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Ni–C–N Nanosheets as Catalyst for Hydrogen Evolution Reaction
Abstract
We report a facile nitrogenation/exfoliation process to prepare hybrid Ni–C–N nanosheets. These nanosheets are <2 nm thin, chemically stable, and metallically conductive. They serve as a robust catalyst for the hydrogen evolution reaction in 0.5 M H 2 SO 4, or 1.0 M KOH or 1.0 M PBS (pH = 7). For example, they catalyze the hydrogen evolution reaction in 0.5 M H 2 SO 4 at an onset potential of 34.7 mV, an overpotential of 60.9 mV (at j = 10 mA cm –2 ) and with remarkable long-term stability (∼10% current drop after 70 h testing period). They are promising as a non-Pt catalyst for practical hydrogen evolution reaction.
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Metadata
- Authors
- Yin, J., Fan, Q., Li, Y., Cheng, F., Zhou, P., Xi, P., & Sun, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-10-26
- Volume
- 138
- Issue
- 44
- Pages
- 14546-14549
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2532179125
- Cited by
- 494
- References
- 48
- FWCI
- 19.67
- Type
- journal article
- Language
- en
- Open access
- closed
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