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High-Performance Rh2P Electrocatalyst for Efficient Water Splitting
Abstract
The search for active, stable, and cost-efficient electrocatalysts for hydrogen production via water splitting could make a substantial impact on energy technologies that do not rely on fossil fuels. Here we report the synthesis of rhodium phosphide electrocatalyst with low metal loading in the form of nanocubes (NCs) dispersed in high-surface-area carbon (Rh 2 P/C) by a facile solvo-thermal approach. The Rh 2 P/C NCs exhibit remarkable performance for hydrogen evolution reaction and oxygen evolution reaction compared to Rh/C and Pt/C catalysts. The atomic structure of the Rh 2 P NCs was directly observed by annular dark-field scanning transmission electron microscopy, which revealed a phosphorus-rich outermost atomic layer. Combined experimental and computational studies suggest that surface phosphorus plays a crucial role in determining the robust catalyst properties.
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Metadata
- Authors
- Duan, H., Li, D., Tang, Y., He, Y., Ji, S., Wang, R., Lv, H., Lopes, P. P., Paulikas, A. P., Li, H., Mao, S. X., Wang, C., Markovic, N. M., Li, J., Stamenkovic, V. R., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-04-05
- Volume
- 139
- Issue
- 15
- Pages
- 5494-5502
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2600851065
- Cited by
- 389
- References
- 40
- FWCI
- 13.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- Ministry of Science and Technology of the People's Republic of China (2011CB932401, 2011CBA00500, 2012CB224802)
- Basic Energy Sciences (DE-AC02-06CH11357)
- Division of Civil, Mechanical and Manufacturing Innovation (1536811)
- National Natural Science Foundation of China (21131004, 21221062, 21390393, 21590792, 91426302)
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