The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Exclusive Ni–N4 Sites Realize Near-Unity CO Selectivity for Electrochemical CO2 Reduction
Abstract
Electrochemical reduction of carbon dioxide (CO 2 ) to value-added carbon products is a promising approach to reduce CO 2 levels and mitigate the energy crisis. However, poor product selectivity is still a major obstacle to the development of CO 2 reduction. Here we demonstrate exclusive Ni–N 4 sites through a topo-chemical transformation strategy, bringing unprecedentedly high activity and selectivity for CO 2 reduction. Topo-chemical transformation by carbon layer coating successfully ensures preservation of the Ni–N 4 structure to a maximum extent and avoids the agglomeration of Ni atoms to particles, providing abundant active sites for the catalytic reaction. The Ni–N 4 structure exhibits excellent activity for electrochemical reduction of CO 2 with particularly high selectivity, achieving high faradaic efficiency over 90% for CO in the potential range from −0.5 to −0.9 V and gives a maximum faradaic efficiency of 99% at −0.81 V with a current density of 28.6 mA cm –2 . We anticipate exclusive catalytic sites will shed new light on the design of high-efficiency electrocatalysts for CO 2 reduction.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
In situ electrochemical quantification of active sites in Fe–N/C non-precious metal catalysts
Malko, D., Kucernak, A., & Lopes, T. (2016) · Nature Communications · doi:10.1038/ncomms13285 · Cited by 568
Trends in electrochemical CO2 reduction activity for open and close-packed metal surfaces
Shi, C., Hansen, H. A., Lausche, A. C., & Nørskov, J. K. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54822h · Cited by 465
Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Yang, H., Wu, Y., Li, G., Lin, Q., Hu, Q., Zhang, Q., Liu, J., & He, C. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b04907 · Cited by 788
Single atom electrocatalysts supported on graphene or graphene-like carbons
Fei, H., Dong, J., Chen, D., Hu, T., Duan, X., Shakir, I., Huang, Y., & Duan, X. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00422j · Cited by 673
Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction
Wang, Q., Lei, Y., Wang, D., & Li, Y. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03781g · Cited by 574
Metadata
- Authors
- Li, X., Bi, W., Chen, M., Sun, Y., Ju, H., Yan, W., Zhu, J., Wu, X., Chu, W., Wu, C., & Xie, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-13
- Volume
- 139
- Issue
- 42
- Pages
- 14889-14892
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2761427375
- Cited by
- 932
- References
- 6
- FWCI
- 24.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, X., Bi, W., Chen, M., Sun, Y., Ju, H., Yan, W., Zhu, J., Wu, X., Chu, W., Wu, C., & Xie, Y. (2017). Exclusive Ni–N4 Sites Realize Near-Unity CO Selectivity for Electrochemical CO2 Reduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b09074
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