correlation to Reactivity in Multivariate Metal–Organic Frameworks
Abstract
Thirty-six porphyrin-based metal–organic frameworks (MOFs) with composition of (M 3 O) 2 (TCPP-M) 3 and M 3 O trigonal SBUs of various metals, Mg 3 O, Mn 3 O, Co 3 O, Ni 3 O, and Fe 3 O including mixed-metal SBUs, Mn x Fe 3– x O, Ni x Fe 3– x O, Co x Ni 3– x O, Mn x Co 3– x O, Mn x Mg 3– x O, and Mn x Ni 3– x O were synthesized and characterized. These multivariate MOFs (MTV-MOFs) were examined by X-ray photoelectron spectroscopy, UV–vis diffuse reflectance spectra, and for the first time, their metal spatial arrangement deciphered and were found to exist in the form of either domains or well-mixed. We find that MTV-MOFs with well-mixed metals in their SBUs, rather than the SBUs having one kind of metal but different from one SBU to another, perform better than the sum of their parts in the test reaction involving the photo-oxidation of 1,5-dihydroxynaphthalene.
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Cited by
Pore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
Sequencing of metals in multivariate metal-organic frameworks
Ji, Z., Li, T., & Yaghi, O. M. (2020) · Science · doi:10.1126/science.aaz4304 · Cited by 272
Metadata
- Authors
- Liu, Q., Cong, H., & Deng, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-10-13
- Volume
- 138
- Issue
- 42
- Pages
- 13822-13825
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2528943651
- Cited by
- 267
- References
- 35
- FWCI
- 7.22
- Type
- journal article
- Language
- en
- Open access
- closed
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