The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Silyl Ether as a Robust and Thermally Stable Dynamic Covalent Motif for Malleable Polymer Design
Abstract
Here we introduce silyl ether linkage as a novel dynamic covalent motif for dynamic material design. Through introduction of a neighboring amino moiety, we show that the silyl ether exchange rate can be accelerated by almost three orders of magnitude. By incorporating such silyl ether linkages into covalently cross-linked polymer networks, we demonstrate dynamic covalent network polymers displaying both malleability and reprocessability. The malleability of the networks is studied by monitoring stress relaxation at varying temperature, and their topology freezing temperatures are determined. The tunable dynamic properties coupled with the high thermal stability and reprocessability of silyl ether-based networks open doors to many potential applications for this family of materials.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Williams, M. L., Landel, R. F., & Ferry, J. D. (1955) · Journal of the American Chemical Society · doi:10.1021/ja01619a008 · Cited by 8,083
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Vitrimers: permanent organic networks with glass-like fluidity
Denissen, W., Winne, J. M., & Du Prez, F. E. (2016) · Chemical Science · doi:10.1039/c5sc02223a · Cited by 1,790
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Catalytic Control of the Vitrimer Glass Transition
Capelot, M., Unterlass, M. M., Tournilhac, F., & Leibler, L. (2012) · ACS Macro Letters · doi:10.1021/mz300239f · Cited by 1,206
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Denissen, W., Rivero, G., Nicolaÿ, R., Leibler, L., Winne, J. M., & Du Prez, F. E. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404553 · Cited by 1,121
Malleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
Cromwell, O. R., Chung, J., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03551 · Cited by 1,048
Self-citationMouldable liquid-crystalline elastomer actuators with exchangeable covalent bonds
Pei, Z., Yang, Y., Chen, Q., Terentjev, E. M., Wei, Y., & Ji, Y. (2014) · Nature Materials · doi:10.1038/nmat3812 · Cited by 886
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Cited by
Dynamic Covalent Bonds in Polymeric Materials
Chakma, P., & Konkolewicz, D. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813525 · Cited by 1,014
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934
Zhang, Q., Shi, C.-Y., Qu, D.-H., Long, Y.-T., Feringa, B. L., & Tian, H. (2018) · Science Advances · doi:10.1126/sciadv.aat8192 · Cited by 771
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
Winne, J. M., Leibler, L., & Du Prez, F. E. (2019) · Polymer Chemistry · doi:10.1039/c9py01260e · Cited by 736
Vitrimers: Permanently crosslinked polymers with dynamic network topology
Van Zee, N. J., & Nicolaÿ, R. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101233 · Cited by 734
Metadata
- Authors
- Nishimura, Y., Chung, J., Muradyan, H., & Guan, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-16
- Volume
- 139
- Issue
- 42
- Pages
- 14881-14884
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2763222969
- Cited by
- 586
- References
- 28
- FWCI
- 20.00
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Silyl Ether as a Robust and Thermally Stable Dynamic Covalent Motif for Malleable Polymer Design. https://app.cochat.ai/papers/10.1021/jacs.7b08826
- The paper
- Nishimura, Y., Chung, J., Muradyan, H., & Guan, Z. (2017). Silyl Ether as a Robust and Thermally Stable Dynamic Covalent Motif for Malleable Polymer Design. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b08826
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
