Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 954

The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.

Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction

Open access
Staszak-Jirkovský, Jakub, Malliakas, Christos D., Lopes, Pietro P., Danilovic, Nemanja, Kota, Subrahmanyam S., Chang, Kee-Chul, Genorio, Bostjan, Strmcnik, Dusan, Stamenkovic, Vojislav R., Kanatzidis, Mercouri G., Markovic, Nenad M.·2016·Nature Materials
DOI 10.1038/nmat4481
Open this paper in CoChat — free account

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1038/nmat4481

Cites

10 of 10 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 10 references

Research works printed but not linked: 40

  1. Markovic, N. M. Electrocatalysis: Interfacing electrochemistry. Nature Mater. 12, 101–102 (2013). · DOI
  2. Gratzel, M. Photoelectrochemical cells. Nature 414, 338–344 (2001). · DOI · Paper page
  3. Schlapbach, L., Zuttel, A. & Züttel, A. Hydrogen-storage materials for mobile applications. Nature 414, 353–358 (2001). · DOI · Paper page
  4. Gasteiger, H. A. & Marković, N. M. Just a dream—or future reality? Science 324, 48–49 (2009). · DOI · Paper page
  5. Chung, I., Lee, B., He, J., Chang, R. P. H. & Kanatzidis, M. G. All-solid-state dye-sensitized solar cells with high efficiency. Nature 485, 486–489 (2012). · DOI · Paper page
  6. Kinoshita, K. Electrochemical Oxygen Technology (John Wiley, 1992).
  7. Gandía, L. M., Oroz, R., Ursúa, A., Sanchis, P. & Diéguez, P. M. Renewable hydrogen production: Performance of an alkaline water electrolyzer working under emulated wind conditions. Energy Fuels 21, 1699–1706 (2007). · DOI · Paper page
  8. Subbaraman, R. et al. Trends in activity for the water electrolyser reactions on 3d M(Ni, Co, Fe, Mn) hydr(oxy)oxide catalysts. Nature Mater. 11, 550–557 (2012). · DOI · Paper page
  9. Moorhouse, J. Modern Chlor-Alkali Technology (Wiley, 2001). · DOI
  10. Birry, L. & Lasia, A. Studies of the hydrogen evolution reaction on Raney nickel–molybdenum electrodes. J. Appl. Electrochem. 34, 735–749 (2004). · DOI · Paper page
  11. Lasia, A. & Rami, A. Kinetics of hydrogen evolution on nickel electrodes. J. Electroanal. Chem. Interfacial Electrochem. 294, 123–141 (1990). · DOI · Paper page
  12. Miousse, D. & Lasia, A. Hydrogen evolution reaction on RuO2 electrodes in alkaline solutions. J. New Mater. 2, 71–78 (1999).
  13. Los, P., Rami, A. & Lasia, A. Hydrogen evolution reaction on Ni–Al electrodes. J. Appl. Electrochem. 23, 135–140 (1993). · DOI
  14. Jaksic, M. M. Advances in electrocatalysis for hydrogen evolution in the light of the Brewer–Engel valence-bond theory. Int. J. Hydrog. Energy 12, 727–752 (1987). · DOI · Paper page
  15. Han, Q., Liu, K., Chen, J. & Wei, X. Hydrogen evolution reaction on amorphous Ni–S–Co alloy in alkaline medium. Int. J. Hydrog. Energy 28, 1345–1352 (2003). · DOI
  16. Faber, M. S., Lukowski, M. A., Ding, Q., Kaiser, N. S. & Jin, S. Earth-abundant metal pyrites (FeS2, CoS2, NiS2, and their alloys) for highly efficient hydrogen evolution and polysulfide reduction electrocatalysis. J. Phys. Chem. C 118, 21347–21356 (2014). · DOI · Paper page
  17. Lukowski, M. A. et al. Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets. J. Am. Chem. Soc. 135, 10274–10277 (2013). · DOI · Paper page
  18. Lauritsen, J. et al. Atomic-scale structure of Co–Mo–S nanoclusters in hydrotreating catalysts. J. Catalys. 197, 1–5 (2001). · DOI · Paper page
  19. Lauritsen, J. V. et al. Location and coordination of promoter atoms in Co- and Ni-promoted MoS2-based hydrotreating catalysts. J. Catalys. 249, 220–233 (2007). · DOI · Paper page
  20. Topsøe, H. The role of Co–Mo–S type structures in hydrotreating catalysts. Appl. Catalys. A 322, 3–8 (2007). · DOI · Paper page
  21. Kibsgaard, J. et al. Comparative atomic-scale analysis of promotional effects by late 3d-transition metals in MoS2 hydrotreating catalysts. J. Catalys. 272, 195–203 (2010). · DOI
  22. Bag, S. et al. Porous semiconducting gels and aerogels from chalcogenide clusters. Science 317, 490–493 (2007). · DOI · Paper page
  23. Bag, S., Gaudette, A. F., Bussell, M. E. & Kanatzidis, M. G. Spongy chalcogels of non-platinum metals act as effective hydrodesulfurization catalysts. Nature Chem. 1, 217–224 (2009). · DOI
  24. Raybaud, P., Hafner, J., Kresse, G., Kasztelan, S. & Toulhoat, H. Ab initio study of the H2–H2S/MoS2 gas–solid interface: The nature of the catalytically active sites. J. Catalys. 189, 129–146 (2000). · DOI · Paper page
  25. Huang, Y., Nielsen, R. J., Goddard, W. A. & Soriaga, M. P. The reaction mechanism with free energy barriers for electrochemical dihydrogen evolution on MoS2 . J. Am. Chem. Soc. 137, 6692–6698 (2015). · DOI · Paper page
  26. Lay, M. D., Varazo, K. & Stickney, J. L. Formation of sulfur atomic layers on gold from aqueous solutions of sulfide and thiosulfate? Studies using EC-STM, UHV-EC, and TLEC. Langmuir 19, 8416–8427 (2003). · DOI
  27. Strmcnik, D. et al. The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum. Nature Chem. 1, 466–472 (2009). · DOI · Paper page
  28. Marković, N. M. & Ross, P. N. Jr. Surface science studies of model fuel cell electrocatalysts. Surf. Sci. Rep. 45, 117–229 (2002). · DOI · Paper page
  29. Tong, Y. J. Unconventional promoters of catalytic activity in electrocatalysis. Chem. Soc. Rev. 41, 8195–8209 (2012). · DOI
  30. Strmcnik, D. et al. Effects of Li+, K+, and Ba2+ cations on the ORR at model and high surface area Pt and Au surfaces in alkaline solutions. J. Phys. Chem. Lett. 2, 2733–2736 (2011). · DOI · Paper page
  31. Jirkovsky, J. S., Björling, A. & Ahlberg, E. Reduction of oxygen on dispersed nanocrystalline CoS2 . J. Phys. Chem. C 116, 24436–24444 (2012). · DOI
  32. Weber, T., Muijsers, J. C. & Niemantsverdriet, J. W. Structure of amorphous MoS3 . J. Phys. Chem. 99, 9194–9200 (1995). · DOI · Paper page
  33. Shafaei-Fallah, M. et al. Ion-exchangeable cobalt polysulfide chalcogel. J. Am. Chem. Soc. 133, 1200–1202 (2011). · DOI
  34. Islam, S. M. et al. One-dimensional molybdenum thiochlorides and their use in high surface area MoSx chalcogels. Chem. Mater. 26, 5151–5160 (2014). · DOI
  35. Boudart, M. Turnover rates in heterogeneous catalysis. Chem. Rev. 95, 661–666 (1995). · DOI · Paper page
  36. Trasatti, S. Work function, electronegativity, and electrochemical behaviour of metals: III. Electrolytic hydrogen evolution in acid solutions. J. Electroanal. Chem. Interfacial Electrochem. 39, 163–184 (1972). · DOI · Paper page
  37. Danilovic, N. et al. Enhancing the alkaline hydrogen evolution reaction activity through the bifunctionality of Ni(OH)2/metal catalysts. Angew. Chem. Int. Ed. 51, 12495–12498 (2012). · DOI · Paper page
  38. Strmcnik, D. S. et al. Unique activity of platinum adislands in the CO electrooxidation reaction. J. Am. Chem. Soc. 130, 15332–15339 (2008). · DOI
  39. Danilovic, N. et al. Activity–stability trends for the oxygen evolution reaction on monometallic oxides in acidic environments. J. Phys. Chem. Lett. 5, 2474–2478 (2014). · DOI · Paper page
  40. Chang, S. H. et al. Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution. Nature Commun. 5, 4191 (2014). · DOI · Paper page

Cited by

See all 954

Metadata

Authors
Staszak-Jirkovský, J., Malliakas, C. D., Lopes, P. P., Danilovic, N., Kota, S. S., Chang, K.-C., Genorio, B., Strmcnik, D., Stamenkovic, V. R., Kanatzidis, M. G., & Markovic, N. M.
Venue
Nature Materials
Publisher
Springer Science and Business Media LLC
Published
2015-11-30
Volume
15
Issue
2
Pages
197-203
ISSN
  • 1476-1122 (ISSN-L)
  • 1476-4660
DOI
10.1038/nmat4481
OpenAlex
W2271655480
Cited by
954
References
10
FWCI
26.78
Type
journal article
Language
en
Open access
green
Licence

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. https://app.cochat.ai/papers/10.1038/nmat4481
The paper
Staszak-Jirkovský, J., Malliakas, C. D., Lopes, P. P., Danilovic, N., Kota, S. S., Chang, K.-C., Genorio, B., Strmcnik, D., Stamenkovic, V. R., Kanatzidis, M. G., & Markovic, N. M. (2016). Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. Nature Materials. https://doi.org/10.1038/nmat4481

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.